Ash produced by many 
coal-fired utilities has little or no commercial value as a 
cement additive or as a component in building materials because of its chemical or 
mineralogical composition. This condition is especially common with ash materials produced by 
Fluidized Bed Combustion boilers (FBC) or Circulating 
Fluidized Bed Combustion boilers (CFBC) fired with 
bituminous coal or waste coals (gob) reclaimed from inactive 
coal mine sites. The present invention describes a novel process that converts otherwise low-value materials such as bottom and fly ashes produced by a FBC or CFBC boilers, for example, into materials that have desirable physical, chemical and mineralogical compositions that can be used as a valuable 
cement additive or component in building materials. The novel process closely integrates the boiler (steam generator) that produces the ash with a new high-temperature process, such as a 
kiln. The ash is mixed with limestone or other bulk materials to provide a feed for the 
kiln of the desired 
chemical composition. The mixture is treated at elevated temperatures in the 
kiln to produce a product, that in combination with further 
processing, exhibits desirable pozzolanic properties. Integrating boiler and kiln operations provides economic and environmental benefits. 
Waste heat produced by the kiln that would otherwise be released into the 
atmosphere is made available to the steam or 
turbine cycle, thus improving the overall boiler heat rate. Effluents and gases produced by the kiln may be efficiently treated by the boiler environmental control systems or independent environmental control systems. Novel production methods and feed materials will be claimed.