2370 results about "Saturated carboxylic acid" patented technology

A γ,δ-unsaturated carboxylic acid silyl ester is prepared by reacting an α,β-unsaturated carboxylic acid ester with a hydrosilane or hydrosiloxane in the presence of tris(pentafluorophenyl)borane. γ,δ-Unsaturated carboxylic acid derivatives are readily prepared through fewer steps and in high yields.

A composition of matter comprising an amine acylated with a hydrocarbyl group substituted carboxylic acylating agent containing an average of from 1.3 to 1.6 groups derived from α,β-unsaturated carboxylic compounds per M_n of the hydrocarbyl group, wherein the hydrocarbyl group has M_n determined by GPC ranging from 1500 to 3000, the amine comprises polyamine bottoms and said acylated amine has total base number (TBN) ranging from 17 to 35. A method for preparing the composition, lubricating oils containing the composition and, in another embodiment, lubricating oil compositions of this invention further comprising a metal overbased sulfonate detergent.

Melt-processable, highly-neutralized ethylene, C3 to C8 alpha,beta ethylenically unsaturated carboxylic acid copolymers and process for making them. Copolymers are made by incorporating a C4 to less than a C36 aliphatic, mono-functional organic acid and neutralizing greater than 90% to 100% of the acid groups present concurrently with or subsequently to the incorporation of the organic acid.

A golf ball has a cover member and a core member. The cover member contains: 3 to 30 parts by weight of a thermoplastic elastomer containing polyamide; 5 to 50 parts by weight of a terpolymer ionomer containing ethylene, (meth)acrylic acid, and (meth)acrylic ester; 30 to 80 parts by weight of a copolymer ionomer containing ethylene and (meth)acrylic acid; and 1 to 20 parts by weight of an epoxidized-diene-based block copolymer. The core member is formed by vulcanizing a rubber composition containing: 100 parts by weight of a base rubber, A parts by weight of an alpha, beta-unsaturated carboxylic acid or a metal salt thereof, B parts by weight of an organic peroxide, and C parts by weight of a sulfide where A, B, and C satisfies the relationship:andA lies in the range from 25 to 45.

The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, and an inorganic filler. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer is formed by injection molding a single resin blend composed primarily of (A) a thermoplastic polyurethane and (B) a polyisocyanate compound, which resin blend contains a polyisocyanate compound in at least some portion of which all the isocyanate groups on the molecule remain in an unreacted state, and has a thickness of 0.5 to 2.5 mm, a Shore D hardness at the surface of 50 to 70. The golf ball has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 3.8 mm. The solid golf ball is advantageous overall in competitive use.

A flame retardant composition comprising(A) about 50 to about 95 percent by weight of at least one ethylene co-polymer selected from an ethylene/vinyl ester copolymer; ethylene/alpha, beta unsaturated carboxylate copolymer; and very low density ethylene/alpha-olefin copolymer; and(B) about 5 to about 50 percent by weight of an ethylene/alpha-olefin copolymer having been prepared with a single site catalyst, and, for each 100 parts by weight of component (A) and component (B) combined,(C) about 2 to about 50 parts by weight of a polyethylene modified with a functional group containing compound;(D) about 5 to about 250 parts by weight of a metal hydrate;(E) about 1 to about 12 parts by weight of a triazine ring containing compound; and(F) about 0.5 to about 5 parts by weight of a flame retardant compound selected from the group consisting of a boron compound, a molybdenum compound, and a silicone.

A process for preparing a water-absorbent resin made from an α,β-unsaturated carboxylic acid as an essential monomer characterized in that the process comprises allowing a metal chelating agent to be present at any step in the process in an amount of 0.001 to 6 parts by weight, based on 100 parts by weight of the α,β-unsaturated carboxylic acid; and adding a reducing agent or an oxidizing agent thereto in an amount of 0.001 to 6 parts by weight, based on 100 parts by weight of the α,β-unsaturated carboxylic acid before initiation of drying and/or during drying of a gelated product containing a water-absorbent resin obtained by polymerization.

