322 results about "Lithium hydroxide monohydrate" patented technology

The present invention relates to a process for producing high purity lithium hydroxide monohydrate, comprising following steps: concentrating a lithium containing brine; purifying the brine to remove or to reduce the concentrations of ions other than lithium; adjusting the pH of the brine to about 10.5 to 11 to further remove cations other than lithium, if necessary; neutralizing the brine with acid; purifying the brine to reduce the total concentration of calcium and magnesium to less than 150 ppb via ion exchange; electrolyzing the brine to generate a lithium hydroxide solution containing less than 150 ppb total calcium and magnesium, with chlorine and hydrogen gas as byproducts; producing hydrochloric acid via combustion of the chlorine gas with excess hydrogen and subsequent scrubbing of the resultant gas stream with purified water, if elected to do so; and concentrating and crystallizing the lithium hydroxide solution to produce lithium hydroxide monohydrate crystals.

In the production process of lithium hydroxide monohydrate, lithium sulfate solution and caustic soda are made to produce metathetic reaction to form mixture solution of sodium sulfate and lithium hydroxide, and sodium sulfate and lithium hydroxide monohydrate are then separated by means of the obvious difference in low temperature solubility. The production process includes the following steps: adding sodium hydroxide into lithium sulfate solution obtained through serial production steps to obtain mixture solution of sodium sulfate and lithium hydroxide; cooling to minus 10 deg.c to 5 deg.c for the crystallization and separation of sodium sulfate; heating to concentrate the separated clear liquid; crystallization and separation to obtain coarse lithium hydroxide monohydrate product; water dissolving coarse lithium hydroxide monohydrate, adding barium hydroxide to form insoluble barium sulfate, filtering, concentrating filtrate, crystallizing to separate wet lithium hydroxide monohydrate; and drying.

The invention provides a process for preparing battery grade lithium hydroxide monohydrate, comprising: (1) adding sodium hydroxide in lithium sulfate purification fluid and obtaining solid of Na2SO4, 10H2O and liquid of LiOH after completely dissolving and cooling, (2) obtaining liquid of LiOH after filtering and separating, (3) evaporating and concentrating the liquid of LiOH and filtering, separating and leaching the liquid of LiOH after cooling and crystallizing to obtain one-time crude product of LiOH, H2O, (4) adding deionized water in the one-time crude product of LiOH, H2O and obtaining re-dissolving solution of the one-time crude product of LiOH, H2O, (5) adding refining agent in the re-dissolving solution of the one-time crude product of LiOH, H2O and obtaining filtrate of LiOH refined liquor after filtering and separating, (6) filtering and separating the LiOH refined liquor after evaporating, concentrating, cooling and crystallizing to obtain solid of battery grade wet product of LiOH, H2O and (7) taking out the battery grade wet product of LiOH, H2O after drying to obtain battery product of LiOH, H2O. The invention is simple in production process, easy operation and perfect product quality.

A preparation method of a layered manganese-based cathode material for raising initial charge/discharge efficiency comprises the following steps of: using ammonium bicarbonate as a precipitating agent, simultaneously adding ammoniacal liquor in a dropwise manner so as to control coprecipitation reaction pH value to 8-9, continuing for 8-12 hours, precipitating a coprecipitation product, adding deionized water to prepare a slurry with the concentration of 150-200g/l, carrying out spray drying on the slurry at the temperature of 100-120 DEG C to prepare a Ni-Mn carbonate powder, insulating at the temperature of 300-350 DEG C for 4-6 hours, heating up to 450-500 DEG C and insulating for 2-4 hours to obtain a precursor powder, weighing lithium hydroxide monohydrate with its mole number being K[1+x/(2+x)], grinding the prepared xLi2MnO3.(1-x)LiNi1/2Mn1/2O2 powder, roasting at the temperature of 600-650 DEG C for 1-6 hours, and annealing. According to the invention, the initial charge/discharge efficiency of the layered manganese-based cathode material is substantially raised, and the cycle stability is obviously improved.

