640 results about "Calcium aluminates" patented technology

The invention provides a concrete super-early-strength quick-hardening material, and relates to the field of building materials. The high-strength concrete comprises the following components in percentage by mass: 40%-50% of calcium aluminate, 30%-40% of gypsum, 8%-15% of high aluminum, 1%-3% of an additive, 3%-12% of an exciting agent and 1%-5% of an auxiliary material. According to the super-early-strength quick-hardening material provided by the invention, hour-level strength can be quickly and stably improved, and the strength increasing curve of each age is smooth and stable, so that the requirements of scenes such as road repair and tunnel construction on early strength can be met; it can be guaranteed that the 28-day compressive strength of the material breaks through 70 MPa, the later strength is kept stable, and the long-term safety of an engineering structure is guaranteed; the anti-seepage, anti-freezing and anti-erosion capabilities are realized in a complex environment, the service life of a project can be effectively prolonged, and the maintenance cost is reduced. In addition, the invention further provides a preparation method of the concrete super-early-strength and quick-hardening material, and the preparation method is used for preparing the super-early-strength and quick-hardening material provided by the invention.

The invention belongs to the field of modified self-repairing calcium aluminate cement 3D printing, and particularly relates to a phosphate modified self-repairing calcium aluminate cement 3D printing material and a preparation method thereof. The phosphate modified self-repairing calcium aluminate cement 3D printing material prepared by the invention is prepared from the following raw materials in parts by mass: 60 to 70 parts of calcium aluminate cement, 3 to 7 parts of silica fume, 2 to 4 parts of metakaolin, 0.5 to 3.5 parts of double-template modified calcium bentonite, 0.8 to 1.5 parts of amino modified sodium polyphosphate and 0.15 to 0.8 part of basalt fiber. The invention relates to a concrete anti-microbial agent, which is prepared from the following raw materials in parts by weight: 20-30 parts of water, 20-30 parts of water, 20-30 parts of water, 20-30 parts of nano calcium carbonate, 20-30 parts of nano calcium carbonate, 20-30 parts of magnesium phosphate cement coated bacteria-loaded porous microspheres, 20-30 parts of a polycarboxylate superplasticizer, 20-30 parts of an organic silicon defoaming agent and 25-35 parts of mixing water. The technical-economic cooperation requirement of building 3D printing under complex working conditions is met, and various indexes of phosphate modified calcium aluminate cement applied to the 3D printing technology are met.

The invention discloses fiber reinforced concrete for bridge deck pavement and a preparation method thereof, and belongs to the technical field of concrete. The fiber reinforced concrete is prepared from the following raw materials: Portland cement, modified basalt fiber, a slow-release mineralizer, a stress-oriented dispersing aid and the like. The modified basalt fiber is a basalt fiber which is subjected to amino silanization through a silane coupling agent KH-550 and then is catalytically grafted with ethylenediamine tetraacetic acid and hydroxyethyl methylacrylate through DCC (dicyclohexylcarbodiimide); the slow-release mineralizer comprises calcium sulphoaluminate and silicon-based coated nano calcium sulfate; the silicon-based coated nano calcium sulfate is core-shell structure powder formed by coating a nano calcium sulfate core material with a silicon dioxide shell layer; the concrete is strong in interface bonding, excellent in dynamic fatigue resistance, good in durability and stable in volume, and the problem that the mechanical property, the durability and the dynamic anti-interference capability of the concrete cannot be considered at the same time is solved.

The invention provides a concrete composite expanding agent and a preparation method thereof, and belongs to the field of concrete admixtures. The concrete composite expanding agent comprises modified phosphogypsum, fly ash, bauxite, a modified oxide and an auxiliary agent, and is obtained by uniformly mixing the modified phosphogypsum, the fly ash, the bauxite, the modified oxide and the auxiliary agent which have different specific surface areas. According to the composite expanding agent, the modified ardealite and the fly ash synergistically provide an early-stage expansion source, early-stage shrinkage of concrete is compensated through calcium sulphoaluminate hydration products, meanwhile, modified magnesium oxide serves as a later-stage expansion source, magnesium hydroxide is generated through slow hydration, and long-term expansion compensation is achieved; the device has the advantages of good strength, compensation capability and the like; a large amount of industrial waste residues such as ardealite and fly ash are utilized, high-added-value utilization of the industrial waste residues is achieved, and remarkable economic benefits are achieved.

