387 results about "Hindered amine light stabilizers" patented technology

The invention belongs to the technical field of building materials, and discloses a preparation method of reflective heat-insulation waterproof real stone paint, which comprises the following three process stages: core layer synthesis, shell layer loading and real stone paint integration: coating a continuous SiO layer on the surface of nano TiO in situ to form TiO-coated SiO particles; graphene quantum dots and a hindered amine light stabilizer are loaded on the surfaces of TiOatSiO particles to form a composite functional filler; adding the composite functional filler into the acrylic emulsion base material in batches at a low speed, and adjusting the rheological property with the aid to obtain a finished product. The preparation process disclosed by the invention is completely compatible with an existing real stone paint industrial production line, does not need to add special equipment, and has excellent reflective heat insulation, heat preservation, water resistance, weather resistance and aging resistance and large-scale industrial feasibility; the technical problems of resin oxidative degradation caused by TiO photocatalytic activity, rapid attenuation of solar radiation reflectivity, failure of waterproof and hydrophobic performance and easiness in damage and stripping of a coating structure of the existing nano TiO-based reflective heat-insulation real stone paint are solved.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention relates to the technical field of preparation of building external wall thermal insulation materials, in particular to a building external wall thermal insulation board based on pearl wool and a preparation method of the building external wall thermal insulation board. The core layer is prepared from the following raw materials in parts by weight: 40 to 60 parts of pearl wool particles, 5 to 15 parts of graphene-loaded expanded graphite, 3 to 10 parts of nano silicon dioxide aerogel, 10 to 20 parts of ammonium polyphosphate, 5 to 12 parts of pentaerythritol, 3 to 8 parts of melamine, 15 to 25 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride grafted polyethylene, 2 to 6 parts of nano montmorillonite and 1 to 5 parts of silicon carbide whisker; the composite material is prepared from the following components in parts by weight: 0.5-2 parts of a silane coupling agent KH560, 0.2-0.8 part of an antioxidant 1010, 3-8 parts of amino-terminated polyether and 0.3-1 part of a hindered amine light stabilizer 770. The thermal insulation board is excellent in thermal insulation, mechanical property and flame retardant property, good in weather resistance, stable in size and high in construction adaptability, pearl wool can be recycled, and the thermal insulation board has practical and environment-friendly values.

The invention relates to the technical field of coatings, in particular to an acrylate-epoxy resin composite coating and a preparation method thereof. According to the technical scheme, the coating is prepared from 25 to 35 parts of methyl methacrylate, 15 to 25 parts of butyl acrylate, 10 to 20 parts of epoxy resin E-5110, 8 to 15 parts of organic silicon modified acrylate prepolymer, 5 to 12 parts of fluorocarbon modified epoxy resin, 4 to 8 parts of core-shell structure corrosion inhibition nano container, 1 to 3 parts of functionalized graphene quantum dots and 4 to 10 parts of polyhedral oligomeric silsesquioxane maleimide modified amine curing agent. And 1-3 parts of a hindered amine light stabilizer. By integrating the core-shell structure corrosion inhibition nano container, the functionalized graphene quantum dots and the photo-thermal dual responsive curing agent component, the sensing, response and self-repairing of the coating on damage are realized, and long-acting corrosion resistance, weather resistance, bacteria resistance, mechanical property balance and intelligent maintenance are considered; and efficient and economical full-period protection is provided for equipment in an extreme environment.

The invention relates to the technical field of anti-drag films, and particularly discloses an ultraviolet aging resistant anti-drag film and a preparation process thereof.A hindered amine light stabilizer HALs and a silane coupling agent KH-560 are introduced into substrate TPU resin, the strength, heat resistance and aging resistance of the material are enhanced, then an adhesive layer is formed on a substrate film, and the anti-drag film is prepared. A disulfide bond in the adhesive layer has a reversible fracture-self-repairing function, the fatigue resistance of the material is enhanced, the long-term service life of the material is prolonged, the surface layer is acrylic resin formed through copolymerization, the structure comprises a flexible alkyl chain and a siloxane chain segment, a microstructure is formed through hot rolling, the aerodynamic performance is optimized, and the purpose of reducing frictional resistance is achieved.

