1505 results about "Thermal shrinkage" patented technology

The invention discloses a lithium battery diaphragm coating based on a nano material and application thereof, and relates to the technical field of lithium battery diaphragms. The coating comprises the following raw materials in parts by weight: 15-25 parts of polystyrene maleic anhydride copolymer modified polyvinylidene fluoride, 10-20 parts of polystyrene, 2-4 parts of nano silicon nitride, 3-6 parts of a boehmite / aluminum oxide and silicon dioxide composite material, 1-2 parts of a dispersing agent and 65-90 parts of a solvent, according to the lithium battery diaphragm coating provided by the invention, the wettability and absorptivity of a diaphragm to an electrolyte are remarkably improved, meanwhile, the lithium battery diaphragm coating also has excellent thermal stability, and the diaphragm can be effectively prevented from thermal shrinkage or melting under a high-temperature condition, so that the safety performance of a battery is remarkably enhanced.

The invention relates to an antistatic PET (Polyethylene Terephthalate) base film for preparing a polaroid release film and a preparation method thereof, the release film base film is prepared by taking an optical-grade PET slice as a main body, adding modified PET with a specific structure and a modified SiO2 filler, and carrying out co-extrusion casting, a unique three-section stretching process and coating with a coating liquid. According to the invention, material modification and process improvement are carried out, specifically, an optical-grade PET slice is taken as a main body material, modified PET and a modified SiO2 filler with a specific structure are added, a film is prepared through co-extrusion casting and a unique three-section stretching process, and then the surface of the film is coated with a layer of antistatic coating liquid, so that the antistatic film is obtained. The finally prepared base film has low alignment angle, low transverse hot shrinkage rate and high surface adhesion, keeps the characteristics of high light transmittance and low haze of an optical-grade polyester film, endows the film with certain antistatic property, and is particularly suitable for being used as a release film of a high-end polaroid.

The invention provides an intelligent sorting method and system for radioactive substances. The method comprises the following steps: synchronously detecting surface element composition and radiation intensity of a radioactive substance through an X-ray fluorescence spectrometer, and constructing a spatial difference matrix of element abundance distribution and a radiation gradient topological graph; the three-dimensional coordinates, the pressure threshold value and the shape adaptation parameters of the target grabbing position are determined on the basis, the curvature radius of the clamping jaw deformation contour is dynamically adjusted, and the error of the dynamic geometric envelope and the contour template is converged to be within the threshold value; finally, when the clamping jaw reaches a target position, the area of the heat shrinkage material is activated to be heated according to the radiation intensity abrupt change boundary coordinates, a sealed isolation layer synchronously expanded with the dynamic geometric envelope is generated, and safe grabbing and sealed isolation of radioactive substances are achieved. According to the technical scheme, accurate grabbing of radioactive substances, error self-adaptive compensation and synchronous isolation of radiation leakage can be achieved, and the sorting safety and efficiency are improved.

The invention relates to the technical field of control systems, in particular to a production process optimization control system and method for a heat shrink film. The method comprises the following steps: obtaining resin characteristic parameters of a heat shrink film raw material, and constructing an initial digital twinborn model by using the resin characteristic parameters; acquiring real-time production data, and updating the initial digital twinborn model by using the real-time production data to obtain a complete digital twinborn model; and performing melt ultrasonic-assisted homogenization and two-way stretching process simulation based on the digital twin model, and performing optimization analysis by using a simulation result to generate optimized process parameters. By constructing and updating the digital twinborn model, the melt uniformity and process parameter optimization are accurately controlled, the quality consistency and stability of the thermal shrinkage film are improved, and the product is ensured to meet the mechanical, optical and thermal shrinkage performance requirements.

