The invention provides a preparation method for an
acrylic acid microemulsion with a self-crosslinking core-shell structure, which sequentially comprises the following steps of: emulsifying a seed
microemulsion monomer in advance, preparing seed
microemulsion and core-shell part microemulsion, emulsifying a core part microemulsion
monomer in advance, and preparing the
acrylic acid microemulsion with the self-crosslinking core-shell structure. In the preparation method for the
acrylic acid microemulsion with the self-crosslinking core-shell structure, common self-crosslinking monomers are adopted for replacing expensive organo-
siloxane monomers and
fluoride-containing vinyl monomers, a
polymerization technology is used for improving the performance of the
emulsion, and therefore, the prepared acrylic acid microemulsion has low cost and can be widely used; the acrylic acid microemulsion with the self-crosslinking core-shell structure, prepared by the invention, has a soft-shell hard-core structure and a self-crosslinking characteristic; the average grain
diameter of the microemulsion is 60-100nm; and the acrylic acid microemulsion with the self-crosslinking core-shell structure has good nanometer effects and good
grinding performance when being used in aqueous woodware primers, and has advantages of good permeability and wettability to base materials, strong
adhesive force, compactness in
coating, good transparency, higher gloss and good smoothness.