The invention belongs to the technical field of preparation and surface protection of polyurethane coatings, and particularly relates to weather-resistant polyurethane and a preparation method thereof. The coating provided by the invention is composed of a component A and a component B according to a weight ratio of 1: (0.2-0.4). The component A is prepared from water-based fluorine-containing hydroxy acrylic dispersion resin with a high hydroxyl value, GMA (glycidyl methacrylate) grafted modified water-based acrylic dispersion resin, a benzotriazole ultraviolet light absorber, a light hindered amine stabilizer, rutile titanium dioxide, wet sericite powder, nano zinc oxide and auxiliaries; and the component B comprises an aliphatic isocyanate curing agent and propylene glycol diacetate. By constructing a quadruple synergistic weather-resistant mechanism of ultraviolet absorption, free radical capture, physical shielding and structural densification, the weather resistance and corrosion resistance of the coating are remarkably improved while the coating keeps excellent adhesive force (0-1 level) and hardness (2H-3H), the color change delta E is smaller than or equal to 1.8 after artificial accelerated aging for 1000 hours, the gloss loss rate is smaller than or equal to 23%, and the weather resistance and corrosion resistance of the coating are greatly improved. And the corrosion spreading width of a 600-hour salt spray test lineation is less than or equal to 2.3 mm.

The invention discloses a UV-cured high-weather-resistance optical thin film and a preparation method thereof, and relates to the technical field of optical thin films. The optical film is prepared by taking polyethylene glycol terephthalate as a base material and coating the base material with a UV curing coating, and the UV curing coating comprises the following raw materials in parts by weight: 15-20 parts of aliphatic polyurethane acrylate, 5-8 parts of perfluorobutyl ethyl acrylate, 8-12 parts of hydroxyethyl acrylate, 6-10 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, the invention relates to a UV (ultraviolet)-resistant coating which is prepared from the following raw materials in parts by weight: 1-2 parts of 2, 6-hexanediol diacrylate, 5-8 parts of trimethylolpropane triacrylate, 30-40 parts of modified epoxy acrylate, 1-2 parts of a silane coupling agent KH-570, 2-3 parts of a photoinitiator 1173, 0.5-1.2 parts of a modified ultraviolet absorbent UV-327, 0.8-1.5 parts of a hindered amine light stabilizer 540, 0.3-0.8 part of an antioxidant 1010, 0.09-0.12 part of an ultraviolet absorbent Tinuvin400 and 0.2-0.5 part of polyether modified polydimethylsiloxane. According to the UV-cured high-weather-resistance optical thin film, polyethylene glycol terephthalate is used as a base material, key raw materials such as a UV-cured coating with a scientific formula, modified epoxy acrylate and the like are finely prepared, a two-stage curing process is adopted, and the weather resistance is excellent.

The invention provides a novel hindered amine light stabilizer as well as a preparation method and application thereof, and relates to the field of light stabilizers. According to the preparation method of the novel hindered amine light stabilizer, specific dibasic acid dimethyl ester and 2, 2, 6, 6-tetramethylpiperidinol are used as raw materials, an alkane solvent or a benzene solvent is used as a solvent, and a catalytic reaction solution is obtained through a heating reaction under the condition of a catalyst; and neutralizing and washing the catalytic reaction liquid to obtain the novel hindered amine light stabilizer. According to the preparation method, ideal preparation effects (such as purity, yield and the like) can be achieved, meanwhile, the chroma of the product is effectively reduced, the problem that the product is prone to yellowing due to the fact that the hindered amine light stabilizer absorbs visible light is solved, and the compatibility and stability of the hindered amine light stabilizer and a high polymer material are further improved.

