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1751 results about "Maleimide" patented technology

Maleimide is a chemical compound with the formula H₂C₂(CO)₂NH (see diagram). This unsaturated imide is an important building block in organic synthesis. The name is a contraction of maleic acid and imide, the -C(O)NHC(O)- functional group. Maleimides also describes a class of derivatives of the parent maleimide where the NH group is replaced with alkyl or aryl groups such as a methyl or phenyl, respectively. The substituent can also be a small molecule (such as biotin, a fluorescent dye, an oligosaccharide a nucleic acid), a reactive group, or a synthetic polymer such as polyethylene glycol. Human hemoglobin chemically modified with maleimide-polyethylene glycol is a blood substitute called MP4.

Flame-retardant ABS (Acrylonitrile Butadiene Styrene) composition and preparation method and application thereof

PendingCN121895709APolymer sciencePhosphate
The invention discloses a flame-retardant ABS (Acrylonitrile Butadiene Styrene) composition as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The flame-retardant ABS composition provided by the invention comprises the following components in parts by mass: 50-80 parts of ABS resin; 8 to 12 parts of styrene-acrylonitrile copolymer; 3 to 5 parts of styrene-acrylonitrile-maleic anhydride terpolymer; 2 to 6 parts of a fluorine-containing maleimide copolymer; 5 to 15 parts of graphite nanosheet modified high rubber powder; 12 to 18 parts of brominated flame retardant; 3-7 parts of a phosphorus-based flame retardant; 0.1-1 part of a processing aid; the phosphorus-based flame retardant is prepared from the following components in parts by mass: 80 to 95 parts of diethyl phosphinate; 0.3 to 3 parts of ethyl butyl phosphinate; 0.1 to 2 parts of ethyl phosphonate; and 5 to 20 parts of melamine polyphosphate. The flame-retardant ABS composition prepared by the invention is good in flame retardant property, good in welding strength and low in cost.
Owner:GUANGDONG XINDA ADVANCED MATERIALS TECH CO LTD +1

Targeted LNP delivery

Disclosed are lipid nanoparticle (LNP) delivery systems that specifically target T cells. The LNP delivery system comprises antibodies conjugated to the surface of the LNP, e.g., via maleimide chemistry, that target at least two T cell surface proteins, e.g., CD3 and CD28. The LNP delivery system can have a single population of LNP conjugated to either a bispecific antiCD3 / antiCD28 antibody, or two monospecific antiCD3 and antiCD28 antibodies, or two populations of LNP wherein each population comprises a monospecific antibody. The payload of the LNP delivery system can be, e.g., mRNA encoding chimeric antigen receptors (CAR), a linear DNA fragment or a plasmid encoding chimeric antigen receptors (CAR) or therapeutic proteins such as antibodies, components of a gene editing systems (e.g., CRISPR-Cas), small molecules, antibody-drug conjugates (ADC), and any combination thereof, either encapsulated in the LNP or attached to its surface (e.g., conjugated). Also provided are lipids, pharmaceutical compositions, kits, and methods of treatment.
Owner:MODEX THERAPEUTICS INC

CNT-based antistatic MPPE composite material and preparation method thereof

ActiveCN119708813AImideModified carbon
The invention discloses a CNT-based antistatic MPPE composite material and a preparation method thereof, the composite material comprises the following raw materials by weight: 40-50 parts of modified polyphenyl ether, 40-50 parts of modified polystyrene, 10-15 parts of modified carbon nanotubes and 1-1.5 parts of zinc oxide, the modified carbon nanotubes are added into the composite filler, and the modified carbon nanotubes have a good conductive effect, so that the antistatic performance of the composite material is improved. And when the modified polyphenyl ether, the modified polystyrene, the modified carbon nanotubes and the zinc oxide are subjected to melt blending, under the action of the zinc oxide, the modified polyphenyl ether and the modified polystyrene are compounded and can be subjected to a DA reaction with maleimide on the modified carbon nanotubes to form dynamic crosslinking, so that the antistatic effect of the composite material is improved. Dynamic crosslinking can absorb and disperse energy when the composite material is impacted, and enables a molecular chain segment to generate greater motion when the composite material is impacted, so that deformation of the material is facilitated without breakage.
Owner:JIANGXI PLASTIC HIGH-TECH MATERIALS CO LTD