The invention relates to the technical field of concrete waterproofing agents, in particular to a high-efficiency concrete anti-crack waterproofing agent and a preparation method thereof, and the high-efficiency concrete anti-crack waterproofing agent is prepared from the following raw materials in parts by weight: a calcium sulphoaluminate expanding agent; light burning of magnesium oxide; re-burning the magnesium oxide; nano-scale silicon dioxide; metakaolin; polypropylene fibers; basalt fibers; styrene-acrylic emulsion; a silane emulsion; silica fume; hydroxypropyl methyl cellulose; and a polycarboxylic acid water reducer compatilizer. According to the high-efficiency concrete anti-crack waterproof agent disclosed by the invention, the nano-silica, the metakaolin and the styrene-acrylic emulsion synergistically block nano-to-macroscopic multi-stage pores, so that double waterproofing of physical filling and chemical film forming is realized; the polypropylene and the basalt fiber are subjected to ultrasonic dispersion and interface combination optimization to form a three-dimensional anti-crack network, the component uniformity and the functional stability are ensured through precise proportioning, graded mixing and directional granulation, meanwhile, the waterproof agent is compatible with industrial production fluctuation, large-scale application reliability is ensured, and the problems that a traditional waterproof agent is single in function and insufficient in durability are solved.

The invention discloses multi-source composite expansion super-early-strength concrete and a preparation method thereof. The concrete comprises a cementing material, aggregate, a water reducing agent, water and a multi-source composite expansion system. The expansion system is composed of a plastic expansion agent, a calcium sulphoaluminate early expansion source, a magnesium oxide delayed expansion source and an internal curing material. Through precise component design and function time sequence matching, a cooperative compensation network covering the whole life cycle of the concrete is constructed, a plastic expanding agent inhibits plastic shrinkage, calcium sulphoaluminate compensates early-stage self-shrinkage, magnesium oxide resists medium-and-long-term drying shrinkage, an internal curing material provides continuous moisture guarantee for the above process, and the overall performance of the concrete is improved. And the efficiency of each expansion source is excited and coupled. According to the invention, seamless and accurate shrinkage compensation from a plastic stage to a service later stage can be realized on the premise of ensuring the super early strength characteristic of the concrete, the technical problem that the super early strength concrete is easy to crack due to severe shrinkage is fundamentally solved, and the volume stability and durability of the structure are remarkably improved.

The invention relates to the technical field of refractory materials, in particular to a waste magnesia-calcium brick-containing refractory material and a preparation method thereof, and the waste magnesia-calcium brick-containing refractory material comprises the following components: composite aggregate, calcium aluminate cement, urea resin-aluminum dihydrogen phosphate, active alpha-Al2O3 micro powder, silica micro powder and sodium tripolyphosphate. In the room-temperature spraying maintenance and low-temperature working stage, hydration of free CaO in the waste magnesia-calcium bricks and erosion of OH <-> are prevented through the hydrophobic effect of fluorinated polyphosphazene and modified zirconium oxide sol, and the compatibility and wettability of the composite aggregate and cement paste are improved through carboxylic acid groups of carboxyethyl silanetriol and polyethylene glycol monomethyl ether. According to the present invention, with the temperature rising, the aluminum dihydrogen phosphate forms the viscous liquid phase to wrap the aggregate so as to provide the temporary protection, the temperature continues to rise, the zirconium oxide and the nanometer Al2O3 react with the CaO and the MgO to generate the CaZrO3 and the MgAl2O3, the aluminum dihydrogen phosphate reacts with the nanometer Al2O3 in the system to generate the AlPO4, and the CaZrO3, the MgAl2O3 and the AlPO4 form the multi-phase fire-resistant structure so as to further improve the fire resistance of the fire-resistant material;

The invention relates to the technical field of refractory materials, and discloses a rotary kiln lining refractory material and a preparation method thereof, the raw materials comprise mullite, boron carbide, calcium hexaluminate, silicon carbide, silica powder, alpha-alumina micro powder, coating powder, modified refractory fiber, and a binder. The mullite and the boron carbide are selected as base materials and have excellent acid corrosion resistance, the titanium dioxide and the aluminum oxide are used for treating the refractory fibers, so that a compact enrichment layer is formed, low-temperature sintering is promoted by adding the yttrium oxide, the titanium dioxide is introduced into the refractory fibers, and the corrosion resistance of the refractory fibers is improved. And micropores in the fiber surface can be blocked, so that the porosity of the refractory material is reduced, and the diffusion path of acid steam is prolonged. The refractory material provided by the invention has excellent high-temperature stability and corrosion resistance.