The invention relates to a thermoplastic molding composition (P) comprising: (A) thermoplastic polymer composition (A) comprising: (A-1) 10 to 50 wt.-% of graft copolymer (A-1), (A-2) 1 to 50 wt.-%, of thermoplastic polymer matrix (A-2) based on one or more vinylaromatic copolymers, (A-3) 20 to 50 wt.-%, of polymerized alkyl methacrylate component (A-3), and (A-4) 0 to 45 wt.-% of comonomer which is copolymerized with the at least one polymerized alkyl methacrylate component (A-3), where the sum of (A-1), (A-2), (A-3) and optional comonomers (A-4) is 83.2 to 99.8 wt.-%; (B) a hindered amine light stabilizer composition (B), comprising at least two of substances (B-1) to (B-3): (B-1) 0 to 0.9 wt.-%, of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure (B-2) 0 to 0.9 wt.-%, of a hindered amine light stabilizer mixture having a monopiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the monopiperidine structure, and (B-3) 0 to 2 wt.-%, of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups with at least one alkyl group at each of the 2 and 6 positions of the piperidine groups (C) 0 to 5 wt.-%, of one or more further additives (C), different from (B); and (D) 0 to 10 wt.-%, of colorants, dyes and / or pigments (D), different from (C); wherein the constituents (A) to (D) sum up to 100 wt.-% of the molding composition (P).

The invention belongs to the technical field of high polymer materials and electric power engineering protection, and particularly relates to an MPP power cable protection pipe containing a rare earth anti-aging system and a preparation method of the MPP power cable protection pipe. The protection tube is composed of rare earth coordination modified polypropylene, N, N '-bis (2-hydroxyethyl) adipamide, an antioxidant 1010, a light stabilizer 622, a hindered amine light stabilizer 944, a lubricant and an anti-ultraviolet absorbent. Rare earth ions and polypropylene grafted maleic anhydride form a stable coordination structure, small organic molecules enhance interface bonding through hydroxyl and acylamino hydrogen bonds, and multi-point stability of molecular chains is achieved. The thermal oxidation resistance, ultraviolet aging resistance and thermal deformation resistance of the material are remarkably improved, and the prepared cable protection tube has excellent mechanical strength, heat resistance and long-term weather resistance.

The application provides a hindered amine light stabilizer and a preparation method thereof, and the preparation method comprises the following steps: putting N, N-bis(2, 2, 6, 6-tetramethyl-4-piperidyl) 1, 6-hexanediamine and an organic solvent into a reaction bottle, heating to 50-80 DEG C, adding methyl acrylate into the system dropwise, obtaining an intermediate I through an addition reaction, and then obtaining a crude product through an ester exchange reaction of the intermediate I and tetramethylpiperidinol in the presence of a catalyst and an organic solvent, washing with water, decoloring, filtering, cooling and crystallizing, filtering and drying to obtain the product; the light stabilizer obtained by the application has multiple hindered amine functional groups, has good heat resistance and extraction resistance, and has good compatibility with resin.

The application belongs to the field of polymer materials and power engineering protection technology, and particularly relates to a MPP power cable protection pipe containing a rare earth anti-aging system and a preparation method thereof. The protection pipe is composed of rare earth coordination modified polypropylene, N,N'-bis(2-hydroxyethyl)adipamide, antioxidant 1010, light stabilizer 622, hindered amine light stabilizer 944, lubricant and ultraviolet absorption agent. Rare earth ions and polypropylene grafted maleic anhydride form a stable coordination structure, and organic small molecules enhance the interface combination through hydrogen bonds of hydroxyl and amide groups, so that the molecular chain is stably connected at multiple points. The application significantly improves the thermal oxidation resistance, ultraviolet aging resistance and thermal deformation performance of the material, and the prepared cable protection pipe has excellent mechanical strength, heat resistance and long-term weather resistance.

