This invention discloses a preform for the hot top of a crystallizer specifically for semi-
continuous casting of aluminum-
lithium alloys and its manufacturing method. Addressing the problems of severe interfacial reactions between existing
refractory materials and molten aluminum-
lithium alloys, resulting in poor forming quality of semi-
continuous casting ingots, this invention employs a gradient
composite structure design:
lithium aluminate is introduced into the working layer to thermodynamically suppress interfacial reactions by increasing the intrinsic lithium chemical sites; the
insulation layer contains β-lithium
nepheline and
lithium aluminate to improve the insulation performance and
thermal shock resistance of the hot top. Furthermore, by using a gradient distribution of
lithium compound concentrations and types, combined with a multi-stage
sintering process, the interlayer
bonding strength is improved. Results show that this invention not only significantly reduces the
interfacial reaction between the molten aluminum-lithium
alloy and the hot top during semi-
continuous casting, improving the forming quality of aluminum-lithium
alloy ingots, but also extends the service life of the preform.