Outdoor anti-aging PP plate and preparation method thereof

InactiveCN119899460ACarbon layerAntioxidant
The invention relates to an outdoor anti-aging PP plate and a preparation method thereof, and belongs to the technical field of high polymer materials. The outdoor anti-aging PP plate comprises the following components in parts by weight: 40-80 parts of PP resin, 10-20 parts of glass fibers, 1-5 parts of an anti-aging modifier, 0.2-3 parts of a modified flame retardant, 0.1-1 part of a lubricant and 0.1-0.5 part of an antioxidant, hydroxybenzophenone in the modified anti-aging agent generates thermal vibration and releases energy when absorbing ultraviolet rays and being irradiated by the ultraviolet rays, and cooperates with butyltrimethoxysilane to protect the material from being damaged by the ultraviolet rays, and a maleimide group improves the glass transition temperature and the melting point and reduces the influence of high-temperature thermal aging; a B-O-C carbon layer is formed at a high temperature under the synergistic effect of boron and phosphorus of the modified flame retardant, flame-retardant gas is released, and the modified flame retardant and phosphorus-oxygen double bonds are synergistically flame-retardant, so that the flame-retardant property is remarkably improved; the outdoor anti-aging PP plate prepared by the invention not only has excellent anti-aging performance, but also has a good flame-retardant effect.
Owner:JIANGXI XULIAN NEW MATERIAL CO LTD

Dynamic self-adaptive polymer artificial SEI layer based on DA bond and preparation and application of dynamic self-adaptive polymer artificial SEI layer

The invention belongs to the technical field of lithium metal batteries, and relates to the technical field of artificial SEI layers, in particular to a dynamic self-adaptive polymer artificial SEI layer based on a DA bond and preparation and application thereof. Linear polyurethane serves as a framework, a dynamic DA bond is introduced into a polymer system, a topological network structure is formed through in-situ reaction of the linear polyurethane and bismaleimide on the surface of a lithium metal negative electrode, and therefore the artificial SEI layer based on the DA bond is prepared. The artificial SEI layer is a three-dimensional topological structure polymer material with a dynamic adaptive characteristic. A DA dynamic covalent bond and a hydrogen bond introduced into the structure endow the artificial protection layer with excellent mechanical properties and dynamic characteristics, so that the artificial protection layer can adapt to the volume change of a lithium metal negative electrode in a battery cycle process, thereby realizing long-term stability of the electrode, and remarkably improving the safety and electrochemical performance of the lithium metal battery. Therefore, the invention provides an innovative method for preparing the novel artificial SEI layer.
Owner:SUN YAT SEN UNIV

Method for recovering anode material aluminum foil of waste lithium ion battery

According to the method for recycling the waste lithium ion battery positive electrode material aluminum foil, double-bond addition is conducted on ureido of allylurea and maleimide, meanwhile, thiazolecarboxylic acid amino cyclization is conducted, ternary heterocyclic molecules containing ureido, thiazole rings and carboxyl are generated, S atoms, N atoms and O atoms form tridentate coordination sites, and the leaching rate of aluminum is increased.
Owner:ZHEJIANG SHANGAO NEW ENERGY CO LTD

Novel linkers for sustained delivery of therapeutic agents

Linkers for linking a therapeutic agent to other moieties, such as an Fc region of an antibody. A linker having two or more maleimide functional groups, which may be subjected to a nucleophilic conjugate addition reaction. A method for increasing the duration of action of a therapeutic agent by linking a novel linker to the Fc region of an antibody. Antibody drug conjugates having a longer duration of action than the drug alone.
Owner:ELI LILLY & CO

High-heat-resistance epoxy modified bismaleimide resin, preparation method thereof and prepreg