The invention discloses a permeable laminated grid ecological bank protection material suitable for improvement of a dredged soil green material and a preparation method of the permeable laminated grid ecological bank protection material. The preparation method comprises the following steps that S1, a dredged soil green improver and dredged soil are evenly mixed in a dry mode, and homogeneous slurry is formed after stirring; s2, injecting the homogenized slurry into a mold, and pressing the homogenized slurry into hollow laminated grid units through a hydraulic forming machine; and S3, the permeable laminated grid units are naturally cured, and the permeable laminated grid ecological bank protection material suitable for improvement of the dredged soil green materials is formed. According to the invention, the dredged soil is taken as a matrix, and the mechanical property and ecological compatibility of the dredged soil are remarkably improved by adding the composite modifier composed of 11 components such as the steel slag micro powder, the red mud activator, the calcium sulphoaluminate expanding agent and the active magnesium oxide and combining the design of the three-layer permeable laminated grid structure.

The invention belongs to the technical field of building materials, and particularly relates to a micro-expansion anti-cracking waterproof composite deep groove filler and a preparation method thereof. The micro-bulking anti-cracking waterproof composite deep groove filler provided by the invention comprises cement, gypsum, mineral powder, nano silicon oxide, coarse aggregate, fine aggregate, modified fibers, an expanding agent, a polycarboxylate superplasticizer and water. According to the invention, polyacrylamide, calcium sulphoaluminate and magnesium oxide are adopted to jointly form an expanding agent, and early-stage-late-stage full-period shrinkage compensation is jointly formed in a concrete hydration process, so that the density of the concrete is effectively improved, and the waterproof performance of the concrete is further improved; according to the invention, sodium dodecyl benzene sulfonate and propylene glycol block polyether are adopted to carry out compound modification on graphene oxide, and gamma-aminopropyltriethoxysilane is connected to the surface of basalt fiber, so that the bonding strength of basalt fiber and a cement matrix and the compactness of the cement matrix are improved, and the waterproof and anti-cracking properties of concrete are further improved.

The invention discloses anti-cracking concrete and a preparation method thereof, and the anti-cracking concrete is prepared from the following raw materials in parts by weight: 400-450 parts of cement, 600-700 parts of fine aggregate, 900-1000 parts of gravel, 70-80 parts of a composite additive, 30-40 parts of modified fiber, 4-5 parts of a water reducing agent and 160-180 parts of water, the composite additive is prepared from fly ash, modified sepiolite, calcium sulphoaluminate and an air entraining agent; the modified sepiolite is obtained by taking sepiolite as a raw material, pretreating the sepiolite through a silane coupling agent and then sequentially reacting the pretreated sepiolite with sulfanilamide and dodecyl chloride. According to the invention, through the synergistic effect of the composite additive and the modified fiber, the comprehensive improvement of the crack resistance and mechanical strength of the concrete is realized, in the composite additive, the moderate expansion of calcium sulphoaluminate compensates the early shrinkage stress, the microbubble system formed by the air entraining agent relieves the stress concentration, and the dispersion effect of the polycarboxylate superplasticizer is matched, so that the crack resistance and mechanical strength of the concrete are improved. The hardened body forms a compact and uniform microstructure, and the tensile strength of the concrete is improved.