The invention discloses a weather-resistant heat-insulation waterproof coating for an outer wall and a preparation method of the weather-resistant heat-insulation waterproof coating. The waterproof coating comprises the following components in parts by weight: 27-35 parts of modified acrylate polymer emulsion, 35-50 parts of composite filler, 5-10 parts of a curing system, 4-8 parts of a coalescing agent, 0.1-0.5 part of a defoaming agent, 0.3-0.8 part of a flatting agent, 0.2-0.6 part of a mildew preventive, 0.5-1.0 part of a thickening agent and 1-5 parts of a pH regulator, the modified acrylate polymer emulsion is prepared by carrying out pretreatment and silanization modification on cardanol and then carrying out monomer pre-emulsification and free radical polymerization. According to the waterproof coating provided by the invention, a Si-O-C network and a hindered amine free radical capture system are introduced, so that the weather resistance is improved; fluoride-nano silicon dioxide is used for constructing a roughness-low surface energy synergistic waterproof interface; acid-washed fly ash floating beads, silicon dioxide aerogel and expanded perlite filler are compounded to form multiple heat conduction scattering paths so as to realize cross-scale porous filler heat preservation; the waterproof coating can serve in complex environments with large temperature difference fluctuation, acid rain and the like.

The invention relates to the technical field of industrial production, and discloses an anti-aging corrosion-resistant photovoltaic cable, which comprises an insulating layer, uniformly distributed conductors are arranged on the inner diameter of the insulating layer, an insulating layer is arranged on the outer diameter of the insulating layer, a protective layer is arranged on the outer diameter of the insulating layer, and a sheath layer is arranged on the outer diameter of the protective layer. Reinforcing layers which are uniformly distributed are arranged between the sheath layer and the protective layer, the reinforcing layers are uniformly arranged and spirally wound on the surface of the protective layer, the insulating layer is made of a modified polyolefin material, and the protective layer is formed by blending fluoroplastic and an anti-aging additive. By adopting a multi-layer structure, the antioxidant can capture free radicals generated by thermo-oxidative aging, the 2-hydroxy-4-n-octyloxybenzophenone can absorb ultraviolet rays to reduce photo-oxidative damage, the protective layer contains a hindered amine light stabilizer and can circularly capture the free radicals and regenerate antioxidant groups, and the sheath layer contains polytetrafluoroethylene micro powder and prevents corrosion medium permeation. And the comprehensive effects of aging resistance and corrosion resistance are achieved.

The invention belongs to the field of polyester resins, and provides a weather-resistant polyester resin for low-temperature curing and a preparation method thereof. A three-step progressive design that a polyester prepolymer is terminated by silane and then is subjected to hydrolytic polycondensation with tetraethyl orthosilicate to construct an organic-inorganic covalent hybrid network is adopted; through cooperation of the condensation catalyst, the hindered amine light stabilizer and the ultraviolet absorbent, the mechanical properties that the pencil hardness reaches the HB level or above and the cross-cut test level is not higher than the first level under the low-temperature curing condition of not higher than 100 DEG C are achieved, and the long-term weather resistance that the color difference is not larger than 2.0 and the gloss retention rate is not lower than 80% after 500-hour artificial accelerated aging is achieved. The technical problems of poor storage stability and difficulty in consideration of high solid content and low viscosity caused by insufficient low-temperature curing capacity and non-uniform organic-inorganic hybridization of the traditional polyester resin are solved, and the polyester resin has wide application value in the fields of building coatings, automobile refinishing paints, wood coatings and the like with strict requirements on low-temperature curing and weather resistance.

The invention discloses a photovoltaic cable sheath material with ultraviolet aging resistance and long service life. Comprising the following components in parts by weight: 100 to 120 parts of high-density polyethylene, 0.3 to 0.5 part of a benzotriazole ultraviolet light absorber, 0.5 to 0.8 part of a hindered amine light stabilizer, 0.2 to 0.5 part of an antioxidant, 3 to 5 parts of salicylate intercalated magnesium aluminum hydrotalcite, 0.02 to 0.05 part of cerium acetylacetonate, 2 to 4 parts of rutile type nano titanium dioxide, 3 to 5 parts of a compatilizer and 0.5 to 1 part of a dispersant. The photovoltaic cable is prepared from the anti-ultraviolet aging long-life photovoltaic cable sheath material, an insulating layer material and a conductor, so that the obtained photovoltaic cable sheath material and the photovoltaic cable have excellent anti-ultraviolet capability and thermal aging resistance, and have relatively long service life.