The invention discloses a dry-process high-temperature-resistant lithium battery diaphragm and a preparation method thereof, and relates to the technical field of lithium battery diaphragms. The specific preparation method comprises the following steps: activating and cross-linking polypropylene, polyimide, a PP-b-PI block copolymer and a cross-linking agent BIBP under the protection of nitrogen to prepare a polypropylene-polyimide matrix; after melting, adding a pre-sintered ZrO2-coated Al2O3 core-shell filler, hydroxylated boron nitride and zinc borate, and carrying out double-stage screw extrusion, ultrasonic orientation, nitrogen annealing and cold roller quenching to obtain a mixed melt; carrying out warm stretching and hot air circulation heat treatment to prepare a hard elastic crystal base film; carrying out stretching, thermal relaxation and thermal shaping to obtain a microporous base membrane; after slitting, plasma activation is carried out, epoxy silane and tetraethyl orthosilicate / polybenzimidazole aerogel precursors are sprayed, and a nano closed-pore coating is formed through pre-curing and heat shrinkage curing; and finally eliminating static electricity and rolling to obtain a finished product. The lithium battery diaphragm prepared by the invention is excellent in high temperature resistance and low in thermal shrinkage rate.

The invention relates to the field of heat shrinkage films, in particular to an antistatic PETG heat shrinkage film. The PETG heat shrink film comprises the following components in parts by weight: 100 parts of PETG resin, 2-6 parts of an anti-adhesion agent, 2-5 parts of a lubricant, 1-5 parts of an antistatic modifier, 1-2 parts of an antioxidant and 0.5-1 part of a light stabilizer. In the preparation process of the PETG heat shrink film, a novel borate antistatic agent is introduced, and the antistatic agent is synthesized by taking tris (2-carboxyethyl) isocyanurate and 4-aminophenylboronic acid pinacol ester as raw materials, so that compared with a traditional antistatic agent, the antistatic property is better, the heat stability is obviously improved, and the service life of the heat shrink film is prolonged. And the phenomenon of local deformation or poor arc-shaped shrinkage of the PETG heat shrinkage film when the PETG heat shrinkage film shrinks at a non-uniform interface is reduced.

The invention discloses an aramid fiber coated polyolefin battery diaphragm and a preparation method and application thereof, the aramid fiber coated polyolefin battery diaphragm can be used for manufacturing a lithium ion battery, and the aramid fiber coated polyolefin battery diaphragm is prepared by the following method: (1) treating a polyolefin base membrane by using a strong oxidant to obtain a modified base membrane; (2) dissolving aramid resin in a solvent to obtain an aramid coating solution; and (3) coating the surface of the modified base membrane with the aramid fiber coating liquid, and then curing. According to the invention, the interface bonding strength of the base membrane and the aramid fiber coating is obviously enhanced, so that the aramid fiber coating can give full play to high heat resistance, on the basis of ensuring the tensile strength of the diaphragm, the overall thermal shrinkage rate of the diaphragm is reduced, the risk of high-temperature short circuit is effectively inhibited, and the composite diaphragm with high porosity, strong mechanical property, high uniformity and no surface defect is formed; the method is suitable for high-energy-density lithium ion batteries, and the safety and high-temperature working condition stability of the batteries are remarkably improved.

The invention discloses a multilayer co-extrusion heat-shrinkable film and a preparation method thereof, the film comprises an outer wear-resistant layer, a middle support layer and an inner functional layer, the thickness ratio of each layer is 1: 3: 1-1: 5: 1, the total thickness is 50-150 [mu] m, and the raw materials are prepared according to respective formulas. The preparation method comprises the steps of raw material preparation, melt mixing, die head extrusion, two-way stretching, water-cooling shaping, electronic crosslinking, aging treatment, heating softening and cold and hot shaping. The carbon nanotubes (CNT) and the h-BN nanosheets synergistically hinder crack propagation in the middle layer, so that the crack propagation resistance of the film is remarkably improved, the tensile strength, the thermal shrinkage rate and other properties are also optimized, compared with a traditional film, the comprehensive properties of wear resistance, high strength and high thermal shrinkage rate are achieved through interface collaborative design, meanwhile, the production cost is reduced by 20-30%, and the application prospect is wide. The method is suitable for food packaging, electronic device protection and other fields.