The invention relates to the field of furnace lining materials, in particular to a rapid repairing material for a tapping hole and a furnace lining of an intermediate frequency furnace. The rapid repairing material comprises the following components in parts by weight: 50-70 parts of tabular corundum, 10-20 parts of fused magnesite, 8-15 parts of alumina micro powder, 3-8 parts of nano zirconia, 5-12 parts of silicon carbide, 10-15 parts of silica sol and 2-5 parts of a reinforcing agent. Wherein the reinforcing agent is titanium calcium aluminate coated with chromium nickel boride. The tabular corundum is mainly used as an integral framework; the fused magnesite is matched with the alumina micro powder to form magnesium aluminate spinel with a high melting point; the nano zirconium oxide can fill pores and is excellent in toughness; the silicon carbide has the advantages of high hardness, high thermal conductivity and high melting point; the reinforcing agent is titanium calcium aluminate coated with chromium nickel boride, although the adding amount is small, the high-temperature strength, toughness and thermal shock resistance of the repairing material can be remarkably improved, and especially the long-term corrosion resistance can be remarkably improved.

The invention discloses a super-early-strength shrinkage-free high-crack-resistance tunnel spraying repair material in the technical field of civil engineering materials, which comprises the following raw materials in percentage by mass: 35-45% of sulphoaluminate cement; 8%-12% of a superfine early strength admixture; 2%-3% of a calcium sulphoaluminate expanding agent; 1%-2% of a magnesium oxide-based expanding agent; 1-2% of a calcium-magnesium composite expanding agent; 10%-15% of hollow glass beads; 1.5%-2.5% of copper plated steel fiber; 0.1%-0.3% of polypropylene fiber; 25%-30% of graded quartz sand; 0.5%-1.0% of a polycarboxylic acid water reducing agent; 3%-5% of an alkali-free liquid accelerator; 0.3%-0.8% of a thixotropic agent; and 0.1%-0.3% of a thickening time control agent. According to the method, a multi-scale performance cooperative regulation system is innovatively constructed. Through accurate control of the hydration process of a gel system, a shrinkage stress multi-stage compensation mechanism and systematic integration of a fiber-matrix interface strengthening technology, the mutual restriction relationship among early strength development, volume stability and crack resistance of a traditional material is broken through.

The invention provides a mixed type shield synchronous grouting material and a grouting process, and relates to the technical field of building materials, the grouting material is composed of fast hydration Portland cement, activated aluminosilicate minerals, nanometer silicon powder, bentonite, a reversible thixotropic polymer, a delayed hydration agent, coated calcium aluminate fast setting powder and a coated silicate gel precursor. The early-stage reaction is inhibited by delaying hydration, and a controllable solidification sequence of slurry from a flowable stage, a rearrangement structure stage to a rapid solidification stage is realized by breaking a membrane under the action of temperature or pressure gradient. In the process, by monitoring the conductivity, the concentration of Ca < 2 + > / Mg < 2 + > and the temperature in real time, the adding amount of an additive and grouting parameters are automatically adjusted, so that the stable diffusivity of the material is kept and the curing speed is accelerated under different stratum conditions. The solidified body forms a C-S-H, C-A-S-H and N-A-S-H gel interpenetrating network, the permeability coefficient is low, the water dispersion resistance is high, and the shield grouting quality and the tunnel structure safety can be remarkably improved.

The invention discloses light building corrosion-resistant fiber concrete and a production method thereof, the light building corrosion-resistant fiber concrete comprises the following raw materials by mass: 300-400 parts of high belite sulphoaluminate cement, 10-20 parts of modified corrosion-resistant fiber, 50-80 parts of a mineral admixture, 800-1000 parts of a coarse aggregate, 600-700 parts of a fine aggregate, 5-10 parts of a composite admixture, and 120-150 parts of water; wherein the mineral composition of the high belite sulphoaluminate cement is as follows: 18 to 25 percent of C4AF, 15 to 20 percent of anhydrous calcium sulphoaluminate (C4A3S), 45 to 55 percent of belite (C2S) and less than or equal to 10 percent of other minerals. By optimizing the ratio of C4AF to anhydrous calcium sulphoaluminate in the high belite sulphoaluminate cement and combining with a special calcining process, the contradiction of low early strength caused by increase of the content of C4AF is solved, and meanwhile, a foundation is laid for long-term corrosion resistance; and by adopting a silane coupling agent-nano silicon dioxide composite modification technology, the limitation of limited single modification effect is solved, and the synchronous improvement of the corrosion resistance of the fiber and the interface bonding strength is realized.