The invention relates to the technical field of nano-composite water-based resin system design and function coordinated regulation and control, in particular to environment-friendly high-gloss wear-resistant water-based epoxy floor paint and a preparation method thereof. The environment-friendly high-gloss wear-resistant water-based epoxy floor paint is prepared from self-emulsifying water-based epoxy resin emulsion, a modified water-based epoxy curing agent containing biguanidyl and the like; the preparation method comprises the following steps: carrying out synergistic modification on a three-dimensional composite wear-resistant filler containing nano silicon dioxide-carbon nanotube-graphene through a silane coupling agent and dopamine; the light response type composite light stabilizer is compounded by a titanium dioxide grafted hindered amine light stabilizer and a benzophenone light stabilizer; a phase change temperature adjusting microcapsule and a nano-silver-chitosan antibacterial agent can also be added, so that multiple functions are realized. According to the floor paint disclosed by the invention, through an innovative formula and process, wear resistance, luster and weather resistance are remarkably improved, and toughness and crack resistance are enhanced; and the preparation method is environment-friendly and efficient, meets the requirements of multiple scenes, and has high economic value.

The invention relates to a cable sheath material, and particularly discloses a weather-proof low-smoke halogen-free flame-retardant polyolefin cable sheath material and a preparation method thereof. The cable sheath material is prepared from 30 to 45 parts of low-density polyethylene, 10 to 30 parts of high-impact homo-polypropylene, 15 to 30 parts of graft modified flexibilizer, 30 to 50 parts of main flame retardant, 1 to 5 parts of coupling agent, 10 to 30 parts of phosphorus-nitrogen synergistic flame retardant, 4 to 10 parts of efficient smoke suppressant, 0.2 to 0.8 part of hindered phenol main antioxidant, 0.4 to 1.2 parts of thioester auxiliary antioxidant, 0.4 to 1.0 part of hindered amine light stabilizer, 0.5 to 1.5 parts of ultraviolet light absorber and 2.5 to 2.5 parts of weather resistance enhancer. 5.0 parts of a lubricant, 0.5 to 2.0 parts of a lubricant, and 0.1 to 0.8 part of an anti-copper agent. The mechanical property, the electrical insulation property and the weather resistance of the sheath material are effectively improved, an efficient synergistic flame retardant effect can be obtained, the flame retardant property is excellent, and a finished product can obtain excellent weather resistance, low-smoke zero-halogen property, flame retardant property, mechanical property, electrical insulation property and the like.

The invention provides high-weather-resistance and anti-aging silicone rubber and a preparation method and application thereof.The high-weather-resistance and anti-aging silicone rubber is prepared from, by mass, 100 parts of methyl vinyl silicone rubber, 30-60 parts of white carbon black, 6-8 parts of an alkyl silane coupling agent, 0.5-2 parts of a hindered amine silane coupling agent, 0.5-2 parts of a vinyl silane coupling agent and 3-5 parts of vinyl MQ silicone resin. 1-1.5 parts of vinyl hydroxyl silicone oil; 1-3 parts of organic peroxide; wherein the hindered amine silane coupling agent is obtained by reacting hindered amine with an isocyanate silane coupling agent. Through the formula design, the excellent toughness of the silicone rubber can be maintained, and meanwhile, the long-term weather resistance and the mechanical property retention rate of the material under ultraviolet radiation and humid and hot conditions can be remarkably improved.

