The invention relates to high-intensity photocatalytic cement-based composite slurry. The high-intensity photocatalyst cement-based composite slurry comprises a photocatalyst composite body, cement, aggregate, an active mixture, a polymer additive, fibers, a water reducing agent and water, wherein the photocatalyst composite body comprises modified rare-earth elements and N co-doped TiO2, activated carbon and conductive fillers. According to the preparation method, the slurry is prepared through the raw materials and then treated by pouring and maintaining and molding with high humidity under a high temperature and other processes to form a face brick and an exterior wall cladding. The product detection result shows that the ultimate bending strength of the product reaches 25 to 30MPa, the ultimate compressive strength reaches 150 to 200MPa, the shock strength reaches 15 to 20kJ/m<2>, an absorption band of a photocatalyst is subjected to redshift to reach a 600nm visible region, the degradation rate for a 1mg/L rhodamine aqueous solution after 6 hours reaches 85 to 90%, and therefore, the product is high in mechanical strength and high in capacity of degrading pollutants with the visible light in a photocatalytic manner.