The invention discloses an anti-erosion Al2O3-SiC-C slag runner castable containing pyrophyllite and a preparation method of the anti-erosion Al2O3-SiC-C slag runner castable, and belongs to the technical field of refractory materials. The Al2O3-SiC-C slag trough castable is mainly prepared from the following raw materials in percentage by mass: 30 to 45 percent of high-alumina clinker, 20 to 35 percent of pyrophyllite, 8 to 15 percent of silicon carbide, 5 to 10 percent of kyanite, 5 to 10 percent of graphite electrode powder, 3 to 6 percent of active Al2O3 micro powder, 2 to 4 percent of silicon micro powder, 1.5 to 2.5 percent of antioxidant, 3 to 5 percent of pure calcium aluminate cement and 1.5 to 2.5 percent of asphalt. In addition, explosion-proof fibers accounting for 0.03-0.15% of the total weight of all the raw materials and a water reducing agent accounting for 0.05-0.15% of the total weight of all the raw materials are added. The anti-erosion Al2O3-SiC-C slag runner castable is prepared by mixing the weighed raw materials uniformly and then obtaining the anti-erosion Al2O3-SiC-C slag runner castable. The Al2O3-SiC-C slag runner castable prepared by the method can completely meet the requirements of the use performance of the Al2O3-SiC-C slag runner castable, and the Al2O3-SiC-C slag runner castable can be well applied to a blast furnace casting house; meanwhile, the cost is reduced, and remarkable social benefits and economic benefits are achieved.

The invention discloses anti-crack and anti-alpine concrete and a preparation method thereof, and relates to the technical field of concrete.The anti-crack and anti-alpine concrete is prepared from, by mass, 300-500 parts of low-heat Portland cement, 50-100 parts of carbon sequestration composite superfine powder and 10-20 parts of nano calcium carbonate; the magnesium oxide is calcined at the temperature of 500 to 600 DEG C, is compounded with the calcium sulphoaluminate, and is modified by a silane coupling agent; the phase change microcapsule is formed by packaging paraffin in a silicon dioxide shell layer, and the phase change temperature ranges from-30 DEG C to 10 DEG C; the microbial self-repairing capsule is characterized in that bacillus pasteurii is coated in a sodium alginate-montmorillonite composite carrier; according to the invention, the multi-dimensional performance breakthrough of the high-cold concrete is realized through gradient expanding agent compounding, fiber synergistic enhancement, phase change microcapsule temperature control and microbial self-repairing technologies. The drying shrinkage is reduced to 1.2 * 10 <-4 > by compounding magnesium oxide / calcium sulphoaluminate, the crack propagation is inhibited by a fiber network, and the initial crack threshold value is less than 0.15 mm.

The present invention relates to a method for co - processing and resource utilization of overhaul slag, fly ash, and desulfurized gypsum. The method comprises the following steps: Step 1) dehydrate and then dry the desulfurized gypsum, add calcium carbonate to the dried desulfurized gypsum, and collect SO3 gas; Step 2) carry out an autoclave reaction on the SO3 gas obtained in Step 1, water, and fly ash. After solid - liquid separation, silicon dioxide and an aluminum sulfate solution are obtained; Step 3) crush and ball - mill the overhaul slag, and carry out first - stage roasting with a peroxide at high temperature to obtain clinker 1; leach out sodium fluoride from clinker 1 by water immersion, and then add it to the aluminum sulfate for second - stage roasting to obtain clinker 2; Step 4) mix clinker 2 with water for leaching to obtain a filtrate and a filter residue; Step 5) calcine calcium oxide and the filter residue to obtain calcium aluminate. The beneficial effect of the present invention aims to synergistically utilize the sodium, aluminum, fluorine, and lithium elements, the aluminum and silicon elements of fly ash, and the calcium element in desulfurized gypsum to achieve the purpose of resource conversion.

