The application provides a method for preparing high-purity
lithium hydroxide monohydrate and recycling
rubidium and cesium, comprising the following steps: (1) mixing, ball-milling and
roasting lithium ore, a
sulfate and an additive at high temperature to obtain clinker; (2) crushing and
grinding the clinker in step (1) and using water to obtain a leaching solution; (3) adding the leaching solution in step (2) into a three-chamber
electrolytic cell for constant-current
electrolysis to obtain an
anode liquid, an intermediate liquid and a
cathode liquid; (4) obtaining
sulfuric acid from the
anode liquid, evaporating and concentrating the intermediate liquid, step-by-step cooling and
crystallization to obtain
rubidium sulfate,
cesium sulfate and
sodium-
potassium sulfate for
roasting in step (1), and evaporating and concentrating the
cathode liquid to obtain high-purity
lithium hydroxide monohydrate. The high-purity
lithium hydroxide monohydrate can be obtained through
high selectivity of lithium
ion solid-state
electrolyte thin film to lithium, the
utilization rate of
potassium,
rubidium and cesium is improved, the whole process is green and
environmentally friendly, the comprehensive
utilization rate of lithium ore is improved, and the
product value is high.