The invention discloses a modified straw polypropylene composite flocculant and a key production technology thereof. The modified straw polypropylene composite flocculant is composed of the following components in parts by weight: ultra-purified water, straw powder, polypropylene, disodium dodecanol sulfosuccinate, 2-methyl-N-[3-(trifluoromethyl) phenyl]propionamide, 1,4-bis[(2,6-diethyl-4-methylphenyl)amino]-9,10-anthraquinone, sodium 1-amino-4-mesitylene amino anthraquinone-2-sulfonate, 3,5-dihydroxyphenylmethanol, uranium nanoparticles, [3-(1-amino-2-bromo-4-amino anthraquinone)proyl]trimethy amino methyl sulfate, 2,2'-[1,2-ethylidene di(oxyl-2,1-phenylene azo)]bis[N-(2,3-dihydro-2-oxo-1H-benzimidazole)-5-yl]-3-oxo-butyrylamide, [4-[4-(acetamino)phenylamino]-1-amino-9,10-dihydro-9,10-dioxoanthracene-2-sulfonic acid. The modified straw polypropylene composite flocculant disclosed by the invention has the advantages that addition quantity is low, and flocculated aggregated particles are dispersed and absorbed; reagent cost is low; alum blossom is large, application range is wide, and pH value range is wide; and formation time is short, precipitates are solid, and phosphorous removal effect is good.