The present invention relates to the technical field of inorganic multi-color coatings, and specifically relates to a preparation method and apparatus for an inorganic multi-color coating, and a use. The preparation method comprises the following raw materials: base paint: water, cellulose, a defoaming agent, a dispersing agent, a wetting agent, a luminescent material, an inorganic hybrid emulsion, an odorless pH regulator, and a bactericide; granulation liquid: water, a bactericide, xanthan gum, protective colloid powder, an odorless pH regulator, nanocellulose, and a defoaming agent; and a continuous phase emulsion: an inorganic hybrid emulsion, a bactericide, inorganic gel, deionized water, an odorless pH regulator, a thickening agent, and a defoaming agent. In the present invention, a mixture of CaAl2O4 calcium aluminate and BaAlO4 barium aluminate is added to serve as a luminescent material, the luminescent material can absorb and store solar energy by means of a specific mode when exposed to sunlight during the daytime, and at night, the internally stored energy is converted into optical radiation to be released, thereby realizing a light-emitting effect and realizing the luminous function of the coating.

The present invention relates to the technical field of supersulfate cement, and specifically discloses a calcium fluoroaluminate-modified high-stability supersulfate cement and its application. The raw materials of the supersulfate cement include the following components: 70-80 parts by weight of mineral powder, 10-15 parts by weight of gypsum, 5-10 parts by weight of calcium fluoroaluminate, and 1-2 parts by weight of modified diatomaceous earth. The modified diatomaceous earth is porous diatomaceous earth microspheres loaded with L-aspartic acid. The present invention utilizes the synergistic effect of the calcium fluoroaluminate and the modified diatomaceous earth to not only improve the early strength of the supersulfate cement, but also effectively improve the chemical stability of the hydration product ettringite (AFt), thereby improving the carbonation resistance of the supersulfate cement and alleviating the problem of long-term strength shrinkage.

The invention discloses a solid-waste-based low-calcium clinker prepared from industrial solid wastes at low temperature and a method, which comprises the following steps: grinding a calcium raw material, a siliceous raw material, an aluminum correction raw material, an iron correction raw material and gypsum as raw materials, and fully mixing in proportion to obtain a homogeneous mixed raw material; calcining the mixed raw material at low temperature, quickly cooling after calcining, and grinding to obtain solid waste-based low-calcium clinker; the mineral phase of the cement clinker comprises 45-50% of calcium sulphosilicate (C5S2), 25-35% of calcium sulphoaluminate (C4A3), 10-15% of an iron phase (C6AF2) and the balance of unreacted raw materials and calcium aluminate in different forms. The CaO content required by the clinker prepared by the method disclosed by the invention is 45-48% and is about 17-20% lower than the CaO content (more than 65%) in ordinary Portland cement clinker. Finally, the carbon emission generated by limestone decomposition is significantly reduced. The low-calcium cement clinker prepared by the invention has the advantages of good burnability, low firing temperature, good grindability and excellent early compressive strength.

The present invention belongs to the technical field of refractory materials, and particularly relates to a cover brick for an electrofused zirconium corundum brick furnace and a preparation method thereof. Based on the total mass fraction of 100 parts of high-purity dense tabular corundum powder, alumina granulated powder and high-purity calcium aluminate cement, it is composed of the following raw materials in parts by weight: corundum powder with a particle size of 10 mm < particle size ≤ 20 mm, 10 - 20 parts, corundum powder with a particle size of 6 mm < particle size ≤ 10 mm, 10 - 20 parts, corundum powder with a particle size of 3 mm < particle size ≤ 6 mm, 5 - 15 parts, corundum powder with a particle size of 1 mm < particle size ≤ 3 mm, 10 - 26 parts, corundum powder with a particle size of 0.1 mm < particle size ≤ 1 mm, 16 - 28 parts, corundum powder with a particle size of 2000 mesh < particle size ≤ 325 mesh, 5 - 10 parts; alumina granulated powder, 5 - 15 parts; high-purity calcium aluminate cement, 3 - 10 parts; water reducing agent, 1 part. The present invention has good alkali erosion resistance, high strength, good heat shock resistance, long service life, large spalling size and little pollution to the product.

