The invention discloses a preparation method of cube-like nano
calcium carbonate. The preparation method comprises the following steps: calcining
raw material limestone with
high magnesium content into
calcium oxide with certain activity, digesting, refining, removing impurities and preparing into
calcium hydroxide suspension; a composite additive accounting for 1%-5% of the
solid content of
calcium hydroxide in the suspension liquid is added when the
carbonization reaction is carried out for 5 min, a
cellulose-based surfactant accounting for 1%-2% of the theoretical yield of the nano
calcium carbonate is added when the
conductivity of the
system starts to be obviously and continuously reduced, the reaction is carried out for 5 min when the
conductivity of the
system is reduced to an inflection point, the
carbonization reaction is terminated, and the nano
calcium carbonate suspension liquid is obtained; and carrying out filter pressing,
drying, crushing and grading to obtain the cube-like nano
calcium carbonate. By controlling the
calcination degree of the limestone, controlling the
process conditions of the
carbonization reaction and using the synergistic effect of the composite additive, the
crystal form and the morphology of the nano calcium
carbonate are regulated and controlled, and the problems of product
crystal form mixing, irregular morphology
doping, irregular particle size, poor uniformity and the like which easily occur in the process of producing the nano calcium
carbonate from the high-
magnesium limestone are effectively solved.