The invention discloses a high-safety temperature-responsive electrolyte, a lithium ion battery and a sodium ion battery, the high-safety temperature-responsive electrolyte comprises a thermal response solvent, a cosolvent and an electrolyte salt, the thermal response solvent is a thermal response polymer monomer, the thermal response polymer monomer has at least one of the structures of vinyl ether, divinyl ether, dialkenyl amide and dialkenyl butanediimine, the thermal response polymer monomer can quickly form a polymer solid electrolyte under the catalysis of an initiator salt in electrolyte salt under a high-temperature condition, and the fixation of the solid electrolyte enables a diaphragm in a battery not to collapse, so that the battery diaphragm can be used as a lithium ion battery diaphragm. Therefore, short circuit caused by thermal shrinkage and fusion of the diaphragm is avoided, and thermal runaway is avoided. The electrolyte can be used for preparing the lithium-ion and sodium-ion battery, and the lithium-ion and sodium-ion battery can keep a relatively high capacity retention rate while giving consideration to the safety performance.

The invention discloses a 110kV high-voltage polypropylene power cable, and relates to the technical field of power cables, and the 110kV high-voltage polypropylene power cable comprises an outer sheath, a conductor is installed in the outer sheath, the conductor is sleeved with a cable core sleeve, a shielding sleeve is embedded in the outer wall of the cable core sleeve, an inner spacer bush is installed on the inner side of the outer sheath, and an outer spacer bush is installed on the outer side of the inner spacer bush. According to the invention, bidirectional limiting and locking protection of the inside and the outside of the cable can be realized, multiple supports are provided for the inside of the cable, the internal stress stability of the cable in the use process is effectively balanced, and the service life of the cable is prolonged. The interface compatibility among the structures in the cable is equivalently improved, the interface air gap generated by the thermal shrinkage of polypropylene is effectively compensated, the double restraint of water branches and electric branches is realized, the multiple optimization of the mechanical performance is structurally realized, the stability of the electric insulation performance is improved, and the effective service life of the cable is prolonged.

The invention provides a rigid-flexible metal-organic framework diaphragm with high selectivity as well as a preparation method and application of the rigid-flexible metal-organic framework diaphragm. Through a seed secondary growth strategy, the problems that MOF particles are easy to fall off and are incompatible with a substrate film are successfully avoided. On one hand, grain seeds embedded in the polyvinylidene fluoride (PVDF) substrate film in advance provide stable anchoring points for growth of MOF, and MOF particles are not prone to falling off due to the high adhesive force of the grain seeds. The high Young modulus of the MOF crystal also effectively improves the thermal shrinkage resistance of the diaphragm, the excellent flexibility of PVDF is complementary with the diaphragm in mechanical property, and the battery diaphragm shows excellent mechanical property and thermal stability due to the rigid-flexible combination strategy. The invention provides an efficient diaphragm construction strategy for developing a lithium metal battery with long cycle life and high safety, and shows a wide application prospect in a next-generation high-safety battery.

The invention provides an ultrahigh-temperature ceramic precursor, a preparation method thereof, a modified high-performance inorganic fiber and application, and relates to the technical field of high-temperature-resistant materials. The preparation of the ultra-high-temperature ceramic precursor comprises the following steps: placing a transition metal compound mixed solution in a low-temperature environment, standing, adding a coordination agent and an exchange agent, reacting, filtering in a low-temperature nitrogen atmosphere, adding a mixed solvent into the filtrate, heating and refluxing, and carrying out a polymerization reaction to obtain the ultra-high-temperature ceramic precursor. The superhigh-temperature ceramic precursor provided by the invention forms a high-temperature protective coating on the surface of a high-performance inorganic fiber and other materials, and meanwhile, a transition metal ion solution is placed under a low-temperature condition through a metal ion stabilization method, so that the internal structure of transition metal ions is more stable, and uniform dispersion at a molecular level is achieved; and the uniformity of the elements can be kept in the curing and cracking processes, and the phenomenon of coating stripping caused by mismatching of thermal shrinkage coefficients of a coating and a substrate material in an extreme environment is avoided.