A carbon-insertion-type palladium metal in which an amount of inserted carbon is 0.16 mol or more with respect to 1.0 mol of a palladium metal, and a carbon-insertion-type palladium metal in which a crystal face distance of a (111) face of a palladium metal is 2.270 Å or more are useful as raw materials of a palladium catalyst for use in an α,β-unsaturated carboxylic acid preparation reaction, and the like. The carbon-insertion-type palladium metal can preferably be prepared by reduction of palladium in a palladium compound having a chlorine content of 0 to 300 ppm.

The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes from 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, from 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer has a thickness of from 0.5 to 1.9 mm, and a Shore D hardness at the surface of from 50 to 70. The ball has at least one intermediate layer between the core and the cover, any one of which intermediate layer or layers has a surface hardness in Shore D units of from 40 to 60, the intermediate layer or layers having a total thickness of from 0.9 to 7.0 mm. The golf ball has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 3.8 mm. The solid golf ball is advantageous overall in competitive use.

Disclosed is an electrochemical device, which comprises: (A) a binder comprising polymer particles obtained from the polymerization of: (a) 20-70 parts by weight of a (meth)acrylic acid ester monomer; (b) 20-60 parts by weight of a vinyl monomer; and (c) 0.01-30 parts by weight of an unsaturated carboxylic acid monomer, based on 100 parts by weight of a binder polymer; and (B) electrochemical cells stacked multiply by using the binder, wherein the binder allows electrode active material particles in an electrode to be fixed and interconnected among themselves and between the electrode active material and a collector, and the electrode and a separator that is in contact with the electrode are bonded to each other by way of hot fusion. The binder is also disclosed. The binder has excellent adhesion and thermal bonding characteristics, and thus is useful for an electrochemical device comprising multiply stacked electrochemical cells, and can improve the overall quality of a battery.

The present invention relates to an industrially beneficial method of manufacturing golf balls which includes the steps of pre-preparing a masterbatch of an unsaturated carboxylic acid and/or a metal salt thereof by mixing an unsaturated carboxylic acid and/or a metal salt thereof with a rubber material, preparing a rubber composition that contains the rubber material by using the masterbatch, and employing a material obtained by molding the rubber composition under heat as a golf ball component. The masterbatch is composed of:

(A) from 20 to 100 wt % of a modified polybutadiene obtained by a modification reaction wherein a polybutadiene having a vinyl content of from 0 to 2%, a cis-1,4 bond content of at least 80% and an active end is modified at the active end with at least one type of alkoxysilane compound, and

(B) from 80 to 0 wt % of a diene rubber other than Ingredient A.

such that ingredients A and B are included in a combined amount of 100 wt %, and

(C) an unsaturated carboxylic acid and/or a metal salt thereof.

The present invention is an improved polymeric resin composition comprising or consisting essentially of from about 70 wt % to about 79 wt % units derived from ethylene and from about 21 wt % to about 30 wt % units derived from an α,β-unsaturated carboxylic acid having from 3 to 8 carbons. Resins of the present invention are particularly suitable for preparing transparent laminates useful as glazing elements that provide a greater measure of safety than non-laminated glazing elements. Laminates of the present invention have 3% haze or less without the addition of amines.

The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes from 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, from 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer is formed by injection molding a single resin blend composed primarily of (A) a polyurethane material and (B) a polyisocyanate compound, which resin blend includes a polyisocyanate compound in at least some portion of which all the isocyanate groups on a molecule remain in an unreacted state. The cover layer has a thickness of from 0.5 to 2.5 mm and a Shore D hardness at the surface of from 50 to 70. The golf ball has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 3.8 mm. The solid golf ball is advantageous overall in competitive use.

