474 results about "Barium carbonate" patented technology

The invention discloses a matte glaze and a preparation method thereof. The matte glaze comprises the following components by weight: 1-5 parts of zinc oxide, 5-15 parts of barium carbonate, 0-15 parts of zirconium silicate, 10-25 parts of potassium feldspar, 10-20 parts of kaolin, 5-15 parts of calcite, 5-15 parts of calcined talcum powder, 20-35 parts of a matte frit and 0.5-1 part of an additive. Specifically, the matte frit comprises the following components by weight: 30-50 parts of SiO2, 15-20 parts of Al2O3, 0.01-0.5 part of Fe2O3, 3-10 parts of CaO, 0.5-5 parts of MgO, 1-5 parts of K2O, 3-10 parts of Na2O, 3-10 parts of ZnO, 0.1-1 part of B2O3 and 10-25 parts of BaO. By introducing the matte frit, the melting temperature of the formula is lowered, the firing range of the formula isbroadened, and the glaze texture achieves a fine matte effect.

The invention relates to the technical field of inorganic nonmetal ceramic materials, in particular to a ceramic tile and a preparation method thereof. The ceramic tile comprises the following raw materials: 40-50 parts of waste residues, 1-5 parts of barium carbonate, 5-8 parts of feldspar powder, 0.5-3 parts of zinc oxide, 2-7 parts of pigment, 15-20 parts of modified kaolin and 1-5 parts of water. The preparation process of the modified kaolin comprises the following steps: (1) adding kaolin into deionized water, then adding octadecyl bis (hydroxyethyl) methyl ammonium chloride, stirring, filtering and drying to obtain pretreated kaolin; and (2) adding the kaolin pretreated in the step (1) into deionized water, then adding cellulose and manganous nitrate, carrying out heating reaction, and then filtering, washing and drying to obtain the modified kaolin. Cellulose is carbonized on the surface of kaolin through a hydrothermal carbonization reaction, the heat conduction efficiency of the ceramic tile is reduced, the hybridization degree of the surface structure of kaolin is further improved by adding manganous nitrate, and the strength of the ceramic tile is improved.

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention provides a concrete admixture with sulfate corrosion resistance and rust resistance functions. The concrete admixture is prepared from the following raw materials in parts by weight: 50-65 parts of fly ash, 8-12 parts of barium carbonate, 8-12 parts of barium hydroxide, 8-12 parts of mineral powder, 5-8 parts of modified hydrotalcite or hydrotalcite, 1-3 parts of nano silicon dioxide and 1-3 parts of calcium nitrite. Nano silicon dioxide is adopted as a compact component, the porosity of the material is reduced, the compactness of concrete is improved, sulfate in the environment is inhibited from being transmitted into the concrete, meanwhile, hydrotalcite is modified by polymaleic acid serving as a scale inhibition component, and the scale inhibition effect is improved through the dual effects of high adsorbability and slow release of the scale inhibition component of hydrotalcite. The preparation method has the advantages that generation of ettringite and gypsum in a sulfate radical environment is inhibited, calcium nitrite is added as a corrosion-inhibiting component, a protective film is formed on the surface of a reinforcing steel bar, the corrosion phenomenon of the reinforcing steel bar in a concrete structure is inhibited, and finally, the concrete admixture with sulfate corrosion resistance and corrosion-inhibiting functions is formed through compounding.

The preparation method of the quartz crucible comprises the following steps that a crucible green body is prepared, the crucible green body comprises a first quartz sand layer and a second quartz sand layer which are sequentially arranged from outside to inside, and the second quartz sand layer comprises quartz sand and barium carbonate; the purity of the quartz sand in the first quartz sand layer is smaller than that of the quartz sand in the second quartz sand layer; the crucible green body is fired, and a crucible body is obtained; a protective coating is sprayed to the inner surface of a crucible body through inert gas, then gradient heating heat treatment is conducted after carbon dioxide gas is introduced, the quartz crucible is obtained, the quartz crucible comprises the crucible body and a protective layer located on the inner surface of the crucible body, and the protective layer comprises barium carbonate, nano silicon dioxide and barium borate. According to the preparation method of the quartz crucible, the binding force between the protective coating and the inner surface of the quartz crucible can be improved, the corrosion resistance of the quartz crucible is improved, and the service life of the quartz crucible is prolonged.

