The invention belongs to a method for producing
strontium hydroxide and a byproduct
sodium thiosulfate by using a
strontium sulfide solution, and belongs to the field of
chemical engineering. According to the technical scheme, the method comprises the following steps: introducing
carbon dioxide-removed air into a
strontium sulfide solution to carry out oxidation reaction, carrying out hot
filtration, and discarding
slag to obtain a red water solution; adding alkali into the red water solution to react, cooling, crystallizing, carrying out
solid-liquid separation, and washing to obtain a crude
strontium hydroxide octahydrate
crystal; recrystallizing the crude
strontium hydroxide octahydrate
crystal, filtering the solution, cooling and crystallizing, carrying out
solid-liquid secondary separation to obtain the
strontium hydroxide octahydrate
crystal, and
drying to obtain a
strontium hydroxide octahydrate product; mixing the mother solution with the washing solution, then introducing
carbon dioxide-removed air or
oxygen for secondary oxidation reaction until the end point is that the red water is completely whitened, and filtering and discarding
slag; and carrying out concentration,
evaporation, cooling
crystallization and
centrifugal separation on the
white water to obtain
sodium thiosulfate pentahydrate crystals. The method comprises the following steps: oxidizing yellow water, adding alkali, filtering, cooling, centrifuging and washing to obtain a crude product, and recrystallizing to obtain a refined product.