Method for separating magnesium from lithium and extracting lithium from brine

A technology of brine magnesium and brine, applied in the field of brine magnesium lithium separation and preparation of inorganic lithium salt products, can solve the problems of difficult filtration, large quantity, large loss, etc., achieve simple technical process, overcome low recovery rate, and low production cost Effect

Inactive Publication Date: 2009-09-23
钟辉
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Problems solved by technology

Although this method overcomes some shortcomings of the above-mentioned method, the process is relatively simple, and Li + The loss rate has been reduced, but the fundamental disadvantage of this method is that the precipitates are mostly colloidal precipitates, and the amount is large, and it is difficult to filter, resulting in Li + The loss is relatively large, reaching 15-20%, and the utilization of boron is more difficult, so it has not been used in industry so far.
[0004] Magnesium sulfate subtype salt lakes in western my country (such as Lake Xitaijinel in Qinghai) brine contains a large amount of Mg 2+ 、K + 、Na + , SO 4 2- , Cl - , Li + In addition, it also contains a large amount of B 2 o 3 , after precipitation of sodium salt, potassium and magnesium mixed salt through the salt field, Li + with large amounts of Mg 2+ 、B 2 o 3 , SO 4 2- Coexistence, using the general sodium hydroxide precipitation method to remove magnesium, because magnesium hydroxide is colloidal precipitation, not only extremely difficult to filter, but also leads to a large amount of lithium loss, which is difficult to achieve in engineering, making lithium extraction technology very difficult
Existing research results and technologies are difficult to solve this technical problem economically and effectively

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  • Method for separating magnesium from lithium and extracting lithium from brine
  • Method for separating magnesium from lithium and extracting lithium from brine

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Embodiment 1

[0018] Table 1 embodiment brine composition (unit: g / L)

[0019] brine name

[0020] Get 2 liters of old bittern (see Table 1 for composition) after natural evaporation and precipitation of sodium chloride, potassium and magnesium mixed salts from the brine of Jinaier Salt Lake in Xitai, Qinghai; 300 mL of magnesium hydroxide slurry with a concentration of 15% (mass ratio) As the bottom liquid, add it into a 5000mL beaker (reactor), take 700mL of analytically pure sodium hydroxide solution with a concentration of 16mol / L, add the old brine and sodium hydroxide solution into the reactor continuously in parallel, and add the old brine at a rate of 40mL / min, the sodium hydroxide solution was added at a rate of 13mL / min, and the reaction temperature was controlled and kept at 85°C with a constant temperature water bath; at the same time, 3 grams of analytically pure polyacrylamide was added at one time, and 54 grams of analytically pure octadecylamine hydrochloride was a...

Embodiment 2

[0022] Get 2.0L of old bittern that Table 1 forms; Get concentration and be that 600mL of magnesium hydroxide slurry of 3.5% (mass ratio) is bottom liquid, join in the 5000mL beaker (reactor), get concentration and be 50% (mass ratio percentage) Industrial grade liquid caustic soda 700mL, old brine and liquid caustic soda are continuously added to the reactor in parallel flow, the old brine is added at a rate of 40mL / min, the liquid caustic soda is added at a rate of 13mL / min, and the reaction temperature is controlled and maintained at 85°C by a constant temperature water bath; At the same time, add 5 grams of industrial first-grade polyferric sulfate at one time, and add industrial first-grade ammonium bicarbonate in 2 times. For the first time, 20 grams of ammonium bicarbonate was added at the beginning of the reaction, and for the second time, ammonium bicarbonate was added when the reaction was halfway through. 22 grams, after adding the reaction materials, use the above-m...

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Abstract

The invention provides a method for separating magnesium from lithium and extracting the lithium from high magnesium-lithium ratio brine (brine from a saline lake, from underground and from an oil-gas field). The method comprises: sodium salt and potassium and magnesium mixed salt are separated from the brine by evaporation of a saltpan; after boron extraction, sodium hydroxide is used for precipitating Mg<2+> from obtained old brine, and crystallized Mg(OH)2 is obtained by modification and precipitation condition control; filtration and separation are carried out to remove the Mg(OH)2 to realize separation of magnesium and lithium; after filtered mother solution is vaporized and concentrated for 2-4 times, Na2SO4 and NaCl are separated by crystallization, and pure caustic soda can be added to form lithium carbonate from lithium; or the operation of further evaporation is carried out until Na2SO4 and NaCl are separated by multiple times of natural evaporation or forced evaporation concentration and multiple times of cooling crystallization; the operations of evaporation and concentration are carried out until LiCl saturation, and LiCl products can be prepared after the operation of cooling crystallization is carried out. Compared with the prior art for separating the magnesium from the lithium and extracting the lithium from the brine, the method obtains the crystallized Mg(OH)2 by modification and precipitation condition control, solves the existing technical problem of hard filtration of Mg(OH)2, solves the defects of high energy consumption, complex process and high cost of the existing calcination method, and solves the fundamental defects of low Li<2+> recovery ratio and complex technical process of the traditional precipitation method. The Li<2+> recovery ratio ranges from 85-93%, Mg<2+> removal ratio is more than 99.5%, and the method solves the problem of extracting Li<+> and Mg<2+> from high-magnesium and low-lithium brine with Mg<2+> / Li<+>>=20 mass ratio.

Description

technical field [0001] The invention relates to the technology of separating magnesium and lithium from brine (salt lake brine, underground brine, oil and gas field brine) and preparing inorganic lithium salt products, in particular to high magnesium-lithium ratio (Mg 2+ / Li + ≥20 mass ratio) brine magnesium lithium separation technology problem. Background technique [0002] Lithium and its compounds have extremely important and extensive applications, especially occupying an irreplaceable position in the field of new energy (lithium batteries). There are abundant lithium resources in brines, and plateau salt lakes, underground brines in basins, and brines in oil and gas fields all contain a large amount of lithium. However, since lithium in brine often coexists with a large amount of alkali metal and alkaline earth metal ions in trace amounts, and their chemical properties are very similar, it is difficult to extract and separate lithium from brine, especially from high-...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F5/22C01D15/04C01D15/08C01D3/04C01D5/00C02F9/10C02F1/04B01D9/02
Inventor 钟辉许惠付烨
Owner 钟辉
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