The invention relates to the technical field of glazes, and particularly discloses an antifouling glaze with a snow velvet effect and a preparation method thereof. The glaze comprises the following raw materials in parts by weight: 35-45 parts of quartz stone, 4-6 parts of zinc oxide, 7-8 parts of strontium carbonate, 4-5 parts of barium carbonate, 7-9 parts of calcite, 8-10 parts of talc, 5-8 parts of kaolin, 0.01-0.1 part of titanium dioxide and 1-5 parts of a microcapsule repairing agent. According to the glaze, a large number of fine willemite crystals can be separated out, so that a flickering crystal flower effect is generated, and a glass phase between the crystals is very compact, so that the unification of a visual effect and an antifouling function is realized. Even if the surface is scrubbed to generate scratches, the surface can be recovered through self-repairing, so that the antifouling effect is further improved.

The invention discloses a wear-resistant and mildew-proof ceramic tile which comprises a green body and a glaze layer attached to the green body, and the wear-resistant and mildew-proof ceramic tile is obtained by coating the surface of the green body with a modified interface agent and then glazing, wherein the glaze layer is prepared from the following raw materials in parts by weight: 40 to 50 parts of silicon dioxide, 30 to 35 parts of aluminum oxide, 15 to 20 parts of modified titanium dioxide, 6 to 10 parts of barium carbonate, 6 to 10 parts of mullite, 5 to 8 parts of silver-loaded zirconium phosphate, 4 to 8 parts of potassium carbonate, 4 to 8 parts of sodium carbonate, 3 to 7 parts of limestone, 3 to 5 parts of sodium borate, 2 to 4 parts of zinc oxide and 0.5 to 1 part of sodium tripolyphosphate. According to the ceramic tile, the modified interface agent with specific composition is introduced between the ceramic tile green body and the glaze layer, modified titanium dioxide and inorganic components (such as aluminum phosphate, aluminum acetylacetonate and tetrapropyl zirconate) in the interface agent form oxides in the sintering process, and the interface bonding strength is remarkably enhanced through physical occlusion; and the long-term wear resistance and mildew resistance of the ceramic tile glaze layer are improved.

The embodiment of the invention discloses a preparation method of a europium-barium-copper oxide superconducting sputtering target material, which comprises the following steps: mixing europium oxide powder, barium carbonate powder and barium oxide powder according to a set proportion, and then mixing with a dispersing agent and water to obtain first europium-barium-copper oxide slurry; carrying out spray granulation on the first europium-barium-copper oxide slurry to obtain first mixed powder; calcining the first mixed powder, and mixing the calcined first mixed powder with a dispersant, a binder and water to obtain second europium barium copper oxide slurry; performing spray granulation on the second europium-barium-copper oxide slurry to obtain second mixed powder; carrying out compression molding-cold isostatic pressing on the second mixed powder to obtain a europium-barium-copper oxide target material biscuit; wherein the mold pressing pressure ranges from 3 MPa to 6 MPa, and the cold isostatic pressing pressure ranges from 100 MPa to 250 MPa; the europium-barium-copper oxide target material biscuit is subjected to degreasing and sintering integrated treatment, and the europium-barium-copper oxide superconducting sputtering target material is obtained; the relative density of the europium barium copper oxide superconducting sputtering target material is as high as 97.98%, and the bulk resistivity is as low as 1.98 m omega.cm.

The invention discloses micro-chemical continuous synthesis equipment and preparation method of nano barium sulfate / barium carbonate, and the micro-chemical continuous synthesis equipment comprises a support frame for bearing the whole equipment; the outer shell is fixed on the support frame, and a plurality of annularly distributed arc-shaped openings are formed in the lower part of the outer shell; the top of the inner shell is fixedly connected with the top of the outer shell, and the lower portion of the inner shell is provided with an adjusting arc opening corresponding to the arc opening. The rotary adjusting assembly is rotationally arranged between the outer shell and the inner shell; the continuous phase conveying device is fixedly arranged in the center of the upper part of the inner shell; the dispersed phase conveying device is fixed in the center of the lower part of the inner shell; the adjusting conveying device corresponds to the arc-shaped opening in the outer shell and is fixed on the outer side of the dispersed phase conveying device; and the collecting assembly is fixed at the bottom of the dispersed phase conveying device and corresponds to the inner shell and the outer shell. According to the invention, controllable growth of crystal grains can be realized, the product size is uniform, the nanocrystallization degree is high, and supporting facilities such as front-end pretreatment and rear-end filtering and drying of a traditional process can be coupled.