The invention discloses a method for recovering valuable metal from a waste power battery cathode waste material. The method comprises the following steps that (1) the waste power battery cathode waste material is subjected to acid dipping treatment, and a nickel cobalt manganese and lithium containing mixed solution is obtained; (2) the nickel cobalt manganese and lithium containing mixed solution is subjected to impurity removal, nickel cobalt manganese and lithium containing purified liquid and impurity removed liquid or impurity removed residue are obtained; (3) nickel cobalt and manganeseare separated from the nickel cobalt manganese and lithium containing purified liquid through a selective co-extraction method, and nickel cobalt and manganese containing strip liquid and lithium-rich extraction raffinate are obtained; (4) lithium-rich extraction raffinate is subjected to deep impurity removal treatment, and lithium-rich purified liquid and impurity removal liquid or impurity removal residue are obtained; (5) the lithium-rich purified liquid is treated by adopting a bipolar membrane electrodialysis method after being subjected to deep degreasing treatment, and a lithium hydroxide solution and a sulfuric acid solution are generated; and (6) the lithium hydroxide solution is evaporated and concentrated, and a battery-level lithium hydroxide monohydrate and concentrated mother liquid are obtained. The recovery rate of nickel cobalt manganese and lithium is higher than 98%, and appreciation of metal products is achieved while the valuable metal is efficiently recovered.

The invention discloses a method for composite production of high-purity lithium hydroxide monohydrate, high-purity lithium carbonate and battery grade lithium carbonate. Industrial grade lithium hydroxide is dissolved into pure water or crystallization mother liquor, and a first solution is prepared; a first impurity removal agent is added into the first solution, then filtering is performed, a lithium hydroxide crystal is added into a filtrate, cooling crystallization is performed, solid-liquid separation is performed to obtain a high-purity lithium hydroxide monohydrate wet material and crystallization mother liquor; the high-purity lithium hydroxide monohydrate wet material is dissolved into pure water or carbonization mother liquor, and a second solution is prepared; carbon dioxide is introduced into the second solution to perform primary carbonization, and solid-liquid separation is performed to obtain a lithium carbonate wet material and a filtrate; a second impurity removal agent is added into the filtrate, after a heat preservation reaction is performed, carbon dioxide is introduced to perform secondary carbonization, then, introduction of the carbon dioxide is stopped, the reaction continues to be performed, then, solid-liquid separation is performed, obtained solids are washed, a high-purity lithium carbonate wet material and carbonization mother liquor are obtained, and after the high-purity lithium carbonate wet material is post-processed, a high-purity lithium carbonate product is obtained.

The invention discloses a method for preparing lithium hydroxide monohydrate by extracting lithium from spodumene. The method includes steps of transformation roasting, cooling, ball milling, acidification roasting, pulping, neutralizing, separation washing, purifying, blending for transformation, freezing for sodium precipitation, deep decontaminating, evaporative crystallization, centrifugal separation, drip washing and drying. By means of a DTB (draft tube baffle) type crystallizer, an FC (forced circulation) crystallizer or an OSLO crystallizer, continuous cooling crystallization and evaporative crystallization are realized, equipment yield is increased by more than 50%, and equipment utilization rate is increased. Therefore, the method is simple and practical in process, high in equipment yield, low in production cost, high in resource utilization rate, low in energy loss and low in three wastes (waste gas, waste water and waste residues).

The invention relates to a method for preparing a high purity level lithium hydroxide monohydrate and belongs to the technical field of lithium hydroxide preparations. The method includes the following steps of adding calcium hydroxide into a lithium sulfate leaching liquid to adjust the potential of hydrogen (pH) value, filtering to obtain a lithium sulfate primary cleaning liquid, adding sodium hydroxide, then filtering and removing impurities, crystallizing to obtain a sodium sulfate decahydrate solid and a lithium hydroxide refrigerating fluid, finely filtering the lithium hydroxide refrigerating fluid, then performing an evaporating separation to obtain a Lithium hydroxide monohydrate primary crude product, dissolving the crude product by adding water, adding a refining agent to remove sodium, then performing an evaporation concentration, separating and leaching to obtain a Lithium hydroxide monohydrate secondary crude product, adding water into the secondary crude product, performing the evaporation concentration, cooling to crystallize, and drying to obtain the high purity level lithium hydroxide monohydrate. By means of the method, the evaporation liquid-solid ratio is reasonably controlled, and processes of crystallizing and crystal growing are modified, so that the high purity level lithium hydroxide monohydrate product is obtained, the process is simple, the operation is easy, the equipment investment is few, the product cost is low, the lithium recovery rate is high, product qualities are stable, and the method is suitable for the industrialized production of the high purity level lithium hydroxide monohydrate.

