The invention discloses a full -process intelligent temperature control system for large-volume concrete, and the system can achieve the automatic sensing, transmission, interconnection, sharing and control of full-process temperature control information of mixing, transportation, warehousing, closing-out, vibrating, maintaining, water cooling and joint grouting of concrete raw materials, thereby achieving the full-element and full-process management of temperature control and crack resistance based on the technologies of the Internet and Internet of Things, effectively protecting the large-volume concrete from cracking, and improving the construction quality of concrete. The system comprises an aggregate intelligent pre-cooling temperature control unit, a concrete intelligent mixing temperature control unit, a concrete pouring cabin internal small environment unit, a concrete intelligent water cooling unit, a concrete exposure face intelligent maintenance unit, a concrete exposure face intelligent heat preservation unit, an intelligent joint grouting unit, and a control center. The invention also provides a control method.