The invention discloses 95 aluminum oxide ceramic for a vacuum switch and a preparation method of the 95 aluminum oxide ceramic, and belongs to the technical field of aluminum oxide ceramic and vacuum switches. The ceramic disclosed by the invention is prepared from the following raw materials: 3 to 5 parts of nano alpha-aluminum oxide, 0.05 to 0.1 part of yttrium oxide, 0.04 to 0.08 part of lanthanum oxide, 0.3 to 0.6 part of zirconium silicate, 3.0 to 4.5 parts of fused quartz, 1 to 1.6 parts of magnesium fluoride, 0.3 to 0.5 part of calcium carbonate, 0.3 to 0.5 part of barium carbonate, 1.5 to 2.5 parts of Suzhou clay and 93 to 94 parts of micron alpha-aluminum oxide. The prepared high-performance 95 aluminum oxide ceramic has excellent breaking strength, electric breakdown strength, thermal shock resistance, chemical stability and the like, can meet the performance requirements of a high-pressure vacuum tube in a severe working environment, and ensures the working stability of a circuit.

The invention discloses a solid waste treatment device for preparing electronic-grade barium chloride by using industrial barium carbonate slag, and relates to the technical field of solid waste treatment.The solid waste treatment device comprises a treatment box and a solid waste crushing mechanism, a first containing cavity is formed in one side of the treatment box, and a fixed gear is connected to the side face of a rolling gear in an engaged mode. According to the solid waste treatment device for preparing the electronic-grade barium chloride by utilizing the industrial barium carbonate slag, a rolling gear rolls along the outer side surface of a fixed gear by utilizing rotation of a sliding rod, so that a reciprocating screw rod is driven to drive a movable sleeve seat, and the sliding rod carries a hammer head to perform reciprocating displacement in a rotor disc; therefore, the hammerheads rotate in the treatment box no longer in a single track, large-particle barium slag originally located between the hammerheads is fully stressed to be crushed due to the change of the rotation track of the hammerheads, and the problem that the barium slag cannot be stressed to be crushed due to the fact that the sliding track of the barium slag is located between the hammerheads is solved. Therefore, the crushing efficiency of the barium slag is effectively improved.

The invention relates to the technical field of domestic ceramics, in particular to a high-strength and high-gloss domestic ceramic and a preparation method thereof, and the high-strength and high-gloss domestic ceramic comprises the following raw materials in parts by weight: 35-45 parts of mullite, 15-20 parts of spodumene, 10-15 parts of quartz, 8-12 parts of a modifier doped with barium carbonate, 5-8 parts of a boric oxide additive and 7-11 parts of a yttrium-zinc reconditioning agent. According to the domestic ceramic, mullite, spodumene and quartz are used as matrixes, an added yttrium-zinc compound regulator is used as an antibacterial functional agent, nano-zinc oxide is blended into cobalt nitrate and yttrium nitrate solutions, sintering improvement is performed, and the antibacterial stability of the product is enhanced and optimized through compounding of yttrium, zinc and cobalt; meanwhile, the added modifier doped with barium carbonate and the boron oxide additive are mutually blended and coordinated, so that the antibacterial property, the glossiness and the strength of the obtained domestic ceramic are improved in a balanced and coordinated manner, and the product is remarkable in cold and heat resistance and temperature-resistant stability effect.

The invention discloses a concave-convex high-skid-resistance archaized brick and a preparation process thereof, and relates to the field of building materials. When the concave-convex high-skid-resistance archaized brick is prepared, ferrochrome waste residues, coal ash, argil, quartz sand, clay powder and red soil powder are subjected to mold pressing and roasting, and a green brick is prepared; mixing albite, quartz, calcite, zinc oxide, barium carbonate, deionized water, water glass and American water, glazing the surface of a green brick, and roasting to obtain an archaized brick matrix; the archaized brick base body is sequentially subjected to a reaction with 3-aminopropyltrimethoxysilane, 5, 7-dihydroxyflavone, 1H, 1H-perfluorooctylamine and 1, 3-propane sultone, and the concave-convex high-skid-resistance archaized brick is prepared. The concave-convex high-skid-resistance archaized brick prepared by the invention has good antibacterial, antifouling and coating durability effects.