The invention relates to a special lubricating grease composition for sintering machine elastic slideways, which comprises 7-12% of thickener, 83-87% of base oil and 4-6% of additive. The additive comprises antioxidant, filler, tackifier and the like. The thickener is complex lithium lubricating grease prepared by reacting C12-C18 long-chain fatty monobasic acid, C6-C10 organic dibasic acid and micromolecule acid with lithium hydroxide monohydrate, wherein the mole ratio of the C12-C18 long-chain fatty monobasic acid to the C6-C10 organic dibasic acid to the micromolecule acid is (10-12):(2-5):(2-4). The mole overrate of the lithium hydroxide monohydrate is 2-20%. The special lubricating grease composition for sintering machine elastic slideways has the advantages of wide raw material sources, lower cost and excellent product performance, can completely satisfy the lubricating requirements of the sintering machine elastic slideway, and thus, has wide application prospects in steel industry as a special lubricating grease for sintering machine elastic slideways.

The invention relates to a preparation method of high-purity lithium carbonate, which belongs to the technical field of preparation of high-purity lithium carbonate. The invention aims at providing the method for directly preparing 99.99% lithium hydroxide by adopting lithium hydroxide, which is simple in production process. The technical scheme of the invention is as follows: preparing battery level lithium hydroxide monohydrate into solution of Li2O with concentration of 50-90g/L; introducing CO2 gas at the flow rate of 3-5L/s into the lithium hydroxide solution, wherein the flow rate of CO2 is decreased to 2-3L/s when the concentration of Li2O in the solution is decreased to 40g/L; decreasing the flow rate of CO2 to 0.8-1.2L/s when the concentration of Li2O in the solution is decreased to 20g/L; stop introducing the gas when a large number of liquids appear in the solution, and preparing lithium carbonate slurry; and separating the lithium carbonate slurry, washing the solids, drying until moisture is less than 0.1%, finally preparing the lithium carbonate. The battery level lithium hydroxide monohydrate is adopted as raw material, the high-purity lithium carbonate with the purity of 99.99% can be simply and conveniently prepared by adopting the method, and further purification is not required.

The invention discloses a production process of micro-powder-grade lithium hydroxide monohydrate. The production process comprises the following steps: (1) sequentially calcining spodumene, cooling the calcining product, finely grinding the calcining product, adding acid for reaction, and then mixing the obtained powder and the acid into slurry; (2) adding calcium salt into the slurry, and carrying out stirring and leaching; (3) filtering the filtered clear liquid again, and purifying the filtered clear liquid by using an alkaline solution; (4) filtering the causticized solution; (5) freezingthe filtered causticized liquid in a freezing workshop to separate out sodium sulfate decahydrate and a lithium hydroxide solution; (6) evaporating, concentrating and purifying the sodium sulfate decahydrate; (7) screening and weighing the sodium sulfate decahydrate; (8) carrying out shunting; (9) carrying out crushing; (10) carrying out grading; and (11) carrying out packaging.