The invention provides a modified negative pole piece, a battery and a battery system. The modified negative pole piece comprises a negative current collector; the modified active material layer is arranged on the surface of at least one side of the negative electrode current collector; the modified active material layer comprises an active material layer and a surface modification layer which are arranged in a laminated manner along the direction far away from the negative electrode current collector; the surface modification layer comprises at least two sub-modification layers, each sub-modification layer comprises a binder and a fast ion conductor electrolyte, and the content of the binder in the sub-modification layers is gradually reduced along the direction far away from the negative electrode current collector. On one hand, the infiltration state of the pole piece in the battery can be improved, the diffusion path of lithium ions can be shortened, the problem of stripping or falling of the active substance layer on the pole piece can be improved, and the structural stability of the battery can be improved, so that the rate capability and the cycle performance of the battery can be improved; the safety performance of the battery is improved and the overall cost of the battery is reduced.

A 3-D honeycomb textile can include a textured yarn. The textile can exhibit a heat-shrinkage rate from about 10% to about 60%. The textile can be configured to reversibly change its dimensions under application of stress. Prosthetic valves can have the disclosed textiles as a sealing member. Additionally, prosthetic valves can the disclosed textiles as cushion materials. In addition, methods of making the disclosed textiles and prosthetic valves are described.

The invention provides a battery and an electric device. A positive plate comprises a positive active material, and the positive active material is doped and / or coated with a lanthanum element; the surface of the diaphragm is coated with a ceramic coating; the electrolyte comprises a first solvent, a second solvent, a first additive and a second additive; the first solvent comprises a cyclic carbonate compound, the second solvent comprises a chain fluorosulfonamide compound, the first additive comprises mannitol carbonate sulfate, and the second additive comprises succinonitrile; the lanthanum element is doped / coated on the positive active material, so that the release of lattice oxygen at high voltage or high temperature can be effectively inhibited, and the exothermic reaction activity at the thermal runaway initial temperature is reduced; the first additive and the second additive in the electrolyte respectively form a compact CEI film and an SEI film with high thermal stability on the surfaces of the positive electrode and the negative electrode; the diaphragm ceramic coating provides a physical barrier, the thermal shrinkage temperature of the diaphragm is increased, and internal short circuit is prevented.

The invention relates to the technical field of PE warning board film covering, in particular to efficient film covering equipment for a PE warning protection board. Comprising a machine frame and a hot-pressing laminating chamber, a hot melting coating mechanism and a curved surface thermal shrinkage laminating mechanism are arranged in the hot-pressing laminating chamber, the hot melting coating mechanism comprises a heating roller and a first supporting roller, a three-layer phase change energy storage nested structure is arranged in the heating roller, and the curved surface thermal shrinkage laminating mechanism comprises a composite elastic roller and an elastic supporting roller. Distributed temperature sensors are arranged in the heating roller and the composite elastic roller, micro-airbag array layers are arranged on the roller surfaces of the composite elastic roller and the elastic supporting roller, pressure detection systems are arranged in the micro-airbag array layers, a cooling mechanism is further arranged behind the hot-pressing film laminating chamber, and the cooling mechanism comprises a cooling roller and two limiting guide rollers which are located on the two sides of the cooling roller and used for guiding. The coating device can adapt to coating operation of the curved-surface PE warning board, it is guaranteed that the surface of the warning board is evenly coated with a hot melt adhesive film, the fitting quality of a complex curved surface is improved, and the energy utilization efficiency is improved while the melting quality of the adhesive film is guaranteed.

The present invention provides a polypropylene resin composition, a high-temperature resistant polymer film containing the same, and a preparation method and application thereof. By mass percentage, the polypropylene resin composition includes 79.7-98.9% of polypropylene resin, 1-20% of cycloolefin copolymer, and 0.1-0.3% of radiation crosslinking agent; the glass transition temperature of the cycloolefin copolymer is 120-160 °C; in the present invention, the film including the polypropylene resin composition has a high heat distortion temperature and a low thermal shrinkage rate, good high-temperature resistance, does not affect the dielectric properties of the film capacitor, has a small dielectric loss, can be biaxially stretched at a high draw ratio, and has a low cost.

The invention provides a composite positive pole piece, a battery and a battery system. The composite positive pole piece comprises a current collector; the active material layer is arranged on the surface of at least one side of the current collector; the functional coating is arranged on the outer surface of the active substance layer, and the functional coating comprises a binder and an inorganic material; wherein the functional coating comprises at least two layers of sub-functional coatings, and the mass fraction of the binder in the sub-functional coatings is gradually reduced along the direction far away from the current collector. The functional coating provided by the invention comprises at least two sub-functional coatings, and the mass fraction of the binder in each sub-functional coating is gradually reduced along the direction far away from the current collector, so that on one hand, the infiltration state of the pole piece in the battery can be improved, and the structural stability and the rate capability of the battery are improved; on the other hand, the thermal shrinkage resistance of the diaphragm can be improved, the safety performance of the battery is improved, and the overall cost of the battery is reduced.