The invention relates to the field of solid waste co-processing and utilization, and particularly discloses complex-phase gypsum-based self-leveling mortar and a preparation method thereof. The mortar comprises the following raw materials in parts by mass: 75-95 parts of complex-phase gypsum, 3-25 parts of an auxiliary cementing material and 0.5-2.5 parts of an auxiliary mixture, the complex-phase gypsum comprises semi-hydrated gypsum, dihydrate gypsum and anhydrous gypsum; the auxiliary gelling material is a mixed compound material of ordinary Portland cement, aluminate cement, a calcium sulphoaluminate cementing material and sulphoaluminate cement; the additive mixture comprises one or more of a retarder, a water-retaining agent, a suspension / stabilizer, a water reducing agent, a flow promoter, a defoaming agent, a water repellent and an exciting agent. The gypsum-based self-leveling mortar prepared by the invention integrates the advantages of single semi-hydrated gypsum and single anhydrous gypsum, realizes the characteristics of high early strength and high later strength, and has the advantages of high strength, good wear resistance and low cost.

The invention relates to belite sulphoaluminate cement, the mass ratio of belite sulphoaluminate cement clinker to gypsum in the cement is (93-100): (0.5-7), the doping amount of gypsum is small, calcium sulphoaluminate can be promoted to be hydrated to generate more alumina gel, the alumina gel and dicalcium silicate generate hydrated calcium aluminosilicate, and the calcium aluminosilicate and dicalcium silicate are mixed to generate calcium aluminosilicate. Meanwhile, calcium sulphoaluminate is promoted to be hydrated to generate less ettringite and part of monosulfur hydrated calcium sulphoaluminate, and the early strength and the later strength of the cement are remarkably improved; the invention further relates to a low-temperature preparation method of the belite sulphoaluminate cement, the calcination temperature of the raw material is 1120-1200 DEG C and is lower than the calcination temperature in the prior art, and the preparation energy consumption of the cement clinker is reduced; according to the present invention, the early strength of the cement prepared through the calcination at the temperature of the present invention develops rapidly, the later strength of the cement slurry does not shrink with the increase of the hydration age, and the cement slurry still presents the stable increase trend, and the calcination temperature can increase the crystal defect of the calcium sulphoaluminate so as to easily provide the hydration activity of the calcium sulphoaluminate.

The invention relates to the technical field of mine filling materials, in particular to a composite filling cementing material and a preparation method thereof, and the composite filling cementing material comprises the following components: oil shale slag, ironmaking slag, clay mineral slag, Portland cement, a composite activator and a polycarboxylate superplasticizer. The composite activator comprises the following components: water glass, sodium carbonate, metakaolin, anhydrous sodium sulfate, calcium sulphoaluminate, dolomite, silica fume, potassium feldspar and an excitation accelerator. The gelling part is completely composed of various industrial wastes, the materials are convenient to obtain, the manufacturing cost is low, the composite exciting agent can effectively excite the potential activity of the oil shale residues, the ironmaking slag and the clay mineral residues and promote the hydration reaction of the oil shale residues, the ironmaking slag and the clay mineral residues, and the prepared composite filling gelling material has good moisture resistance and good durability.

The invention relates to an alkali-activated solid waste cementing repair material and a preparation method thereof, and belongs to the technical field of solid waste resource utilization and building materials. The repairing material is prepared from the following raw materials in parts by weight: 30 parts of fly ash, 70 parts of blast furnace slag, 40 parts of machine-made sand, 45-50 parts of water, 7-13 parts of an exciting agent, 1-2 parts of sodium tetraborate, 1-2 parts of calcium oxide, 1-2 parts of magnesium oxide, 1-2 parts of calcium sulphoaluminate, 0.5 part of aluminum oxide, 0.2 part of aluminum potassium sulfate, 0.2 part of aluminum powder, 0.2 part of alunite and 1 part of polyethylene glycol. By optimizing the modulus of the exciting agent, the alkali content, the water-binder ratio and the admixture ratio, the material has the shrinkage-compensating and micro-expansion characteristics, the compressive strength of the material in one day reaches 25-30 MPa, the compressive strength in three days reaches 30-35 MPa, the compressive strength in seven days reaches 35-40 MPa, the compressive strength in 28 days reaches 45-50 MPa, the initial fluidity and the 30min fluidity meet the standard requirements, and the expansion rate is 0.1%. The concrete is completely prepared from industrial solid wastes, does not contain cement clinker, has excellent volume stability and durability, is suitable for repairing roads, bridges and building structures, and is particularly suitable for severe environments such as high humidity, salt mist, freeze thawing and the like.