The invention relates to a preparation method of a LiAlO2-coated lithium manganese oxide spinel cathode material. The preparation method comprises the steps of: (a) blending electrolytic manganese dioxide, lithium carbonate and chromium oxide at a molar ratio of Li to Mn of 0.51, and a molar ratio of Cr to Mn of 0.026, crushing and mixing; (b) sintering the material mixture in an air sintering furnace, grinding, sieving, and mixing for the second time; (c) placing the mixed material in the air sintering furnace, and keeping temperature for 10 to 20 hours; (d) blending the product sintered for the second time with lithium fluoride, crushing, and mixing; (e) placing the mixture obtained in the step (d) in the air sintering furnace to obtain LiMn1.95Cr0.05O3.95F0.05; and (f) preparing a 0.2mol/L mixed solution containing lithium hydroxide monohydrate and aluminium isopropoxide, and coating to obtain the final product, namely LiAlO2-coated LiMn1.95Cr0.05O3.95F0.05. The capacity and the cycle performance of the cathode material can be improved effectively by modifying the lithium manganese oxide spinel cathode material by coating.

The invention discloses a production process of lithium hydroxide. According to the production process of lithium hydroxide, the crystallization mother liquor with high-concentration sodium sulfate and lithium hydroxide is used as the raw material, wherein the crystallization mother liquor with high-concentration sodium sulfate and lithium hydroxide is obtained after crystallization precipitation of sodium sulfate decahydrate in the production process of lithium hydroxide by the lithium sulfate method. Lithium hydroxide is prepared by the following steps: step A, introducing the crystallization mother liquor into a membrane separation system, wherein concentrated sodium sulfate solution is the intercept liquid and lithium hydroxide solution is the permeate liquid; step B, cooling (or cooling after further concentration) the sodium sulfate solution obtained in the step A, separating the sodium sulfate solution by centrifugation and drying the centrifuged sodium sulfate solution, so that crystal of sodium sulfate decahydrate is obtained; step C, concentrating the lithium hydroxide solution obtained in the step A by a steamer and further concentrating the concentrated lithium hydroxide solution in a crystallizing tank, then cooling, crystallizing and separating the concentrated lithium hydroxide solution by centrifugation and drying the centrifuged lithium hydroxide solution to obtain crystal of lithium hydroxide monohydrate. According to the production process, sodium sulfate and lithium hydroxide are effectively separated by the membrane separation technology, so that the purity of the lithium hydroxide solution is improved; thus, the quality of the lithium hydroxide product is effectively improved and production efficiency of the lithium hydroxide product is raised while the production cost is reduced.

The invention discloses a technology for extracting lithium hydroxide monohydrate and lithium carbonate by activating, roasting and leaching lepidolite concentrate with sulfuric acid. The technology comprises the following steps: adding water into lepidolite concentrate and calcium sulfate, barite powder or barium sulfate slag and carbon fuel, pressing and acquiring a green ball; roasting in a shaft kiln under an appropriate temperature and at appropriate time; milling the roasted ball; leaching with sulfuric acid; primarily purifying the leachate, concentrating and secondarily purifying, thereby acquiring a finished LiOH solution; secondarily crystalizing and firstly washing the finished solution with saturated solution, thereby acquiring a lithium hydroxide monohydrate product; adding sodium carbonate into lithium hydroxide monohydrate crystallization mother liquor and scrubbing solution and precipitating, thereby acquiring the lithium carbonate product. According to the technology, the lithium can be effectively separated from the lepidolite concentrate and the qualified lithium hydroxide monohydrate and lithium carbonate products can be produced. The technology has the advantages of less energy consumption, few flowing materials, low production cost, less discharge capacity, environmental protection, capability of efficiently realizing the recycling comprehensive utilization and suitability for industrial production.

The invention belongs to the technical field of preparation of electrode materials for lithium ion batteries, and particularly relates to a nanometer iron-lithium oxide composite negative electrode material and a preparation method thereof. The material is a mixture or one of Li0.5F2.5O4 and LiFeO2, is a nanometer material and is uniform in size. The particle diameter of the prepared iron-lithium oxide material is about 250-300 nanometer. The preparation method of the material comprises the following steps: firstly preparing a ferric oxide (Fe2O3) nanorod through the hydrothermal reaction of ferric chloride hexahydrate (FeC13.6H2O) and ammonium dihydrogen phosphate (NH4H2PO4), then mixing the prepared ferric oxide (Fe2O3) nanorod with lithium hydroxide monohydrate (LiOH.H2O), and carrying out high-temperature calcination so as to prepare the nanometer iron-lithium oxide composite negative electrode material. The nanometer iron-lithium oxide composite negative electrode material has regular morphology, high purity and good electrochemical performance and is relatively uniform in size; the preparation method of the nanometer iron-lithium oxide composite negative electrode material is simple in process and is easy for large-scale industrial production.

