The invention relates to Al2O3 / C
powder as well as a preparation method and application thereof, and belongs to the field of
ceramic powder preparation. The invention relates to a preparation method of Al2O3 / C
powder, which comprises the following steps: by taking
aluminum acetate as a
raw material,
acrylamide as an organic
monomer, N, N '-methylenebisacrylamide as a cross-linking agent and
ammonium persulfate as an initiator, forming
polymer gel with a three-dimensional
network structure through a
sol-
gel method, and
drying to obtain dry gel powder; and pyrolyzing the dry gel powder in
nitrogen to obtain Al2O3 / C powder with a porous structure characteristic. According to the invention,
acrylamide is utilized to form gel with a three-dimensional
network structure, Al < 3 + > is trapped in pores of the gel structure, so that an aluminum source and a
carbon source are uniformly distributed on a
molecular level, and growth of Al2O3 particles is effectively inhibited by utilizing an
isolation effect of C and combining a rapid heating process, so that the
diffusion distance of a substance for forming AlN is greatly shortened, and the preparation process is simplified. According to the method, rapid formation of AlN is promoted, the reaction time is effectively shortened, the efficiency is improved, and the obtained pure-phase AlN powder is small in particle size.