15 results about "Cesium sulfate" patented technology

The invention belongs to the field of organic synthesis, and particularly relates to a synthesis method of a benzofuran compound. In an inert gas environment, a 2-fluorotoluene compound as shown in a formula 1 and a methyl benzoate compound as shown in a formula 2 are mixed and reacted with an organic solvent methyl tert-butyl ether in the presence of bis (trimethylsilyl) amino cesium and cesium sulfate, and the benzofuran compound as shown in a formula 3 is synthesized under a heating condition. Wherein the methyl benzoate compound as shown in the formula 2 can also be replaced by 2-naphthoic acid methyl ester or 1-naphthoic acid methyl ester. The research develops a benzofuran synthesis strategy without transition metal catalysis. According to the method, on the basis of commercially available raw materials, the construction of a benzofuran skeleton is realized through a simple and efficient path. Due to the mild and green reaction characteristic, a route with practical value is provided for synthesis of active medicine molecules and key intermediates of the active medicine molecules.

The present invention belongs to the technical field of metal smelting, and specifically relates to a method for recovering lithium, rubidium, and cesium from lepidolite ore. The method comprises the following steps: mixing lepidolite concentrate with a reaction agent and roasting the mixture; leaching the obtained roasted sand and an immersion liquid; purifying the obtained leached precious liquid; subjecting the obtained purified slurry to solid-liquid separation and evaporation and concentration to obtain a potassium-sodium mixed salt and a solution after potassium and sodium are removed; using an adsorption resin to remove calcium and magnesium from the solution after potassium and sodium are removed to precipitate lithium, thereby obtaining a crude lithium carbonate product and a lithium precipitation mother liquor; refining the crude lithium carbonate product to obtain battery-grade lithium carbonate; subjecting the lithium precipitation mother liquor to countercurrent continuous extraction and stripping to obtain a cesium-rich strip liquor; subjecting the obtained cesium-extracted solution to countercurrent continuous extraction and stripping to obtain a rubidium-rich strip liquor; and evaporating and crystallizing the cesium-rich strip liquor and the rubidium-rich strip liquor to obtain cesium sulfate and rubidium sulfate products. The invention realizes high leaching of lithium, rubidium and cesium, with a lithium recovery rate of 85% to 90% and a rubidium and cesium recovery rate both greater than 70%. The purity of the prepared lithium carbonate, rubidium sulfate and cesium sulfate products is greater than 99.9%.

The present disclosure broadly relates to a high temperature chemical process for the synthesis of cesium tungstate in the solid state and the preparation of aqueous solutions or deuterated solutions of cesium tungstate. More specifically, but not exclusively, the present disclosure relates to a high temperature chemical process in which tungsten oxide compounds such as tungsten oxides, or natural or synthetic concentrates such as wolframite or scheelite, tungsten industrial by-products or there mixture thereof, are mixed with cesium compounds such as cesium carbonate, or cesium sulfate, or cesium hydroxide or their mixtures thereof and the mixture is roasted in air or oxygen at high temperature inside a kiln. After cooling, the solid sintered mass containing cesium tungstate is leached or dissolved with water or heavy water for producing dense aqueous solutions or deuterated solutions of cesium tungstate.

The invention relates to the technical field of perovskite thin films, in particular to an electron transport layer and perovskite thin film structure and a preparation method thereof.The electron transport layer and perovskite thin film structure comprises an electron transport layer, a sulfate modified layer and a perovskite layer, the electron transport layer, the sulfate modified layer and the perovskite layer are included, the sulfate modified layer is prepared through a sulfate solution, and the sulfate modified layer is prepared through a sulfate solution. The sulfate solution is cesium sulfate, ammonium sulfate or potassium sulfate solution. The adopted salt passivator is economical and environmentally friendly, surface defects are reduced through the reaction of acidic sulfate ions and SnO2, and meanwhile, Cs < + > is used for filling defect sites and adjusting the Fermi level. Through the preparation of the sulfate layer, the carrier transport kinetics of SnO2ETL is improved, the quality of the perovskite film is improved, ion migration is inhibited, and the treatment condition is simple.