The invention discloses a lithium titanate/porous carbon composite material. The invention further discloses a preparation method of the lithium titanate/porous carbon composite material. The prepapration method comprises the following steps: weighing lithium hydroxide monohydrate, tetrabutyl titanate and porous carbon according to a certain stoichiometric ratio; adding ethanol and de-ionized water and uniformly mixing; transferring a stirred suspension solution into a hydrothermal reaction kettle and reacting at 180 DEG C for 24h to 48h to obtain precursor slurry; drying and crushing the precursor slurry to obtain precursor powder; treating the precursor powder in an inert atmosphere at the temperature of 500 DEG C to 700 DEG C for 5 to 10 hours to obtain the lithium titanate/porous carbon composite material. The composite material prepared by the technical scheme provided by the invention has excellent rate performance and low-temperature property.

The invention relates to the preparation of high-purity compounds in the technical field of chemical engineering, and particularly relates to a method for preparing sheet high-purity lithium hydroxide by using spodumene concentrate. The method comprises the steps of dissolving the obtained crude product of the lithium hydroxide monohydrate to ensure that the mass concentration of Li2O is 65-70g/L, carrying out concentration and crystallization by using an organic solvent and finally carrying out solid-liquid separation and drying to obtain the sheet high-purity lithium hydroxide. The method can be used for treating different types of minerals; the hydration reaction of the organic solvent plays a role in concentration to ensure that the lithium hydroxide is separated out more easily and more quickly and the impurities are not crystallized along with the lithium hydroxide, so that the purity of the lithium hydroxide is improved, the purity is above 99.8% and the light transmittance is up to 99%. The crystallized particles are narrow in distribution and easy to control; the product quality is stable and exceeds the international electronic-grade standard; and the crystal is sheet; the organic solvent is convenient for repeated application; the operation is carried out at normal temperature so that the energy consumption is reduced.

The invention relates to the technical field of lithium-ion-battery manufacture, in particular to a method for preparation of a sulfur-nitrogen codoped carbon coated nano flower-like lithium titanatecomposite negative electrode material. According to the method, polyvinylpyrrolidone, tetrabutyl titanate and lithium hydroxide monohydrate are dispersed in an organic solvent, after hydrolysis and calcination, thiourea and polyacrylamide are added, then high-temperature plasma treatment is conducted, and the sulfur-nitrogen codoped carbon coated nano flower-like lithium titanate composite negative electrode material is obtained. The seep of preparation of the electrode material and the specific capacity under the high rate condition are improved.

The invention refers to a dust-free lithium hydroxide monohydrate and a preparation method thereof, belonging to the technical field of lithium hydroxide. The technical problems to be solved by the invention are that wet LiOH.H2O has a problem of hardening and dry LiOH.H2O has a problem of dust explosion in the prior art. The invention provides a novel LiOH.H2O, that is, dust-free lithium hydroxide monohydrate without hardening. The lithium hydroxide monohydrate is a loosened granular wet product, wherein the content of water is less than or equal to 3.5%, and the surface of the lithium hydroxide monohydrate is coated with a little anti-hardening agent. The dust-free lithium hydroxide monohydrate is prepared by the following methods: (1) preparing a LiOH solution having a Li2O concentration of 70+-5g/l, and the concentration of SO42- is less than or equal to 15g/l; (2) evaporating the LiOH solution obtained in the step (1) until the ratio of liquid to solid is 1: (0.8-1.5); adding a little anti-hardening agent; uniformly stirring; separating and washing the mixture to obtain dust-free wet LiOH.H2O; and carrying out vacuum seal and packing the wet product, wherein the obtained product is not hardened within 3-5 months.