Provided is a polyester-based heat-shrinkable film or the like that, even when used in various types of PET bottles and the like, thermally shrinks stably and exhibits excellent wrinkle resistance characteristics.　This polyester-based heat-shrinkable film or the like has the following features (a)-(d). (a) The heat shrinkage rate A1 in the main shrinkage direction when being shrunk in hot water at 80°C at a condition of 10 seconds is set to a value within the range of 21-65%. (b) The heat shrinkage rate A2 in a direction orthogonal to the main shrinkage direction when being shrunk in hot water at 80°C at a condition of 10 seconds is set to a value within the range of -5% to 10%. (c) The absolute value (A1 / A2) of the ratio of the heat shrinkage rates A1 and A2 is 5.5 or more. (d) The neck-in rate measured in hot water at 70°C at a condition of 10 seconds is set to 6% or less.

The invention relates to the technical field of POF heat shrinkage films, and particularly discloses a recoverable POF heat shrinkage film and a preparation method thereof. A recyclable POF heat shrink film comprises a middle core layer and surface layers, the surface layers are located on the upper side and the lower side of the middle core layer, and the surface layers are prepared from 25-32 parts of PP, 2-5 parts of recycled master batch, 0.5-2 parts of an anti-blocking agent, 1-4 parts of a slipping agent and 1-2 parts of an anti-fogging agent; the recycled master batch is prepared from the following components in parts by weight: 65 to 73 parts of LLDPE (Linear Low Density Polyethylene) new material, 3 to 40 parts of LLDPE recycled material and 21 to 30 parts of active component; the active components comprise the following components in parts by weight: 45-55 parts of P34HB, 12-15 parts of alginate fibers and 4-5 parts of a nucleating agent. The preparation method comprises the following steps: mixing the PP and the recycled master batch, adding the anti-blocking agent, the slipping agent and the anti-fogging agent, carrying out internal mixing, carrying out internal mixing on the raw materials of the middle core layer, carrying out three-layer co-extrusion by using an extruder to prepare a sheet, and carrying out stretching and shaping. According to the POF heat shrink film, the conflict between the anti-fog function and the processing performance can be improved, so that the POF heat shrink film has excellent anti-fog performance, and meanwhile, the overall structural strength is relatively good.

The invention discloses a laser die-cutting machine capable of cutting an elastic film, and relates to the field of laser die-cutting machines, the laser die-cutting machine comprises a case, a first moving table capable of transversely and vertically moving and a second moving table capable of longitudinally moving are arranged in the case, a mounting frame is fixed on the first moving table, and a laser cutting head is arranged at the bottom end of the mounting frame; a fixing base coaxial with the laser cutting head is arranged at the bottom end of the mounting frame, and the bottom end of the fixing base is connected with an air blowing box and an air suction box which are oppositely arranged. When the stainless steel plate with the single face coated with the film is cut, high-power laser can be directly used for cutting the stainless steel plate at a time, high-speed airflow synchronously blown out by the air cooling mechanism can effectively restrain heat shrinkage of the elastic film caused by high temperature, material deformation and irregular edge cutting are avoided, the machining efficiency is remarkably improved while the high-power laser penetrates through the stainless steel plate, and the production cost is reduced. Repeated positioning errors and operation cost of equipment are reduced, and integrated efficient precision machining of the film-coated metal plate is achieved.