The present invention provides a pressure sensitive adhesive composition for optical members, which is excellent in durability, re-releasability and stress relaxation, as well as a pressure sensitive adhesive composition for optical members, which hardly increases adhesion after storage for a long time and does not leave a residual adhesive on glass upon disposal or repair. The pressure sensitive adhesive composition for optical members according to the present invention comprises 100 parts by weight of an acrylic polymer (A) having a weight-average molecular weight of 500,000 or more, containing at least 50 wt % alkyl (meth)acrylate having an alkyl group with 5 or more carbon atoms and 0.2 to 2 wt % unsaturated carboxylic acid as the monomer unit, 0.1 to 4 parts by weight of an acrylic polymer (B) having a weight-average molecular weight of 2,000 to 50,000, containing at least 70 wt % alkyl(meth)acrylate and 1 to 7 wt % unsaturated carboxylic acid as the monomer unit and having a higher carboxylic acid equivalent than that of the acrylic polymer (A), 0.01 to 1 part by weight of a silane coupling agent, and a crosslinking agent.

A mixture having good thermal stability, flow and moldability and suitable as a golf ball-forming material is obtained when a base resin comprising a (metal ion-neutralized) olefin-unsaturated carboxylic acid-unsaturated carboxylate ternary random copolymer and optionally a (metal ion-neutralized) olefin-unsaturated carboxylic acid binary random copolymer is blended with specific proportions of a fatty acid and/or fatty acid derivative and a basic inorganic metal compound capable of neutralizing acidic groups left unneutralized in the base resin and fatty acid. Using the same material, high-rebound golf balls can be effectively manufactured.

A multi-piece solid golf ball has a solid core obtained by molding and vulcanizing a rubber composition which includes (A) a base rubber containing a polybutadiene synthesized using a rare-earth catalyst, (B) an unsaturated carboxylic acid and/or a metal salt thereof, (C) an organic sulfur compound, (D) an inorganic filler and (E) an organic peroxide. The core is enclosed within a mantle of one or more layer which is made primarily of a thermoplastic resin and has a Durometer D hardness of 30 to 70. The mantle is enclosed within a cover which is made primarily of a thermoplastic polyurethane and which has a Durometer D hardness of 40 to 60 that is lower than the Durometer D hardness of the outermost layer of the mantle. This construction provides the golf ball with an outstanding rebound.

The invention relates to a polycarboxylic acid water reducing agent, a preparation method and an application thereof, and belongs to the technical field of concrete additives. The polycarboxylic acid water reducing agent is prepared by using industrializedly produced isobutenol polyether or isoamylenol polyether with relatively good performances as a monomer A, unsaturated carboxylic acid, unsaturated acid anhydride or unsaturated ester as a monomer B and unsaturated sulfonic acid and salts thereof as a monomer C, according to a water reducing agent functional group theory and a polycarboxylic acid water reducing agent molecule design theory; and co-polymerizing the monomer A, B and C. A polycarboxylic acid water reducing agent product is obtained in a water solution via a one-step method, under initiation of a redox initiation system, by introducing carboxyls or ester groups having the functions of delayed coagulation and slump resistance, and the sulfonic acid groups having high water reducing effect into the molecular structure of the water reducing agent and controlling a material ratio and material-feeding modes. Besides, cost can be further reduced by selecting a proper redox system to make the polymerization carried out at a low temperature. The method is suitable for industrialize production.

Economical and efficient processes for producing an alpha, beta-unsaturated carboxylic acid heterocycle-inserted ester and an alpha,beta-unsaturated carboxylic acid polyheteroalkylene ester as well as a catalyst suited for use in economically and efficiently producing an alpha,beta-unsaturated carboxylic acid ester are provided. The invention provides (1) a process for producing an alpha,beta-unsaturated carboxylic acid ester which comprises reacting an alpha,beta-unsaturated carboxylic acid ester with a heterocyclic compound, (2) a process for producing an alpha,beta-unsaturated carboxylic acid ester which comprises reacting an alpha,beta-unsaturated carboxylic acid with a heterocyclic compound in the presence of a polymerization inhibitor and a metal oxide catalyst, and (3) a catalyst for the production of an alpha,beta-unsaturated carboxylic acid ester comprising a metal oxide.