The invention provides a neutral
cyanide-free
brush electroplating silver plating solution. The neutral
cyanide-free
brush electroplating silver plating solution is prepared from, by
mass concentration, 20 g / L to 30 g / L of silver salt, 40 g / L to 60 g / L of a coordination agent
sodium thiosulfate, 70 g / L to 90 g / L of
thiourea and homolog thereof, 20 g / L to 30 g / L of a protective agent
methanesulfonic acid derivative, 20 g / L to 120 g / L of an additive polyethyleneimine, 5 g / L to 20 g / L of
potassium metabisulfite, 35 g / L to 110 g / L of
ammonium hydroxide and 0.1 g / L to 0.6 g / L of a stabilizer
sodium citrate, the pH value of the solution is adjusted to range from 6.8 to 7.2 with dilute
nitric acid or dilute
sodium hydroxide, and the solution is a neutral plating solution. The invention further provides a preparation process and use method of the neutral
cyanide-free
brush electroplating silver plating solution. The neutral cyanide-free brush electroplating silver plating solution is prepared by mixing the harmfulless silver salt, coordination agent, protective agent and the like, the raw materials are easy to obtain, and the preparation process is simple. The neutral cyanide-free brush electroplating silver plating solution is applied to the surface of
copper or a
copper alloy for brush electroplating, the method is simple and practicable, and plating is stable.