PendingCN120699432AEpoxyImide
The invention discloses high-heat-resistance epoxy modified bismaleimide resin as well as a preparation method and prepreg thereof, and relates to the technical field of thermosetting resin. The resin comprises the following raw materials in parts by weight: 30-60 parts of bismaleimide monomer resin, 10-30 parts of polyfunctional epoxy resin and 20-40 parts of an allyl mixture, the bismaleimide monomer resin at least comprises special bismaleimide monomer resin with a structural formula and / or a structural formula; the allyl mixture at least comprises 1, 2-bis (4-(allyloxy) phenyl) disulfane. The structural heat resistance can be effectively improved by specifically selecting the component raw materials and limiting the dosage, aggregation and accumulation of polymer chains are promoted, and the crosslinking density of the bismaleimide resin is further improved. Meanwhile, the curing temperature of the bismaleimide resin is obviously reduced to 190 DEG C, so that the problems of high manufacturing cost, long curing period and the like of the bismaleimide resin are solved, the dimensional stability of a bismaleimide composite material product can be improved, and the dimensional precision is improved.
Owner:HENGSHEN

Flame-retardant and insulated low-voltage power cable and preparation method and application thereof

The invention relates to the technical field of crosslinked polyethylene insulated power cables, in particular to a flame-retardant and insulated low-voltage power cable and a preparation method and application thereof. The flame-retardant and insulating low-voltage power cable comprises the inner core layer, the filler layer, the belting layer, the lining layer, the metal armor layer and the outer sheath layer from inside to outside, and the multiple layers can effectively protect the inner core and endow the cable with better performance; in addition, low-density polyethylene, a furan modified polyethylene compatilizer, a reactive flame retardant, bismaleimide, dicumyl peroxide and an auxiliary are adopted to obtain the cross-linked polyethylene material for the cable outer sheath, and the cross-linked polyethylene material has excellent insulation, flame retardance, strength, toughness and repairing performance.
Owner:KUNMING DUOBAO CABLE CO LTD

Flexible flame-retardant aerogel and preparation method thereof

The invention relates to the technical field of aerogel, in particular to flexible flame-retardant aerogel and a preparation method thereof.The flexible flame-retardant aerogel is prepared from modified graphene, modified polyvinyl alcohol, silver nanowires, phytic acid and epoxy resin E-51; the furan group is introduced into the aerogel through the modified graphene, the furan group and the maleimide group are subjected to a D-A reaction, an adhesive is prevented from being used when the aerogel is bonded with a screen backboard, the D-A reaction is reversible, and lossless reworking can be realized. PVA and epoxy resin E-51 are added together, so that the heat resistance and mechanical strength of the material are improved. PVA is grafted with a large-steric-hindrance amine group, weak interaction with a furan group is generated, side reaction with an epoxy group of epoxy resin E-51 is avoided, and when aerogel is bonded to an OLED screen backboard, the protective layer is reversibly released, so that D-A reaction can be smoothly carried out. The hydrophobic treatment of the modified graphene and the modified grafting of the polyethylene to the mPEG can effectively improve the agglomeration of the modified graphene and ensure the uniform dispersion of the modified graphene.
Owner:SHENZHEN XINFUYI INDAL

Acrylate-epoxy resin composite coating and preparation method thereof

The invention relates to the technical field of coatings, in particular to an acrylate-epoxy resin composite coating and a preparation method thereof. According to the technical scheme, the coating is prepared from 25 to 35 parts of methyl methacrylate, 15 to 25 parts of butyl acrylate, 10 to 20 parts of epoxy resin E-5110, 8 to 15 parts of organic silicon modified acrylate prepolymer, 5 to 12 parts of fluorocarbon modified epoxy resin, 4 to 8 parts of core-shell structure corrosion inhibition nano container, 1 to 3 parts of functionalized graphene quantum dots and 4 to 10 parts of polyhedral oligomeric silsesquioxane maleimide modified amine curing agent. And 1-3 parts of a hindered amine light stabilizer. By integrating the core-shell structure corrosion inhibition nano container, the functionalized graphene quantum dots and the photo-thermal dual responsive curing agent component, the sensing, response and self-repairing of the coating on damage are realized, and long-acting corrosion resistance, weather resistance, bacteria resistance, mechanical property balance and intelligent maintenance are considered; and efficient and economical full-period protection is provided for equipment in an extreme environment.
Owner:深圳市深赛尔股份有限公司

Resin composition, prepreg and preparation method therefor, and laminate and preparation method therefor