The invention relates to the technical field of barium carbonate preparation, and provides a barium carbonate synthesis reactor and an application method thereof.The barium carbonate synthesis reactor comprises a tower body, a reaction pipe, a flow guide pipe and a sprayer, and the tower body, the reaction pipe and the flow guide pipe are coaxially arranged; the reaction tube is positioned in the tower body, and one end of the reaction tube extends out of the tower body; the flow guide pipe is located in the reaction pipe, and the flow guide pipe and the reaction pipe form a turbulent flow part used for reducing the gas flow rate and discharging reaction gas; the spray head is arranged on the reaction tube, and the spraying end of the spray head is positioned in the reaction tube and corresponds to the turbulent flow part. The reaction pipe and the flow guide pipe are arranged in the tower body, the reaction pipe extends out of the tower body, carbon dioxide gas can be conveniently input, and the flow guide pipe can conduct gas flow guide, so that the carbon dioxide gas can fully react with a barium sulfide solution sprayed by the spray heads on the periphery of the reaction pipe; meanwhile, the flow guide pipe is also used for outputting gas, so that gas output in the tower is realized, and the device is suitable for preparing barium carbonate by taking a barium sulfide solution as a raw material.

The invention belongs to the technical field of ceramic tiles, and discloses a light-sensitive ceramic tile with a combined dry particle and dazzling diamond effect and a preparation method of the light-sensitive ceramic tile. The combined dry granules comprise ceramic dry granules and zircon sand dry granules in a mass ratio of (5-9): (1-5), the ceramic dry granules comprise the following raw materials in parts by weight: 2-7 parts of albite, 1-4 parts of dolomite, 15-21 parts of calcite, 9-13 parts of potassium carbonate, 5-10 parts of aluminum oxide, 45-55 parts of quartz powder, 0.5-1.5 parts of barium carbonate and 6-10 parts of zinc oxide. The light-sensitive ceramic tile with the dazzling diamond effect can be obtained by applying the combined dry particles to a glue dry particle layer. The combined dry particles adopted by the invention can enable the ceramic tile to generate a dazzling three-dimensional flash form, and the pattern is more three-dimensional and natural; and the ceramic tile is smooth in glaze surface and good in antifouling effect.

The invention discloses an environment-friendly ceramic and a preparation method thereof, and belongs to the field of ceramics, the method comprises the following steps: grinding and mixing kaolin, boric oxide, carbon powder, zirconium, barium carbonate, calcium carbonate, boron, silicon and titanium to obtain a mixture; mixing zinc nitrate, zirconium nitrate and a dispersing agent to obtain a mixed solution; mixing the mixture with the mixed liquid to obtain mixed slurry; preparing the mixed slurry into a blank body; putting the blank body into a sintering furnace, heating to 560-720 DEG C, and treating in a first treatment environment for 1.5-4 hours; the temperature of the sintering furnace is increased to 880-1130 DEG C, and treatment is conducted for 2-5 h in a second treatment environment; the temperature of the sintering furnace is increased to 1280-1420 DEG C, and treatment is conducted for 3-6 h in a third treatment environment; the temperature of the sintering furnace is increased to 1530-1620 DEG C, and treatment is conducted for 1-3 h in a fourth treatment environment; the first treatment environment, the second treatment environment, the third treatment environment and the fourth treatment environment comprise vacuum or inert atmosphere. The sintered ceramic is high in strength and good in wear resistance and corrosion resistance.

The invention discloses a titanium-based enamel coating suitable for low-temperature firing and a preparation method of the titanium-based enamel coating, and belongs to the field of enamel material preparation and application. Wherein TA1 is adopted as the titanium alloy base material; the enamel frit provided by the invention is prepared by mixing and melting the following components in percentage by mass: 28 to 47.7 percent of quartz, 21.2 to 46.4 percent of boric acid, 10.5 to 13.6 percent of sodium carbonate, 5.4 to 6.9 percent of lithium carbonate, 3.8 to 4.4 percent of zinc oxide, 1.8 to 3.0 percent of barium carbonate, 2.6 to 5.5 percent of strontium carbonate and 0.5 to 1.0 percent of zircon quartz powder. The preparation method of the coating comprises the following steps: carrying out ball milling on the enamel frit, a small amount of clay, nitrite and water, spraying on the surface of a TA1 titanium substrate with a clean surface, drying, and sintering in a high-temperature furnace at 740-840 DEG C for 10 minutes; according to the titanium-based enamel coating obtained through the method, the firing temperature ranges from 740 DEG C to 840 DEG C, the coating is firmly combined with a base material, the temperature sudden change resistance is excellent, and the titanium-based enamel coating can bear the temperature difference impact of 700 DEG C.