The invention discloses a comprehensive utilization method of industrial waste at least containing potassium sulfate, and belongs to the technical field of waste resource utilization. With industrial waste salt as an example, the industrial waste salt is subjected to split-phase dissolution, and a high-potassium solution and a high-sodium solution are obtained; carrying out modified crystallization on the high-potassium solution to obtain crude potassium salt and a potassium-removed solution; dissociating and purifying the crude potassium salt to obtain potassium sulfate; performing salt separation and crystallization on the high-sodium solution to obtain crude sodium salt and a sodium-removed solution; purifying the crude sodium salt to obtain sodium sulfate; mixing the potassium-removed solution and the sodium-removed solution, extracting rubidium and cesium by using an extracting agent solution, and layering; carrying out reverse extraction on the organic layer, and concentrating, crystallizing and drying the obtained rubidium-cesium-rich solution to obtain rubidium sulfate and cesium sulfate; and lithium resources are selectively recovered and heavy metals are removed. The method is simple in process and easy to operate, almost zero emission of pollution is achieved in the whole process, short-distance efficient comprehensive recovery of metal such as sodium, potassium, rubidium, cesium and lithium can be completed, and meanwhile harmless treatment of heavy metal removal is considered.

The invention belongs to the technical field of catalysts, and particularly relates to a preparation method of a catalytic cracking reaction composite metal catalyst and application of the catalytic cracking reaction composite metal catalyst in preparation of vinylidene chloride, and the preparation method of the catalytic cracking reaction composite metal catalyst comprises the following steps: (1) mixing a chitosan solution and an acetic acid solution, adjusting the pH value to obtain a mixed solution, adding the zinc lactate solution into the mixed solution, and uniformly mixing to obtain a zinc chelate solution; (2) mixing the zinc chelate solution, an aluminum-containing compound, a silicon-containing compound and a template agent to form slurry, performing spray granulation to form molecular sieve particles, and performing crystallization, washing and drying to obtain zinc-containing molecular sieve microspheres; (3) mixing cesium sulfate, oleic acid and octadecene for reaction to obtain a cesium oleate solution; and (4) dispersing the zinc-containing molecular sieve microspheres into a cesium oleate solution for reaction to obtain the composite metal catalyst for catalytic cracking reaction. According to the preparation process, the process conditions are optimized, and a perfect catalytic system is formed.

The present application belongs to the technical field of catalysts, and particularly relates to a preparation method of a catalytic cracking reaction composite metal catalyst and application thereof in preparation of vinylidene chloride, the preparation method of the catalytic cracking reaction composite metal catalyst comprising the following steps: (1) mixing a chitosan solution with an acetic acid solution, adjusting pH to obtain a mixed solution, and then adding a zinc lactate solution into the mixed solution and mixing uniformly to obtain a zinc chelate solution; (2) mixing the zinc chelate solution, an aluminum-containing compound, a silicon-containing compound and a template agent to form a slurry, forming molecular sieve particles through spray granulation, crystallizing, washing and drying to obtain zinc-containing molecular sieve microspheres; (3) mixing cesium sulfate, oleic acid and octadecene to obtain a cesium oleate solution through a mixing reaction; and (4) dispersing the zinc-containing molecular sieve microspheres into the cesium oleate solution to react, and obtaining the catalytic cracking reaction composite metal catalyst. The present application optimizes process conditions in the preparation process, and forms a perfect catalytic system.

The invention discloses a palladium-carbon catalyst for meropenem and a preparation method thereof, and the preparation method comprises the following steps: step 1, preparing a carrier: adding activated carbon into an aluminum ammonium sulfate solution, and stirring uniformly at a set temperature; adjusting the pH value of the system to 9-9.5 by using ammonium bicarbonate, and continuously reacting for preset time; after the reaction is finished, filtering, drying an obtained filter cake, and calcining at high temperature in a nitrogen atmosphere to obtain a catalyst carrier; 2, mixing a palladium oxalate solution with a cesium sulfate solution, adding the catalyst carrier prepared in the step 1, and concentrating until the system is anhydrous; and introducing hydrogen under a high-temperature condition for reduction to obtain the palladium-carbon catalyst. The palladium-carbon catalyst can maintain the specific surface area of the activated carbon and increase the density of the activated carbon, is easier to precipitate compared with pure activated carbon, and improves the filtering speed; the prepared palladium-carbon does not contain chloride ions, the activity of the palladium-carbon is improved, and meanwhile, cesium oxide is introduced into the palladium-carbon, so that the selectivity of the catalyst is improved.