A resin composition, a prepreg and a preparation method therefor, and a laminate and a preparation method therefor. The resin composition comprises the following raw materials in parts by mass: 20-50 parts of a modified bismaleimide prepolymer, 10-40 parts of cyanate ester resin, 30-60 parts of functional resin, and 50-200 parts of an inorganic filler, wherein raw materials of the modified bismaleimide prepolymer include bismaleimide resin and a modifier, and the modifier comprises tripolynaphthalene diallyl ether. A cured product of the resin composition has an extremely low coefficient of thermal expansion, excellent high-temperature modulus retention and extremely high heat resistance, also shows excellent dielectric properties, and is thus suitable for preparing high-performance semiconductor packaging substrates.
Owner:GUANGDONG HINNO TECH CO LTD

Thermosetting resin composition, resin sheet, metal foil with resin, metal-clad laminate, and printed wiring board

The present disclosure provides a thermosetting resin composition contributing to reducing the elastic modulus of a cured product and increasing the flexibility thereof while reducing the chances of causing a decline in the heat resistance of the cured product. A thermosetting resin composition contains: a maleimide compound (A) having at least two maleimide groups in one molecule; a compound (B) having, at either or both of terminals thereof, a substituent with an ethylenic unsaturated bond and having a polyphenylene ether skeleton; and an inorganic filler (C). The compound (B) includes a compound (B1) having a butadiene-derived structural unit.
Owner:PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD

ZrB2 / SiC / TiB2 ultrahigh-temperature ceramic and preparation method thereof

ActiveCN120117907ADiphenylmethaneImide
The invention provides ZrB2 / SiC / TiB2 ultrahigh-temperature ceramic and a preparation method thereof, and belongs to the field of ultrahigh-temperature ceramic. The preparation method comprises the following steps: preparing SiC / TiB2 composite particles, modifying and compounding the SiC / TiB2 composite particles, preparing ceramic slurry, forming and calcining. The compounding step comprises the following steps: putting modified SiC / TiB2 composite particles and modified ZrB2 particles into N-methyl pyrrolidone, uniformly stirring, adding 4, 4 '-bismaleimide diphenylmethane, and stirring at 110-115 DEG C for 2.8-3.2 hours to obtain ZrB2 / SiC / TiB2 particles; the ceramic product prepared by the invention is high in interface bonding strength, uniform in internal structure, relatively high in toughness and strength, good in temperature resistance, stable in overall performance and excellent in comprehensive performance.
Owner:SHANDONG RES & DESIGN ACADEMY OF IND CERAMICS

Resin composition and preparation method thereof, prepreg, laminated board and printed circuit board

The invention relates to a resin composition and a preparation method thereof, a prepreg, a laminated board and a printed circuit board. The resin composition is prepared from the following components in parts by mass: 30 to 80 parts of modified bismaleimide prepolymer and 20 to 60 parts of cyanate ester resin, the modified bismaleimide prepolymer is prepared from the following raw materials: bismaleimide resin and a diamine compound, wherein the diamine compound contains a benzocyclobutene structure. In the resin composition, the modified bismaleimide prepolymer prepared from specific preparation raw materials and the cyanate ester resin are matched according to a specific proportion, so that the resin composition has a relatively low thermal expansion coefficient; meanwhile, the glass transition temperature and the thermal decomposition temperature are higher, the peel strength and the elastic modulus are higher, and the dielectric constant and the dielectric loss are lower, so that the high thermal stability, the size stability, the mechanical property and the dielectric property are better.
Owner:GUANGDONG HINNO TECH CO LTD +1

High-oxidation-resistance long-life polyethylene cable sheath material and preparation method thereof

The invention discloses a high-oxidation-resistance long-life polyethylene cable sheath material and a preparation method thereof, and relates to the technical field of high polymer materials. Comprising the following components: high-molecular-weight high-density polyethylene, surface-modified nano-dioxide, furan-maleimide grafted polyethylene, a Schiff base dynamic cross-linking agent, tea polyphenol grafted polyethylene, a temperature-responsive oxygen-blocking microcapsule, a main antioxidant, an auxiliary antioxidant, an emergency antioxidant, a light stabilizer, a halogen-free flame retardant, a processing aid and an acid absorbent. According to the invention, the main antioxidant, the auxiliary antioxidant and the tea polyphenol grafted polyethylene form a chemically synthesized and naturally modified composite antioxidant system, the designed service life of the material is greatly prolonged, the temperature-responsive oxygen-blocking microcapsule automatically cracks to release the core material when the operating temperature of the cable is greater than or equal to 90 DEG C, a dynamic oxygen-blocking layer is formed, and the service life of the cable is prolonged. The defect that the effect of traditional physical oxygen barrier is attenuated at high temperature is overcome, and the oxygen permeability at high temperature is reduced compared with that of a single nano barrier scheme.
Owner:HUBEI PROVINCE KANGTAI PLASTIC CO LTD

