Environment-friendly starch adhesive for cementing corrugated boards at low temperature and preparation method of environment-friendly starch adhesive

A starch adhesive, corrugated board technology, applied in the directions of starch derived adhesives, adhesive additives, polymer adhesive additives, etc., can solve the problem of large, steam pressure of 6 to 7 kg for the production of three-layer boards, and five-layer boards. The steam pressure is as high as 8-9 kg, the bonding strength is decreased, and the steam pressure is high.

Inactive Publication Date: 2016-11-09
明辉大秦(上海)环保科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, most of the adhesives used in the production of corrugated cardboard are starch adhesives, which have a wide range of raw materials and a simple glue-making process. They are basically composed of water, starch, alkali, borax, and stabilizers, which are stirred and reacted in a certain proportion and in a certain order. , but in the actual use process, there are slow drying speed, slow vehicle speed, and poor water resistance. The corrugated cardboard produced is easy to get damp and soft, which leads to a decrease in bond strength and edge pressure strength.
Another prominent disadvantage of using ordinary starch adhesives to produce corrugated cardboard is that the required steam pressure is high and the production energy consumption is large. The steam pressure of three-layer boards needs 6-7 kg, and the steam pressure of five-layer boards is as high as 8-9. kg, which runs counter to my country's current energy-saving and emission-reduction policies
[0003] Chinese invention paten

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0030] Example 1

[0031] Add 20 parts (by weight) of starch and 70 parts (by weight) of water into the reactor, stir well, heat up to 40~45°C, add 0.1 part (by weight) of hydrogen peroxide, and react for 45 minutes to obtain oxidized starch, then add 0.9 part ( Weight) sodium hydroxide, track the viscosity of the paste, when the viscosity reaches 20 seconds, add 0.5 parts (weight) magnesium sulfate, 0.5 parts (weight) borax, 5 parts (weight) calcium carbonate, 2.5 parts (weight) urea-formaldehyde resin And 0.5 parts by weight of TX-10, and stir evenly to obtain a starch adhesive.

[0032] Application effect: This starch adhesive has strong initial tack. When the good cardboard is laminated with this adhesive, the steam pressure of the three-layer board machine is reduced from 7 kg to 5 kg, and the steam pressure of the five-layer board paper machine is reduced from 9 kg to 7 kg.

Example Embodiment

[0033] Example 2

[0034] Add 25 parts (weight) of starch and 65 parts (weight) of water into the reaction kettle, stir well, heat up to 40~45°C, add 0.05 parts (weight) of sodium persulfate, react for 30 minutes to obtain oxidized starch, then add 0.95 Parts (weight) of sodium hydroxide, track the viscosity of the paste, when the viscosity reaches 25 seconds, add 0.75 parts (weight) of magnesium sulfate, 0.75 parts (weight) of boric acid, 4 parts (weight) of heavy calcium, 3.5 parts (weight) Melamine formaldehyde resin and 0.5 parts (weight) of AEO-09 are stirred evenly to obtain starch adhesive.

[0035] Application effect: This starch adhesive has strong initial tack. When the good cardboard is laminated with this adhesive, the steam pressure of the three-layer board machine is reduced from 7 kg to 4 kg, and the steam pressure of the five-layer board machine is reduced from 9 kg to 6 kg.

Example Embodiment

[0036] Example 3

[0037] Add 20 parts (weight) of starch and 60 parts (weight) of water into the reactor, stir well, heat up to 40~45°C, add 0.1 part (weight) of potassium persulfate, react for 60 minutes to obtain oxidized starch, then add 0.9 Parts (by weight) of sodium hydroxide, tracking the viscosity of the paste, when the viscosity reaches 30 seconds, add 0.5 parts (by weight) of magnesium chloride, 0.5 parts (by weight) of boric acid, 5 parts (by weight) of calcium carbonate, 5 parts (by weight) of bentonite , 2.5 parts (by weight) of epoxy resin and 0.5 parts (by weight) of TX-10, stir evenly to obtain starch adhesive.

[0038] Application effect: This starch adhesive has a strong initial tack. When the good cardboard is laminated with this adhesive, the steam pressure of the three-layer board machine is reduced from 7 kg to 3.5 kg, and the steam pressure of the five-layer board machine is reduced from 9 kg to 5 kg.

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PUM

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Abstract

The invention relates to an environment-friendly starch adhesive for cementing corrugated boards at a low temperature and a preparation method of the environment-friendly starch adhesive. The starch adhesive is prepared from the following raw materials in parts by weight: 15 to 30 parts of starch, 60 to 80 parts of water, 0.2 to 1 part of sodium hydroxide, 0.05 to 0.2 part of oxidizing agent, 0.1 to 0.5 part of cross-linking agent, 0.1 to 0.5 part of stabilizing agent, 2 to 10 parts of drier, 1 to 5 parts of reinforcing agent and 0.1 to 1 part of penetrating agent. Under the oxidation of the oxidizing agent, besides hydroxyl, groups such as carboxyl and carbonyl are added on molecular chains of the starch, so that the initial adhesion of the adhesive is improved, the cementing quantity is reduced, and the rapidness in drying is facilitated; by adding the penetrating agent, the adhesive can rapidly penetrate through paper and destroy fibers; by adding the cross-linking agent and the reinforcing agent, the adhesive can be instantaneously cross-linked to form a mass structure, the rapid dryness of the adhesive is facilitated, and the adhesive can also be cross-linked with groups on the paper fibers so as to increase the cementing strength and the water resistance of paper boards; and by adding the drier, the drying speed of the starch adhesive can be increased, so that the steam pressure of a paper machine is reduced.

Description

technical field [0001] The invention relates to a starch adhesive, in particular to an environment-friendly starch adhesive for low-temperature lamination of corrugated cardboard and a preparation method thereof. Background technique [0002] At present, most of the adhesives used in the production of corrugated cardboard are starch adhesives, which have a wide range of raw materials and a simple glue-making process. They are basically composed of water, starch, alkali, borax, and stabilizers, which are stirred and reacted in a certain proportion and in a certain order. , but in the actual use process, there are slow drying speed, slow vehicle speed, poor water resistance, and the produced corrugated cardboard is easy to get damp and soft, resulting in a decrease in bond strength and edge pressure strength. Another prominent disadvantage of using ordinary starch adhesives to produce corrugated cardboard is that the required steam pressure is high and the production energy co...

Claims

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Application Information

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IPC IPC(8): C09J103/10C09J11/08C09J11/04C09J11/06C08B31/18
CPCC08B31/18C08K2201/014C08L2205/03C09J11/04C09J11/06C09J11/08C09J103/10C08L61/24C08K3/00C08K2003/265C08K2003/3063C08K2003/387C08L61/28C08L63/00C08K2003/166C08K3/346C08L75/04C08L71/02C08K13/02C08K3/26C08K5/092
Inventor 秦清春
Owner 明辉大秦(上海)环保科技股份有限公司
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