The invention discloses an anti-aging bronze powder pigment and a preparation method and application thereof in the technical field of bronze powder pigments, and the anti-aging bronze powder pigment takes copper-zinc alloy as a base material, and is sequentially connected with a composite chemical passivation layer, a functionalized organic-inorganic hybrid compact barrier layer and a surface super-hydrophobic layer through chemical bonding from inside to outside; wherein the composite chemical passivation layer is formed by treating a passivation solution containing phytic acid, ammonium metavanadate and sodium tungstate; the functionalized organic-inorganic hybrid compact barrier layer is constructed by a silane mixed solution containing 3-mercaptopropyltriethoxysilane, a reaction type ultraviolet light absorber Si-BP, a reaction type hindered amine light stabilizer Si-HALS and tetraethyl orthosilicate through a sol-gel process. Through the design of a multi-layer composite system, the aging resistance of the bronze powder is improved, and meanwhile, the optical decoration performance can be reserved to the maximum extent, so that the dual strict requirements of high-end outdoor applications such as automobile coatings on durability and visual texture can be met.

The invention relates to the field of high-performance composite materials, and discloses a basalt fiber / weather-resistant polyurethane resin-based composite material as well as a preparation method and application thereof. Comprising the following steps: mixing polyether polyol, polyester polyol, a blocked isocyanate prepolymer and a DA monomer to react to obtain a polyurethane prepolymer; mixing a polyurethane prepolymer, a nano silicon dioxide modifier, a hindered amine light stabilizer, a microencapsulated latent curing agent and a phosphorus-nitrogen synergistic flame retardant to obtain a polyurethane resin mixture; the preparation method comprises the following steps: coating the surface of basalt fiber with a silane coupling agent to obtain modified basalt fiber, forming an epoxy nano-alumina coating and a polyurethane resin mixture layer on the surface of the modified basalt fiber, soaking in a polyurethane resin mixture, and curing to obtain the basalt fiber / weather-resistant polyurethane resin-based composite material. According to the scheme, the basalt fibers are coated in a gradient manner to form a chemical-physical synergistic enhancement structure, so that the interfacial force between the polyurethane resin and the basalt fibers is enhanced.

The invention provides a high-performance polypropylene plastic bucket material and a preparation method thereof, and belongs to the field of high-performance polypropylene plastic. The high-performance polypropylene plastic bucket material is prepared from the following raw materials in parts by weight: 100 parts of polypropylene resin, 8 to 15 parts of hydrogenated styrene-butadiene-styrene block copolymer, 3 to 8 parts of modified nano silicon dioxide, 2 to 5 parts of epoxy functionalized polypropylene, 3 to 10 parts of ethylene-vinyl acetate copolymer, 0.2 to 0.5 part of beta crystal form nucleating agent and 1.5 to 4 parts of hyperbranched dynamic cross-linking agent, the composition comprises the following components in parts by weight: 1-4 parts of maleic anhydride grafted polypropylene, 0.3-0.6 part of an antioxidant, 0.2-0.4 part of a hindered amine light stabilizer and 0.1-0.3 part of an ultraviolet light absorber. By constructing a multi-component and multi-network synergistically enhanced polypropylene composite material system, the problem that rigidity, toughness, long-term stability and weather resistance are difficult to consider at the same time is essentially and synergistically solved.

The invention relates to the technical field of waterproof coatings, in particular to a photo-initiation cold coating type non-curing rubber asphalt waterproof coating and a preparation method thereof, and the photo-initiation cold coating type non-curing rubber asphalt waterproof coating comprises an asphalt-based main material, a photo-curing agent and epoxy resin; the light curing agent is composed of a photoinitiator, a rubber monomer and a hindered amine light stabilizer, and the photoinitiator comprises a benzothiophene compound; the waterproof coating is in a single-component paste state, can be constructed at normal temperature, and is cured to form a waterproof coating film after being irradiated by ultraviolet rays; according to the technical scheme, a cross-linking system of the light curing agent and the epoxy resin not only keeps the creep deformation and self-healing characteristics of non-cured rubber asphalt, but also improves the heat resistance, acid, alkali and salt resistance and bonding performance of a coating film through a three-dimensional network cross-linking structure, and it is ensured that a waterproof layer adapts to building structure deformation and severe environments for a long time.