The invention belongs to the field of organic synthesis, and particularly relates to a synthetic method of a benzyl phosphine compound. A methylbenzene compound shown in a formula 1 and a phosphine chloride compound shown in a formula 2 react in the presence of bis (trimethylsilyl) lithium amide, potassium tert-butoxide and cesium sulfate to synthesize a benzyl phosphine compound shown in a formula 3, and the benzyl phosphine compound is treated with a borane-tetrahydrofuran solution to obtain a benzyl phosphine-borane complex easy to separate and shown in a formula 4. Wherein the toluene compound as shown in the formula 1 can be replaced by 2-methylpyridine as shown in a formula 5, fluorene as shown in a formula 8, 9-methylanthracene as shown in a formula 11 or 1-methylnaphthalene as shown in a formula 14, and benzyl phosphine compounds as shown in a formula 6, a formula 9, a formula 12 or a formula 15 and benzyl phosphine-borane complexes as shown in a formula 7, a formula 10, a formula 13 or a formula 16 are synthesized respectively. According to the method, direct deprotonation of the toluene compound and nucleophilic substitution reaction of the toluene compound and the phosphonium chloride compound are realized by adopting the combined alkali, and the method has the advantages of easiness in reaction control, high economic benefit and the like.

The invention relates to high-purity cesium carbonate, the content of the cesium carbonate is greater than or equal to 99.999% wt in terms of Cs2CO3, and the total content of impurities Li, Na, K, Rb, Ca, Mg, Al, Fe, SiO2 and heavy metal (in terms of Pb) is less than or equal to 0.001% wt. The preparation method of the high-purity cesium carbonate comprises the following steps: leaching pollucite serving as a raw material with sulfuric acid, crystallizing and recrystallizing a leaching solution to obtain high-purity cesium alum, and adding at least one of cesium chloride, cesium sulfate and cesium nitrate during recrystallization and dissolution of cesium vanadium; and removing aluminum, converting, purifying and removing impurities to obtain a high-purity cesium carbonate solution, evaporating, concentrating, carbonizing and crystallizing to obtain high-purity cesium bicarbonate, and finally drying and decomposing to obtain the high-purity cesium carbonate. Compared with a conventional method for preparing cesium carbonate by extracting cesium from pollucite and a conventional method for preparing high-purity cesium carbonate by extracting cesium from pollucite, the method has the advantages that the product purity is greatly improved, and particularly, the impurity Rb of the same family is less than or equal to 0.0001% wt.

The invention belongs to the field of organic synthesis, and particularly relates to a synthesis method of monobenzyl and dibenzyl phosphine compounds. The preparation method comprises the following steps: mixing toluene as shown in a formula 1 and a dialkyl phosphonium chloride compound as shown in a formula 2 with an organic solvent toluene in the presence of potassium tert-butoxide, bis (trimethylsilyl) lithium amide and cesium sulfate, and carrying out nucleophilic substitution reaction to synthesize the monobenzyl phosphine compound as shown in a formula 3, adding a borane-tetrahydrofuran solution to obtain a mono-benzyl phosphine-borane complex which is easy to separate and is shown as a formula 4; the preparation method comprises the following steps: mixing toluene as shown in a formula 1 and a dichlorophenyl phosphine compound as shown in a formula 2 with an organic solvent in the presence of potassium tert-butoxide, bis (trimethylsilyl) lithium amide and cesium sulfate, and carrying out nucleophilic substitution reaction to synthesize the dibenzyl phosphine compound as shown in a formula 6, and adding a borane-tetrahydrofuran solution to obtain the dibenzyl phosphine-borane complex which is easy to separate and is shown as a formula 7. According to the invention, a'one-pot method 'synthesis strategy is adopted, so that the separation of an unstable phosphine intermediate is avoided.