The invention belongs to the technical field of preparation processes of barium metaphosphate, and particularly relates to a preparation method of monodisperse micron-sized barium metaphosphate. The preparation method comprises the following steps: mixing purified barium carbonate slurry and phosphoric acid according to a certain molar ratio, reacting to obtain barium dihydrogen phosphate slurry, adding ethanol and a particle size regulating agent, uniformly mixing, and carrying out spray drying to obtain a crude product; the particle size regulating agent comprises ammonium citrate, polyalcohol and barium metaphosphate; and calcining the crude product to obtain the product monodisperse micron-sized barium metaphosphate. According to the preparation method, a small amount of particle size regulating agent and a certain amount of ethanol are added, a crude product with uniform particle size distribution is prepared under a spray drying process condition, and then calcination is performed to obtain the micron-sized barium metaphosphate with uniform particle size distribution.

The invention discloses micron-sized pearl glaze ceramic and a preparation method thereof, and relates to the technical field of ceramic, and the micron-sized pearl glaze ceramic is characterized by comprising a ceramic body, a toning ground coat layer and a dry particle layer, the toning ground coat layer is prepared from the following raw materials in parts by weight: 15 to 25 parts of quartz, 20 to 30 parts of feldspar, 5 to 10 parts of kaolin, 3 to 8 parts of calcined zinc oxide, 5 to 10 parts of calcium carbonate, 8 to 15 parts of barium carbonate, 8 to 15 parts of zirconium silicate, 0.05 to 0.5 part of toning metal oxide and 1 to 3 parts of functional additive; the dry particle layer is prepared from the following raw materials in parts by weight: 30 to 40 parts of quartz sand, 10 to 15 parts of borax, 5 to 8 parts of sodium carbonate, 3 to 6 parts of lithium carbonate, 10 to 18 parts of Bi2O3, 10 to 18 parts of TiO2, 0.5 to 2 parts of rare earth oxide and 0.5 to 2 parts of nucleating agent. The prepared ceramic shows soft and layered pearl luster under light rays of different angles, and the physical performance is greatly improved.

The invention relates to the technical field of dielectric ceramic powder preparation processes, in particular to a multilayer ceramic capacitor, high-activity nano barium titanate powder for the multilayer ceramic capacitor and a preparation method of the high-activity nano barium titanate powder, and the method comprises the following steps: (1) reacting soluble barium salt with a precipitator to obtain barium carbonate precursor particles with high specific surface area; (2) uniformly coating the surfaces of the barium carbonate precursor particles with nano titanium dioxide particles by using a supercritical fluid flash evaporation technology to form a composite precursor; and (3) carrying out solid-phase synthesis reaction on the composite precursor, and sintering to obtain the nano barium titanate powder. Through the synergistic effect of two means of high-activity precursor preparation and nanoscale uniform coating, the composite precursor with extremely high specific surface area, surface energy and microcosmic uniformity is prepared, the thermal sintering temperature is effectively reduced, abnormal growth of crystal grains and lattice distortion are restrained, and the preparation method has the advantages that the preparation process is simple, and the preparation cost is low. The tetragonality of the nano barium titanate powder is obviously improved.

The invention relates to chemical-corrosion-resistant full-polished glaze as well as a preparation method and application thereof, and belongs to the technical field of ceramic production and manufacturing. The chemical-corrosion-resistant fully-polished glaze comprises the following mineral components in percentage by mass: 5%-10% of quartz, 5%-10% of kaolin, 1%-10% of calcined talc, 20%-25% of wollastonite, 10%-20% of calcined kaolin, 1%-5% of calcined alumina, 1%-5% of calcined zinc oxide, 1%-5% of barium carbonate, 1%-3% of titanium oxide, 1%-5% of zirconium silicate and 10%-20% of boron frit. By specially designing a full-polishing glaze formula of the ceramic tile, adjusting the firing temperature and discharging or reducing defects such as air holes in a glaze layer as much as possible, the glaze layer forms a stable inert surface, and chemical substances cannot react with the glaze layer or only slightly react with the glaze layer, so that the transparency, integrity and glossiness of the surface are kept.