The invention discloses an anti-ultraviolet functional plastic particle and a preparation method thereof, and belongs to the technical field of polymer modified materials. The plastic particles are prepared from polyolefin resin subjected to organic silicon-phenolic hydroxyl synergistic grafting modification, 2, 4-dihydroxyacetophenone, an antioxidant, a hindered amine light stabilizer, a lubrication dispersant and an anti-yellowing agent. A siloxane-phenolic hydroxyl bifunctional chain segment is introduced into the surface of a molecular chain of the polyolefin resin subjected to organic silicon-phenolic hydroxyl synergistic grafting modification, so that a flexible-rigid synergistic interface layer is formed; the 2, 4-dihydroxyacetophenone has a hydroxyl and carbonyl conjugated structure and can form hydrogen bond complexation with a matrix, so that free radical degradation is effectively inhibited. The preparation method disclosed by the invention comprises the following three steps: grafting reaction of polyolefin resin subjected to organic silicon-phenolic hydroxyl synergistic grafting modification, high-speed mixing and melt blending granulation. Tests show that after the plastic particles are subjected to 365nm ultraviolet radiation for 500h, the tensile strength retention rate exceeds 94%, the chromatic aberration delta E is less than or equal to 1.5, the oxidation induction time is prolonged to 55min, and the plastic particles have excellent ultraviolet aging resistance, yellowing resistance and thermal oxidation stability.

The invention relates to the technical field of waterproof coiled materials, in particular to an anti-ultraviolet SBS waterproof coiled material and a preparation method thereof.The waterproof coiled material comprises a base layer, an anti-ultraviolet SBS asphalt layer and a thin film layer, the anti-ultraviolet SBS asphalt layer comprises asphalt, an SBS elastomer, asphalt softening oil, an anti-aging waterproof multifunctional agent, composite filler, an initiator and the like, and the thin film layer is prepared from the following components; the anti-aging waterproof multifunctional agent prepared by the invention takes macromolecular polysiloxane as a main chain and simultaneously contains a double hindered amine structure and a benzoxazole structure, and the benzoxazole structure not only can cooperate with a polysiloxane structure to improve the thermal aging resistance of a material, but also can endow a coiled material with a rigid structure; the double hindered amine structure has better ultraviolet aging resistance and does not influence the improvement of silicon-oxygen bonds on the waterproof performance of the coiled material, and the functional agent can make the asphalt coiled material become a coiled material resistant to thermal aging, ultraviolet aging and chemical substance erosion.

The invention relates to the technical field of film materials, and particularly discloses an environment-friendly high-strength salt film and a preparation method thereof.The salt film is prepared from, by weight, 90-110 parts of grafted PVC, 35-45 parts of environment-friendly plasticizer, 3.0-4.5 parts of heat stabilizer, 0.3-0.6 part of benzotriazole ultraviolet light absorber, 0.4-0.8 part of hindered amine light stabilizer, 0.2-0.4 part of antioxidant, 0.5-1.5 parts of lubricant, 10-20 parts of filler and 1-2 parts of degradation promoting agent. Through the cooperation of the ultraviolet light absorber, the light stabilizer and the antioxidant, the anti-aging performance is realized, and the service life of the smoke film is prolonged; meanwhile, by enhancing the compatibility between the PVC resin and the auxiliaries, migration of the auxiliaries is reduced, and pollution to brine is reduced; in addition, degradation of PVC is enhanced by adopting a degradation promoting agent of a microbial environmental degradation triggering mechanism, non-interference to the service life and high-efficiency degradation after waste are realized, and two contradictory performances of environmental friendliness, degradability and weather resistance are met.