A method for extracting high-purity cesium sulfate from high-salinity wastewater relates to the technical field of wastewater treatment and recovery. The method first freezes the high-salinity wastewater to precipitate the sodium ions therein in the form of high-grade sodium sulfate, and reduces the sodium ion and sulfate ion content in the frozen liquid. Subsequently, the potassium ion crystals are precipitated through the first extraction and back extraction, and the back extraction liquid is evaporated for the first time. Finally, the evaporated liquid is subjected to secondary extraction, back extraction, and evaporation to obtain a high-grade cesium sulfate product. It is not only simple and convenient to operate, but also has low requirements on equipment and has good practical value. A device for extracting high-purity cesium sulfate from high-salinity wastewater, which is used in conjunction with the above method, and includes a refrigeration tank, a first extraction tank, a first evaporation tank, a second extraction tank, and a second evaporation tank connected in series in sequence. It is not only simple in structure and easy to use, but also has high processing efficiency.

The application provides a method for preparing high-purity lithium hydroxide monohydrate and recycling rubidium and cesium, comprising the following steps: (1) mixing, ball-milling and roasting lithium ore, a sulfate and an additive at high temperature to obtain clinker; (2) crushing and grinding the clinker in step (1) and using water to obtain a leaching solution; (3) adding the leaching solution in step (2) into a three-chamber electrolytic cell for constant-current electrolysis to obtain an anode liquid, an intermediate liquid and a cathode liquid; (4) obtaining sulfuric acid from the anode liquid, evaporating and concentrating the intermediate liquid, step-by-step cooling and crystallization to obtain rubidium sulfate, cesium sulfate and sodium-potassium sulfate for roasting in step (1), and evaporating and concentrating the cathode liquid to obtain high-purity lithium hydroxide monohydrate. The high-purity lithium hydroxide monohydrate can be obtained through high selectivity of lithium ion solid-state electrolyte thin film to lithium, the utilization rate of potassium, rubidium and cesium is improved, the whole process is green and environmentally friendly, the comprehensive utilization rate of lithium ore is improved, and the product value is high.

The invention discloses a resource utilization method of potassium, aluminum, sulfur, rubidium and cesium, which can efficiently recover aluminum, potassium and rubidium sulfate resources and is used for producing lithium carbonate from lithium ores, and the method comprises the following steps: carrying out dehydration treatment and high-temperature roasting treatment on a byproduct alum to obtain a roasted material and acid gas; performing multi-stage absorption on the acid gas to prepare a first sulfuric acid solution and a second sulfuric acid solution; adding the roasted material into water, stirring and dissolving, and carrying out solid-liquid separation to obtain crude aluminum oxide and potassium sulfate enriched liquid; freezing and crystallizing the potassium sulfate enriched liquid, and separating out potassium sulfate crystals and crystallization mother liquor containing rubidium and cesium; mixing the crystallization mother liquor with the lithium precipitation mother liquor to obtain rubidium and cesium enriched liquor; extracting the rubidium-cesium enriched liquid to obtain a cesium-containing organic phase and a rubidium-containing water phase; the cesium-containing organic phase is subjected to reverse extraction, and a cesium sulfate solution and an inactivation extraction agent are obtained; extracting the rubidium-containing water phase to obtain a rubidium-containing organic phase and raffinate; and the rubidium-containing organic phase is subjected to reverse extraction, and a rubidium sulfate solution and an inactivation extraction agent are obtained.

The present application relates to the field of concrete, specifically discloses ultra-high performance concrete and its preparation process, concrete includes the following raw materials: cement, glass beads, mineral powder, silica fume, fine aggregate, water, water-reducing agent, steel fiber, expansion agent, modified nanoporous carbon fiber, magnesium slag powder and casein water-absorbing composition;Modified nanoporous carbon fiber is modified by nanoporous carbon fiber after cesium sulfate solution immersion;Casein water-absorbing composition is obtained by mixing casein and chitosan-based water-absorbing polymer and genipin;Its preparation process includes the following steps:Cement, glass beads, mineral powder, silica fume and fine aggregate are mixed, expansion agent, magnesium slag powder and casein water-absorbing composition are added;Water-reducing agent is dissolved in water and added, steel fiber and modified nanoporous carbon fiber are added in batches, residual water is added, and ultra-high performance concrete is obtained. The present application has the characteristics of improving the autogenous shrinkage value of ultra-high performance concrete, while having higher mechanical strength.