The invention relates to a liquid double-reagent kit for measuring free light chains in serum or urine by a double-latex method. The kit provided by the invention comprises a reagent R1, a reagent R2 and a light chain antigen calibrator with known concentration, wherein the reagent R1 comprises a macromolecular accelerant, a preservative, a surface active agent, a reaction promoter, a stabilizer, an electrolyte and a buffer solution; R2 comprises two types of latex particles with different diameters, wherein the diameters of the latex particles are respectively in ranges from 40nm to 80nm and from 100nm to 200nm; the two types of latex particles are both cross linked with kappa-type or lambda-type anti-FLC (full-load current) polyclonal antibody, and the latex particles comprise the preservative, the surface active agent, the reaction promoter, the electrolyte, the stabilizer and the buffer solution; the light chain antigen calibrator with known concentration comprises the preservative, the electrolyte, the stabilizer, kappa-type or lambda-type FLC antigen and the buffer solution. The kit in the invention has the advantages that the specificity is strong, the sensitivity is high, the linear range is wide, the operation is simple, and the kit is suitable for various full automatic biochemical analyzers.