Crosslinked polyethylene insulating material with intrinsic self-repairing and recoverable characteristics as well as preparation method and application of crosslinked polyethylene insulating material

The invention provides a crosslinked polyethylene insulating material with intrinsic self-repairing and recoverable characteristics as well as a preparation method and application thereof, and relates to the technical field of cable materials. The crosslinked polyethylene insulating material with intrinsic self-repairing and recoverable characteristics is prepared from the following components in parts by weight: 99.7 parts by weight of low-density polyethylene, 1.0 to 2.6 parts by weight of peroxide, 0.1 to 0.5 part by weight of an antioxidant, 5 to 20 parts by weight of a maleimide monomer, 0.35 to 0.7 part by weight of a catalyst, 0.5 to 3.0 parts by weight of a ligand and 0.5 to 3.0 parts by weight of furyl micromolecules. The low-density polyethylene is subjected to functional modification through catalytic amination reaction, chain interruption and crosslinking in the modification process are avoided, and the mechanical property, the insulating property and the dielectric property of the crosslinked polyethylene are enhanced through peroxide introduced through post-absorption. Meanwhile, the dynamic reversible Diels-Alder reaction introduced by the furyl small molecules is absorbed, so that the polyethylene insulating material has a good intrinsic self-repairing effect on mechanical damage and electric damage.
Owner:UNIV OF SCI & TECH BEIJING

Crosslinked polyethylene insulation material with intrinsic self-repairing and recyclable properties, and preparation method and application thereof

The application provides a crosslinked polyethylene insulating material with intrinsic self-repairing and recyclable characteristics, a preparation method and application thereof, and relates to the technical field of cable materials.The crosslinked polyethylene insulating material with intrinsic self-repairing and recyclable characteristics is prepared from the following components in parts by weight: 99.7 parts by weight of low-density polyethylene, 1.0-2.6 parts by weight of peroxide, 0.1-0.5 parts by weight of antioxidant, 5-20 parts by weight of maleimide monomer, 0.35-0.7 parts by weight of catalyst, 0.5-3.0 parts by weight of ligand and 0.5-3.0 parts by weight of furan-based small molecule.The low-density polyethylene is functionally modified through catalytic amination reaction, so that the chain breaking and crosslinking in the modification process are avoided, and the mechanical properties, insulating properties and dielectric properties of the crosslinked polyethylene are enhanced through the post-absorption of the introduced peroxide.Meanwhile, the dynamic reversible Diels-Alder reaction introduced by the post-absorption of the furan-based small molecule enables the polyethylene insulating material to have good intrinsic self-repairing effect on mechanical damage and electrical damage.
Owner:UNIV OF SCI & TECH BEIJING

Preparation process of early-warning anti-loosening bolt

The invention discloses a preparation process of an early-warning anti-loosening bolt, and relates to the technical field of bolts, the outer side of a bolt base body is coated with a layer of anti-corrosion sheath containing a polyamide composite material through an injection molding process, so that the effect of improving the corrosion resistance of the bolt is achieved. Furan-2, 5-diketone is used for modifying aminated graphene oxide, maleimide modified graphene oxide is obtained, maleimide has the characteristic of being sensitive to ultraviolet light, and can react with styrene and methyl methacrylate under ultraviolet irradiation, so that vinyl graphene oxide is obtained; and then polyamide modified glass fibers are added, so that the corrosion resistance of the bolt is further improved.
Owner:CHINATOWER CO LTD HEBEI BRANCH

Nitrogen-containing heterocyclic compound as well as preparation method and application thereof