The invention relates to a weather-resistant silane self-crosslinking low-smoke halogen-free flame-retardant polyolefin cable material and a preparation method thereof. Comprising the following components in parts by weight: 50 to 70 parts of EVA (Ethylene-Vinyl Acetate) resin, 20 to 30 parts of POE (Polyolefin Elastomer) resin, 80 to 100 parts of nano aluminum hydroxide, 5 to 10 parts of zinc borate, 2 to 4 parts of gamma-(methacryloyloxy) propyltrimethoxysilane (KH570), 0.2 to 0.4 part of a crosslinking initiator, 2 to 4 parts of anti-UV (Ultraviolet) master batch, 3 to 5 parts of nano titanium dioxide, 0.3 to 0.6 part of a hindered amine light stabilizer and 0.03 to 0.06 part of an organic tin catalyst. The composite material has the advantages of strong weather resistance, flame retardant rating up to UL94V0, smoke density Dsmax less than 30, high cold bending qualification rate at-40 DEG C, low dielectric loss and the like, is suitable for photovoltaic cables, meets 25-year outdoor service requirements, and solves the problems of weather resistance, flame retardance, mechanical property balance and the like of existing photovoltaic cables.

The invention belongs to the technical field of polylactic acid filter materials, and discloses an antibacterial electret polylactic acid composition for melt-blowing, a preparation method of the antibacterial electret polylactic acid composition, polylactic acid granules, application of the polylactic acid granules and polylactic acid melt-blown cloth, the antibacterial electret polylactic acid composition for melt-blowing comprises polylactic acid, a plasticizer, a composite electret and a guanidine salt polymer, optionally a dispersant and optionally an antioxidant; relative to 100 parts by weight of polylactic acid, the content of the plasticizer is 0.5-2 parts by weight, the content of the composite electret is 0.5-3 parts by weight, the content of the guanidine salt polymer is 0.3-3 parts by weight, the content of the dispersing agent is 0-0.3 part by weight, and the content of the antioxidant is 0-0.2 part by weight; the composite electret comprises tourmaline powder, a hindered amine light stabilizer, hydroxy stearate and a dendritic polymer. The composite electret and the guanidine salt polymer are added into the polylactic acid composition, so that the antibacterial polylactic acid melt-blown cloth with excellent antibacterial effect and efficient filtering efficiency is prepared.

The application discloses a waterproof coating for outer wall weather resistance, heat insulation and heat preservation and a preparation method thereof. The waterproof coating comprises the following components in parts by weight: modified acrylate polymer emulsion 27-35 parts, composite filler 35-50 parts, curing system 5-10 parts, film forming aid 4-8 parts, defoaming agent 0.1-0.5 parts, leveling agent 0.3-0.8 parts, mildew-proof agent 0.2-0.6 parts, thickening agent 0.5-1.0 parts and pH regulator 1-5 parts. The modified acrylate polymer emulsion is prepared by pretreating and silanization modifying cardanol, monomer pre-emulsification and free radical polymerization. The waterproof coating provided by the application introduces Si-O-C network and hindered amine free radical capture system to improve weather resistance; fluorine compound-nano silicon dioxide constructs roughness-low surface energy synergistic waterproof interface; acid washing fly ash floating beads, silica aerogel and expanded perlite filler are compounded to form multiple heat conduction scattering paths to realize cross-scale porous filler heat preservation; and the waterproof coating can serve in complex environments such as large temperature difference fluctuation and acid rain.

The invention relates to a high-impact PC-elastomer composite battery shell and a preparation method thereof, and belongs to the technical field of battery shell manufacturing. The shell adopts a three-layer composite structure design and comprises an outer polycarbonate layer of which the end group is grafted with a hindered amine light stabilizer, a middle thermoplastic polyurethane layer containing a double-crosslinking network and an inner glass fiber reinforced polycarbonate layer. Through material modification, uniform distribution and dense combination of all layers of materials are realized, the impact resistance and the weather resistance of the battery shell are remarkably improved, and the excellent bonding property of an interface is ensured.