The present application relates to the technical field of dielectric ceramic powder preparation, and particularly relates to a multilayer ceramic capacitor, a high-activity nano-barium titanate powder for the multilayer ceramic capacitor and a preparation method of the high-activity nano-barium titanate powder, the method comprising the following steps: (1) reacting a soluble barium salt with a precipitator to obtain barium carbonate precursor particles with high specific surface area; (2) uniformly coating nano-titanium dioxide particles on the surface of the barium carbonate precursor particles by using a supercritical fluid flash technology to form a composite precursor; and (3) performing a solid-phase synthesis reaction on the composite precursor and sintering to obtain nano-barium titanate powder. The present application, through the synergistic effect of the two means of "high-activity precursor preparation" and "nano-level uniform coating", prepares a composite precursor with extremely high specific surface area, surface energy and micro-uniformity, effectively reduces the heat sintering temperature, suppresses abnormal grain growth and lattice distortion, and significantly improves the tetragonality of the nano-barium titanate powder.

The invention discloses a sintering aid coated lead barium titanate-based thermal sensitive ceramic and a preparation method thereof, and relates to the technical field of material science, the raw materials of the core layer comprise barium carbonate, lead tetraoxide, calcium carbonate, strontium carbonate, zirconium oxide, tin oxide, titanium dioxide, manganese oxide and niobium pentoxide; the raw materials of the shell layer comprise silica sol, an aluminum compound, a calcium compound, a sodium compound, a potassium compound, a magnesium compound and boric acid; the preparation method comprises the following steps: mixing the raw materials of the core layer, calcining at 950-1050 DEG C, adding a deionized water solution of the raw materials of the shell layer, mixing, calcining at 1000-1100 DEG C, adding a polyvinyl alcohol water solution, granulating, forming, degumming and sintering to obtain the sintering aid coated lead barium titanate based thermal sensitive ceramic. According to the invention, the sintering aid is used for coating the lead barium titanate-based thermal sensitive ceramic, so that the densification of the ceramic is promoted while grains are refined, and the ceramic has high voltage resistance and excellent PTC (Positive Temperature Coefficient) effect.

The invention belongs to the technical field of preparation of barium titanate, and particularly relates to a preparation method of a defect-regulating barium titanate composite material, which comprises the following preparation steps: S1, adding a proper amount of barium carbonate, titanium dioxide, nickel oxide and dopant mixed powder into a ball milling tank for ball milling to obtain initial barium titanate composite particles; s2, dispersing the initial barium titanate composite particles obtained in the step S1 into an aqueous solution of a growth inhibitor for reaction to form modified barium titanate composite powder; and S3, mixing the barium titanate composite powder obtained in the step S2 with an adhesive polyvinyl butyral, pressing into a biscuit, performing cold isostatic pressing, sintering, annealing in a nitrogen atmosphere, and performing heat preservation to obtain the defect-regulated barium titanate composite material.

The present invention discloses a wave absorbing patch for a 700MHz 5G base station in the P band, which belongs to the technical field of wave absorbing materials. The wave absorbing patch is made of a ternary magnetic composite absorber and rubber; wherein the ternary magnetic composite absorber includes secondary sintered ferrite, flaky carbonyl iron and flaky iron silicon aluminum; the secondary sintered ferrite includes ferric oxide, zinc oxide, cobalt oxide and barium carbonate. The present invention also provides a method for preparing a wave absorbing patch, comprising the following steps: S1, ferric oxide, zinc oxide, cobalt oxide and barium carbonate are proportioned, and secondary sintered ferrite is obtained by high-temperature solid phase secondary sintering; S2, secondary sintered ferrite, flaky carbonyl iron and flaky iron silicon aluminum are mixed in proportion by ball milling process to obtain a ternary magnetic composite absorber; S3, the ternary magnetic composite absorber and rubber are proportioned, and subjected to internal refining, open refining, sheeting and high-temperature flat plate vulcanization to obtain a wave absorbing patch.