The invention relates to a nitrogen-containing heterocyclic compound as well as a preparation method and application thereof, belongs to the technical field of heterocyclic compound synthesis, and solves the problems of low reaction efficiency and high energy consumption caused by the fact that an existing method for synthesizing an indole maleimide derivative needs to be carried out step by step. The preparation method comprises the following steps: step 1, adding indoleacetamide and a nucleophilic reagent into a mixed solution, and reacting; 2, performing post-treatment to obtain a nitrogen-containing heterocyclic compound; the mixed solution comprises alkali, an additive and an organic solvent; the alkali comprises one of triethylamine (Et3N), N, N-diisopropylethylamine, pyridine and 1, 8-diazabicyclo [5.4. 0] undec-7-ene, and the alkali comprises one of 1, 8-diazabicyclo [5.4. 0] undec-7-ene.
Owner:HUNAN VOCATIONAL COLLEGE OF SCI & TECH

High-adhesiveness water-based printing ink and preparation method thereof

The invention discloses high-adhesiveness water-based printing ink and a preparation method thereof, and belongs to the technical field of printing, and the high-adhesiveness water-based printing ink comprises the following components: water-based acrylic resin, SiO2 (at) TiO2 (at) EPS composite filler, pigment, a dynamic covalent cross-linking agent, nano cellulose, a wetting dispersant, a defoaming agent and deionized water. The preparation method comprises the following steps: firstly, preparing an EPS terpolymer containing a multi-functional group, and then modifying a SiO2 / TiO2 preassembly to prepare a composite filler; meanwhile, a dynamic covalent cross-linking agent generated by the reaction of furan methacrylate and maleimide propyl triethoxy silane is prepared; and finally, mixing the components step by step to obtain the ink. The multi-stage structure of the composite filler enhances the interface effect and covering power, the dynamic covalent cross-linking agent forms a reversible network to improve the stability and the self-repairing property, and the nano cellulose and other components have the synergistic effect, so that the ink has good adhesiveness and stability.
Owner:GUIZHOU NORMAL UNIVERSITY

High-chemical-resistance TPO material and preparation method thereof

PendingCN120464073AFuranPolymer science
The invention relates to the technical field of high polymer materials, and discloses a high-chemical-resistance TPO material which comprises the following components in parts by mass: 55-65 parts of polypropylene; 35 to 45 parts of a styrene-ethylene / butylene-styrene block copolymer; 0.4 to 0.6 part of a furan end-capping reagent; 0.2 to 0.4 part of a maleimide cross-linking agent; 4-6 parts of modified shell powder; 8 to 12 parts of epoxidized cardanol; 2-4 parts of a heat-sensitive microcapsule, wherein the heat-sensitive microcapsule comprises a shell layer and an inner core; and 0.5 to 1.5 parts of a nano cellulose surface treating agent. Through the synergistic effect of a dynamic cross-linked network and fluorocarbon chain surface modification, when the material is in contact with acid, alkali and an organic solvent, reversible cross-linked bonds release local stress through a fracture-reconstruction mechanism, and microcrack propagation is inhibited; and the compact fluorocarbon layer on the surface forms a chemical inert barrier, so that the permeation rate of a corrosive medium is remarkably reduced, and the structural stability and long-term durability of the material in a complex chemical environment are guaranteed.
Owner:SUZHOU GREENTECH CO LTD

Self-repairing epoxy resin and preparation method thereof

PendingCN121086475AFuranPolymer science
The invention relates to the technical field of epoxy resin, in particular to self-repairing epoxy resin and a preparation method thereof. The self-repairing epoxy resin is prepared from the following raw materials in parts by mass: 80 to 120 parts of bisphenol A type epoxy resin, 20 to 40 parts of bisphenol F type epoxy resin, 5 to 15 parts of 1, 6-hexanediol diglycidyl ether, 1 to 3 parts of 3, 5-dimethylphenylboronic acid, 1 to 5 parts of furyl maleimide, 10 to 20 parts of dodecanedioic acid, 5 to 15 parts of butanetetracarboxylic acid, 1 to 3 parts of catalyst, 10 to 15 parts of nano silicon dioxide, 1 to 2 parts of boron nitride nanosheet and 1 to 2 parts of hyperbranched polyamidoamine. The curing agent is prepared from the following components in parts by weight: 20-30 parts of epoxy resin, 1-2 parts of sulfydryl-terminated polysiloxane, 20-30 parts of amine curing agent, 5-15 parts of reinforcing filler and 0.5 According to the invention, the balance among self-repairing capability, mechanical property and heat resistance is successfully realized; in the microcrack propagation process, fracture and recombination mechanisms of dynamic covalent bonds effectively prevent further propagation of cracks.
Owner:TIANJIN XINGTAI ENVIRONMENTAL PROTECTION TECH CO LTD