The invention belongs to the technical field of diaphragm material preparation, and particularly relates to a microporous membrane as well as a preparation method and application thereof. The microporous membrane comprises a polymer and an ionic liquid, and the microporous membrane comprises 0.01 wt%-5wt% of the ionic liquid, optionally 0.1 wt%-5wt% of the ionic liquid, based on the total mass of the microporous membrane. A proper amount of ionic liquid is introduced into the microporous membrane, the ionic liquid can be continuously or discontinuously adsorbed on the surfaces of the fibers in the microporous membrane, and the ionic liquid is adsorbed on the surfaces of the fibers in the microporous membrane through the oleophylic end of the ionic liquid, so that internal static electricity can be eliminated, and reduction of ionic conductivity can be better avoided; and the ion migration speed of the electrolyte is increased, and lithium dendrites are reduced. When the microporous membrane is used as a battery diaphragm, a proper amount of ionic liquid is added into the microporous membrane, so that the problem of electrostatic accumulation of the microporous membrane is solved, meanwhile, the microporous membrane has relatively low thermal shrinkage, and the problems that the battery capacity is influenced, the electrochemical safety is caused and the like are avoided.

The invention relates to the technical field of auxiliary supporting pieces for steel belt pipe welding, in particular to an auxiliary supporting mechanism for steel belt pipe welding, which comprises a base, two supporting pieces are arranged at the top end of the base, each supporting piece comprises a supporting column fixedly connected with the base, and the top end of each supporting column is connected with a supporting plate. Two movable blocks are symmetrically and movably installed on the surface of the supporting plate through sliding grooves, a positioning plate is connected to the top ends of the movable blocks, and the two movable blocks are arranged on the surfaces of the opposite threaded shafts in a sleeving mode through threads. The driving motor serves as a power source, the gear is controlled to rotate on the surface of the gear ring end of the ring frame, the bristle set is driven to rotate around the surface of the steel belt pipe, the sanding plate rubs the surface of the steel belt pipe, and steel bristles of the steel belt pipe can generate burrs and scratches on the heating surface of the steel belt pipe; the friction force and the contact surface of the heat-shrinkable bag covering and shrinking on the surface of the steel belt pipe are increased, the butt joint effect of the butt joint of the heat-shrinkable belt and the steel belt pipe is effectively improved, and the probability that the heat-shrinkable bag falls off in the later period is reduced.

The invention belongs to the field of intelligent materials, and discloses a nematic phase liquid crystal elastomer fiber and a method for optimizing the thermal shrinkage performance of the nematic phase liquid crystal elastomer fiber. According to the method, the mass ratio of a cross-linking agent pentaerythritol tetra (3-mercaptopropionate) (PETMP) to a chain extender 2, 2 '-[1, 2-ethanediyl bis (oxygen)] bis (ethanethiol) (EDDET) in an LCE spinning solution is accurately controlled through a wet spinning technology, and drafting and heat treatment processes are combined, so that the LCE fiber with adjustable and controllable heat shrinkage performance and mechanical performance is prepared. The invention aims to overcome the limitations of low response speed, low shrinkage rate, insufficient environmental stability and the like of the existing LCE fiber. The reversible thermal shrinkage rate of the fiber can reach up to 35%, the maximum shrinkage deformation can be completed within 2 seconds at the soonest at the temperature of 80 DEG C, and the maximum tensile strength can reach 170 MPa. And the catalyst has excellent oxidation stability (the mass retention rate is about 97%), and can maintain efficient thermal response in a water environment. And a new way is provided for development of high-performance intelligent materials.

The purpose of the present invention is to provide a heat-shrinkable film that has a reduced natural shrinkage rate and improved shrink finish. This heat-shrinkable film is composed of polyester and / or polystyrene and satisfies the following (1) to (4): (1) the shrinkage rate in the main shrinkage direction when treated in hot water at 70°C for 10 seconds is 3% or less; (2) the shrinkage rate in the main shrinkage direction when treated in hot water at 80°C for 10 seconds is more than 10% and not more than 50%; (3) the shrinkage rate in the main shrinkage direction when treated in silicon oil at 120°C for 10 seconds is 50-80%; and (4) the natural shrinkage rate (dimensional change rate) in the main shrinkage direction of the film after aging for 168 hours in an atmosphere of 50°C and 40% relative humidity is 1% or less.