The invention provides a method for determining boron element in iron ore, which comprises the following steps: weighing 0.2 g of sample, uniformly mixing with a flux, heating to red at 700-800 DEG C, cooling, adding sodium peroxide for secondary melting, dissolving in water, and transferring to a beaker; adding ethanol to boil, fixing the volume to 500mL, filtering and taking 100mL, adjusting the pH value, adding hydrogen peroxide to slightly boil, cooling, adding barium carbonate to boil, diluting and filtering, and taking 25mL for color development determination. According to the method, sodium carbonate and / or potassium carbonate and sodium peroxide are adopted to form a composite flux, an iron ore sample is completely decomposed through secondary melting and step-by-step dissolution, and the sample decomposition efficiency is improved; the method is stable in recovery rate, is superior to a conventional method in precision, can accurately measure the boron content in the iron ore, meets the technical requirements on boron element detection in the fields of ferrous metallurgy, geological exploration and the like, provides an efficient and reliable detection means for boron content analysis, and ensures the accuracy and reproducibility of a detection result.

The invention discloses a glaze with a shell luster effect, a shell pearlescent glazed tile and a preparation method thereof, and the glaze comprises the following raw material components in parts by weight: 14-24 parts of modified shell frit, 10-15 parts of albite, 9-16 parts of dolomite, 6-10 parts of kaolin, 6-9 parts of zinc oxide, 11-16 parts of strontium carbonate, 6-9 parts of limestone, 2-6 parts of barium carbonate and 15-25 parts of lithium feldspar. The modified shell frit is introduced and matched with other specific raw materials to prepare the glaze capable of presenting shell luster, so that a glass phase and a crystal phase with different refractive indexes are separated out in the firing process of the glaze, a shell-shaped iridescent and soft light effect is simulated, and a glaze surface has wear resistance, skid resistance and antifouling properties and has good physical properties.

The invention relates to the technical field of building ceramics, in particular to waxy antifouling matte glaze and a preparation method and application thereof.The waxy antifouling matte glaze is prepared from, by mass, 7-10 parts of kaolin, 6-15 parts of calcined kaolin, 4-8 parts of quartz, 20-30 parts of potassium feldspar, 5-15 parts of albite, 5-10 parts of wollastonite, 1-5 parts of zinc oxide, 5-10 parts of strontium carbonate, 5-12 parts of barium carbonate and 10-20 parts of crystalline frit; the crystalline frit is prepared from the following raw materials in parts by mass: 25 to 35 parts of kaolin, 3 to 8 parts of calcined aluminum oxide, 20 to 35 parts of calcite, 0.5 to 3 parts of dolomite, 5 to 10 parts of zinc oxide, 25 to 35 parts of potassium feldspar, 0.5 to 3 parts of barium carbonate and 1 to 5 parts of anorthite powder. The waxy antifouling matte glaze provided by the invention not only has antifouling performance, but also has high hardness and high wear resistance on the premise of having matte texture and waxy silky hand feeling, so as to overcome the defects in the prior art.

The invention discloses a high-pressure-resistant lead barium titanate-based thermal sensitive ceramic and a preparation method thereof, and belongs to the technical field of material science, a core layer of the high-pressure-resistant lead barium titanate-based thermal sensitive ceramic comprises the following raw materials in parts by mole: 2-5 parts of lead tetraoxide, 25-39 parts of barium carbonate, 30-45 parts of titanium dioxide, 0.03-0.3 part of manganese oxide and 0.2-0.4 part of niobium oxide; the shell layer comprises the following raw materials in parts by mole: 1-15 parts of a barium compound, 5-20 parts of a titanium compound, 0-3 parts of a strontium compound, 0-5 parts of a calcium compound, 0.5-5 parts of zirconium oxychloride and 1-8 parts of a tin compound; the preparation method comprises the following steps: mixing the raw materials of the core layer, calcining at 1000-1100 DEG C, adding a deionized water solution of the raw materials of the shell layer, mixing, spray-drying, calcining at 950-1050 DEG C, adding a polyvinyl alcohol water solution, granulating, forming, degumming and sintering. The ceramic prepared by the preparation method disclosed by the invention has high voltage-resistant characteristic and excellent PTC (Positive Temperature Coefficient) effect.

The invention belongs to the technical field of high-temperature-resistant containers, and provides a quartz crucible preparation method and a quartz crucible. The preparation method of the quartz crucible comprises the following steps: preparing the matrix; the base body is subjected to heating pretreatment; coating the inner wall of the substrate with a barium solution; sintering to form a barium silicate prefabricated layer on the inner wall of the substrate; and barium carbonate powder is scattered on the barium silicate prefabricated layer to form a barium silicate protective layer. According to the quartz crucible prepared by the quartz crucible preparation method provided by the invention, the barium silicate protective layer in the quartz crucible can effectively prevent a product to be prepared from corroding the quartz crucible.