Silicon-based aerogel composite material as well as preparation method and application thereof

The invention relates to the technical field of building, chemical engineering and energy heat preservation, and discloses a silicon-based aerogel composite material and a preparation method and application thereof. The invention relates to a light-emitting diode (LED) photo-curing agent, which is prepared from tetraethyl orthosilicate, methyltrimethoxysilane, allyltriethoxysilane, pentaerythritol tetra (3-mercaptopropionate), N-(3-(triethoxysilyl) propyl) furfuryl amine, N-(3-(triethoxysilyl) propyl) maleimide, a photoacid generator and a photoinitiator. The composite material has a three-dimensional porous silicon dioxide network skeleton and a polymer interpenetrating network, the three-dimensional porous silicon dioxide network skeleton is formed by copolymerization of tetraethyl orthosilicate and methyltrimethoxysilane, and the polymer interpenetrating network is formed by reaction of pentaerythritol tetra (3-mercaptopropionate) and allyltriethoxysilane. The preparation method comprises the steps of sol preparation, light curing, solvent replacement, surface hydrophobic modification and normal-pressure drying. The material shows excellent thermal insulation and mechanical properties in the fields of building heat insulation, pipeline heat preservation and cryogenic heat insulation.
Owner:江西宏柏新材料股份有限公司

DA bond polymer film with antibacterial and self-repairing functions as well as preparation method and use method of DA bond polymer film

The invention discloses a DA bond polymer with antibacterial and self-repairing functions for a wood surface as well as a preparation method and a use method of the DA bond polymer. Chitosan serves as a wall material, cinnamon essential oil serves as a core material, the cinnamon essential oil and chitosan antibacterial microcapsules are prepared through emulsification, crosslinking and spray drying, and essential oil controlled release is achieved. Then bisphenol A diglycidyl ether DGEBA and furfuryl alcohol FA are used as raw materials, furyl functional epoxy resin FER is prepared under the catalysis of triethylamine TEA, bismaleimide BMI is added, and a DA bond self-repairing polymer is prepared through a DA reaction; and adding 4, 4-diaminodiphenylmethane DDM into the system, reacting with redundant DGEBA to generate a cross-linked polymer network, and adding the microcapsules into a DA bond semi-interpenetrating self-repairing network solution to obtain the DA bond polymer. A thin film formed by brushing and curing wood has antibacterial and self-repairing functions, scratches and microcracks on the surface of the wood can be repaired, and microbial erosion is inhibited.
Owner:NANJING FORESTRY UNIV

Single-component high-heat-resistance epoxy adhesive and preparation method thereof

The invention discloses a single-component high-heat-resistance type epoxy adhesive and a preparation method of the single-component high-heat-resistance type epoxy adhesive. The adhesive is prepared from the following components in parts by weight: 30 to 40 parts of N, N-4, 4 '-diphenylmethane bismaleimide; 50 parts of bisphenol F epoxy resin; 36.47 parts of 4, 4 '-diaminodiphenyl sulfone; 20 to 40 phr of phenyl glycidyl ether; 1 to 2 phr of two terminal type epoxy silicone oil; 4 to 6 phr of hydroxyl-terminated polyether sulfone; 10 to 20 phr of boron nitride, the surface of which is modified by gamma-glycidyl ether oxypropyl trimethoxy silane; and 1 to 3 phr of an adhesion promoter. According to the adhesive disclosed by the invention, the heat resistance, the mechanical property, the dimensional stability, the process adaptability and the like are synergistically improved, the use requirements of an aviation structural part on long-term service at 150-180 DEG C and an electronic packaging device on the condition of short-time reflow soldering at about 200 DEG C can be met, and the reliability of the adhesive in a high-temperature environment is remarkably improved.
Owner:SUZHOU MECOTECH PROCESS ELECTRONIC TECH CO LTD