The invention relates to the field of PETG heat shrink films, and provides an alkali-resistant PETG heat shrink film for battery labels and a preparation method thereof, the PETG heat shrink film comprises the following raw materials by weight: 90-110 parts of PETG, 5-15 parts of a composite alkali-resistant filler, 1-4 parts of an antistatic agent, 0.5-2 parts of an antioxidant, and 0.3-2 parts of a lubricant; wherein the composite alkali-resistant filler is a mixture of modified mica and modified calcined kaolin. The PETG thermal shrinkage film provided by the invention has the characteristics of high thermal shrinkage rate, high strength, good chemical stability and excellent alkali resistance.

The invention discloses a cross-linking type biodegradable POF heat shrink film and a preparation method thereof, and belongs to the technical field of heat shrink films, and the cross-linking type biodegradable POF heat shrink film is characterized by comprising three layers of films which are sequentially attached, each of the first-layer film and the third-layer film comprises the following raw materials in percentage by weight: 89.5-94% of PP, 2-6% of degradable master batch, 0.5-3% of an anti-blocking agent and 1-4% of a slipping agent; the second-layer film is prepared from the following raw materials in percentage by weight: 30 to 35 percent of LLDPE-A, 9 to 14.5 percent of toughening agent, 0.5 to 1 percent of degradable master batch, 40 to 45 percent of LLDPE-B and 10 to 15 percent of metallocene LLDPE; the melt index of the LLDPE-A is 2.5 g / 10min, the melt index of the LLDPE-B is 2.1 g / 10min, the melt index of the metallocene LLDPE is 1.0 g / 10min, and through the synergistic effect between the LLDPE with different melt indexes and the flexibilizer, the low-temperature tear resistance of the heat shrink film is effectively improved.

The invention relates to the technical field of digital die-cutting machines, in particular to a digital die-cutting machine which comprises a digital die-cutting machine body, a material conveying module and a movable cutting module, and the digital die-cutting machine body is fixedly connected with the movable cutting module. According to the film cutting device, parts such as a constraint cooling mechanism are arranged, a moving box synchronously moves along with the cutting end of a moving cutting module, an air collecting box is driven by wind power to drive a cooling block to be attached to a cut film in a self-adaptive mode under the action of a spring and an inclined block, heat is absorbed in time through a circulating cooling assembly, and meanwhile when an air collecting ring pushes the corresponding cooling block, the cooling block is cooled; a movable plate and a silica gel pressing ring pre-press a film before cutting under the cooperation of an inclined block, and are matched with the synergistic effect of a movable flattening assembly and a cooling abutting assembly, so that all parts form the process of pre-pressing before cutting, synchronous cooling constraint in cutting and flattening and shaping after cutting; and therefore, the effects that the thermal shrinkage effect and the rippled edge phenomenon can be effectively restrained when the thin film is cut through laser, and the cutting precision and the edge quality are improved are achieved.

The invention belongs to the technical field of thermal shrinkage label films, and particularly relates to a preparation method of a water-washing removable PETG label adhesive and application of a product of the water-washing removable PETG label adhesive, the water-washing removable PETG label adhesive is formed by adopting an emulsion polymerization method on the basis of PSt / P (BA-MMA) core-shell structure emulsion, and the application of the adhesive in PETG labels is provided. The problems that an existing adhesive is high in adhesive capacity and serious in residue are solved, the balance of adhesive force and cohesive force is achieved through the core-shell microsphere structure, the wetting power with a base material is reduced, the compatibility with the base material is reduced, and the performance that the adhesive is removed by washing is improved.

To provide a shrink film and a multilayer shrink film having excellent transparency and strength while enhancing heat shrinkability even when a polyethylene having a low degree of crystallization is used.SOLUTION: There is provided a shrink film which comprises a first polyethylene having a density of 0.910 to 0.930 g / cm3, a second polyethylene having a density of 0.890 g / cm3 or more and less than 0.910 g / cm3, silica dioxide having an average particle diameter of 0.1 μm or less and a glycerin fatty acid ester, contains the first polyethylene and the second polyethylene in a mass ratio of 80:20 to 60:40, contains 0.5 to 5 pts.mass of silica dioxide based on 100 pts.mass of the total of the first polyethylene and the second polyethylene and contains 0.5 to 3 pts.mass of the glycerin fatty acid ester. A multilayer shrink film has the shrink film.SELECTED DRAWING: None