The present invention provides a VD furnace cover castable lining and a preparation method thereof, which belongs to the technical field of high-temperature refractory materials, comprising the steps of: mixing an emulsion of hydrogenated silicone oil, aminopropyltriethoxysilane, and pearl sand, heating and soaking, and drying to obtain modified pearl sand; mixing graphite, acetic acid, tetrabutyl titanate, and nano silicon powder, dropping an ethanol aqueous solution, adjusting the pH value to acidic, aging, drying, heating at a high temperature under an inert gas environment, and cooling to obtain TiC-Ti3SiC2 composite coating graphite; mixing brown corundum, silicon carbide, α-Al2O3 powder, calcium aluminate cement, TiC-Ti3SiC2 composite coating graphite, and modified pearl sand, drying, adding distilled water, stirring, putting into a mold, casting and molding, standing, taking out, drying, spraying silicon powder on the surface, and performing heat treatment under a nitrogen atmosphere to obtain a VD furnace cover castable lining. The present invention can improve the thermal insulation performance of the VD furnace cover while improving the thermal shock stability of the VD furnace cover castable lining.

The invention discloses an admixture for building formwork concrete, and belongs to the technical field of concrete materials. The admixture for the building formwork concrete, disclosed by the invention, comprises the following components in parts by weight: 65-70 parts of chitosan modified metakaolin; 10 to 15 parts of microencapsulated latex powder; 5 to 10 parts of calcium sulphoaluminate clinker; and 3-5 parts of modified polypropylene chopped fiber. Through reasonable proportioning of the components, the synergistic effect of the different components is brought into full play, and the invention aims to provide the additive for the building formwork concrete, which can significantly improve the thixotropic property, the interface bonding force and the crack resistance of the building formwork concrete and effectively prevent the corrosion of a steel formwork at the same time. The method is suitable for building formwork concrete engineering of a complex grid structure and has remarkable application value.

The invention discloses a grouting material suitable for rapid plugging of a water-rich stratum as well as a preparation method and application of the grouting material, and belongs to the technical field of grouting materials. The preparation raw materials comprise a component A and a component B, the component A comprises the following components in parts by mass: 20-80 parts of cement; 10-50 parts of a fly ash extract; 20 to 60 parts of water; the concrete admixture is prepared from the following components in parts by weight: 0.01 to 1 part of polycarboxylate superplasticizer, 0.025 to 0.05 part of polyacrylamide, 0.1 to 0.6 part of hydroxypropyl methyl cellulose, 0.5 to 1 part of disodium hydrogen phosphate and 1.5 to 4.5 parts of calcium metaaluminate. The component B is water glass, and the volume ratio of the component A to the component B is (1-5): 1. The grouting material provided by the invention has the properties of early strength, rapid setting, adjustable setting time, good fluidity, high flowing water retention rate and the like, and can meet the rapid plugging requirements of grouting of underground engineering such as tunnels, coal mines and the like.

The invention discloses an enhanced high-temperature wear-resistant refractory castable. Comprising the following raw materials in parts by weight: 84.5 to 93.6 parts of high bauxite, 21.4 to 25.3 parts of andalusite, 32.5 to 37.8 parts of silicon oxide micro powder, 23.8 to 26.2 parts of silicon nitride micro powder, 6.8 to 9.2 parts of aluminum triphosphate, 6.3 to 10.5 parts of aluminum oxide micro powder, 1.5 to 3.2 parts of attapulgite clay, 11.5 to 22.4 parts of calcium aluminate cement, 15.6 to 18.4 parts of modified short-cut basalt fiber, 5.7 to 6.5 parts of a water reducing agent and 1.5 to 3.2 parts of silica sol. The invention also discloses a preparation method of the enhanced high-temperature wear-resistant refractory castable. The high bauxite and the andalusite are combined as the aggregate, the weight and the heat conductivity of the castable are reduced, the strength of the castable is improved, the modified chopped basalt fiber has the advantages of light volume weight, high temperature resistance, good heat stability, low heat conductivity, small heat capacity, good mechanical vibration resistance, small thermal expansion and good heat insulation performance, and the compactness of the castable is further enhanced.