Preparation method of diamine chain extension toughened bismaleimide resin

PendingCN119899379AImidePolymer science
The invention belongs to the field of new resin materials, and particularly relates to a preparation method of diamine chain extension toughened bismaleimide resin, which comprises the following steps: mixing a diamine chain extender with bismaleimide, heating and melting the mixture, continuously stirring in a molten state, and reacting for a period of time to form a prepolymer A; mixing the prepolymer A and a reactive diluent to form a blending system, heating and melting the blending system, continuously stirring in a molten state, and reacting for a period of time to form a prepolymer B; and defoaming and curing the prepolymer B to obtain the diamine chain extension toughened maleimide resin. According to the preparation method, on the basis of keeping good thermal stability, the manufacturability of the bismaleimide resin in the preparation process is obviously improved, and meanwhile, the toughness of the bismaleimide resin is obviously improved.
Owner:SHANDONG NON METALLIC MATERIAL RESEARCH INSTITUTE

Resin composition, prepreg and printed circuit board

The invention belongs to the field of high polymer materials, and particularly relates to a resin composition, a prepreg and a printed circuit board. The resin composition provided by the invention is prepared from the following components: 40 to 80 parts of prepolymer, 10 to 50 parts of curing agent, 30 to 70 parts of epoxy resin, 1 to 10 parts of imidazole compound and 50 to 150 parts of filler, wherein the prepolymer is prepared from the following raw materials: maleimide resin and a fluorenyl compound containing amino groups; the maleimide resin comprises one or more of compounds with a structure as shown in a formula (I); the fluorenyl compound containing the amino group comprises one or more of compounds with a structure as shown in a formula (II). According to the resin composition provided by the invention, the maleimide resin modified prepolymer is selected and has good compatibility with epoxy resin, so that the addition of filler can be effectively reduced, and further the processability of the resin composition can be ensured; and the resin composition provided by the invention has excellent heat resistance.
Owner:GUANGDONG HINNO TECH CO LTD

High-strength high-resilience TPE (thermoplastic elastomer) and preparation method thereof

The invention discloses a high-strength and high-resilience TPE (thermoplastic elastomer) and a preparation method thereof in the technical field of high polymer materials, and the elastomer is prepared by taking a hydrogenated styrene block copolymer as a matrix and matching with a polyolefin rigid phase, plasticizing oil and a specific additive. The method is characterized in that two self-made reaction type modifiers are introduced, wherein one self-made reaction type modifier is a core-shell nano reinforcing agent containing an epoxy functional group and polyhedral oligomeric siloxane, and the other self-made reaction type modifier is a furan maleimide bifunctional dynamic cross-linking agent. The nano reinforcing agent is prepared through silane hydrolysis and amination reaction, and can react with a matrix for grafting, so that the strength and creep resistance of the material are remarkably improved; the dynamic cross-linking agent is synthesized through step-by-step isocyanate addition reaction, a cross-linked network can be reversibly formed in the processing process, and the material is endowed with extremely high rebound resilience and low permanent deformation. The obtained product has high strength, high resilience and excellent processability, and is especially suitable for high-end fitness equipment.
Owner:HUNAN TIANTOU PLASTIC PRODUCTS CO LTD

Polyethylene wax with reversible crosslinking characteristic as well as preparation method and application thereof

PendingCN121343041AFuranImide
The invention relates to polyethylene wax with a reversible crosslinking characteristic and a preparation method and application thereof, and relates to the field of polymer functional aids and processing and application thereof. The polyethylene wax with the reversible cross-linking characteristic is prepared from three monomers of furyl ethylene, maleimide ethylene and ethylene through double-bond addition copolymerization, and the number-average molecular weight is 1000-100000. The polyethylene wax provided by the invention can be used as a flow modifier during polyethylene material processing and a cross-linking modifier during use. The low molecular weight polyethylene wax can reduce the energy consumption of processing equipment and increase the flatness of the product. And meanwhile, the reversible crosslinking of furan and maleimide groups on the chain segment can endow the resin with thermoset property in use and thermoplastic cycle processability after use.
Owner:SHANGHAI JIAOTONG UNIV +1