280results about How to "Strong salt resistance" patented technology

The invention discloses a novel aluminum-based anti-collapse agent and provides a strong-inhibition and strong-blockage aluminum-based anti-collapse water-based drilling fluid system by combining the performance requirement of drilling fluid based on the novel aluminum-based anti-collapse agent. The strong-inhibition and strong-blockage aluminum-based anti-collapse water-based drilling fluid contains the following substances in parts by weight: 100 parts of fresh water, 4 parts of sodium bentonite, 0.1-1 part of a coating inhibitor, 0.3-5 parts of a strong amine inhibitor, 0.5-5 parts of a filtrate reducer, 0.3-1 part of a thickening agent, 1-5 parts of a lubricating agent and 0.5-5 parts of an efficient aluminum-based blocking agent. The key technique of the invention is to provide use of the aluminum-based anti-collapse agent as a mud rock blocking anti-collapse agent in drilling fluid. After an aluminum-based blockage anti-collapse agent acts with a rock core with same thickness, the time required for transferring differential pressure of 1MPa is substantially shortened in comparison with the time (about 1.5 hours) required for transferring differential pressure in a blank rock core, so that the aluminum-based blockage anti-collapse agent has excellent blockage performance. Compared with the prior art, the strong-inhibition and strong-blockage aluminum-based anti-collapse water-based drilling fluid has the following advantages that (1) an amine inhibitor has prominent inhibition performance, and the hydration dispersion inhibition capacity of shale of the drilling fluid system is strong; (2) the anti-collapse agent has prominent inhibition performance and strong blockage anti-collapse capacity, and the hydration expansion inhibition capacity of shale of the drilling fluid system is strong; (3) the water-based drilling fluid system has relatively good rheological property and strong temperature resistance, salt resistance and calcium and inferior soil pollution resistance; and (4) the system contains less treating agents and is simple to prepare and convenient to maintain.

The invention discloses an APG (alkyl polyglucoside) plant environmentally-friendly shampoo which comprises APG (alkyl polyglucoside), coconut oil 6501, water-soluble wool grease, cocamidopropylamine oxide, emulsified silicon oil softener, EDTA (ethyle, diamine tetraacetic acid), citric acid, sodium alginate, Germall, plant additive and water. The APG plant environmentally-friendly shampoo has the effects of effectively resisting hair dropping, blacking hair, shinning hair, nourishing hair, sterilizing, removing dandruff and relieving itching, has small skin irritation, and does not produce drug resistance after being used for long term.

The invention relates to a high-temperature oil-soluble temporary blocking agent. The high-temperature oil-soluble temporary blocking agent is characterized by comprising the following components in percent by weight: 10-40% of asphalt, 20-50% of C9 petroleum resin, 15-50% of coumarone resin, 5-15% of a surfactant, 2-15% of a polymer fiber and 1-10% of a softening-point additive. The preparation procedures of the high-temperature oil-soluble temporary blocking agent are as follows: firstly, adding the asphalt into a reactor, heating to melt the asphalt, adding the C9 petroleum resin and the coumarone resin into the reactor, stirring continuously until the substances in the reactor are fully melted, continuously adding the surfactant, the polymer fiber and the softening-point additive into the reactor, stirring for 30 minutes to mix uniformly, stopping heating a mixture, cooling, then collecting particles, washing, and screening to obtain the high-temperature oil-soluble temporary blocking agent with different particle sizes. The high-temperature oil-soluble temporary blocking agent provided by the invention overcomes the defect that the traditional oil-soluble temporary blocking agent can not resist high temperature. The high-temperature oil-soluble temporary blocking agent has good oil solubility, acid and salt resistance and high-temperature degradation resistance. The added softening-point additive is capable of regulating the range of the softening point, and thus an oil layer can be protected.

The invention relates to a salt tolerant corrosion and scale inhibitor for underground oil-gas wells and a preparation method thereof. The salt tolerant corrosion and scale inhibitor is composed of an oxazoline derivative, thiourea, cetyl pyridinium chloride, dodecyl dimethyl benzyl ammonium chloride, amino trimethylene phosphonic acid, hydroxyethylidene diphosphonic acid, hexamethylenetetramine, and methanol. The corrosion and scale inhibitor has very strong salt resistance, and under high salinity conditions (100000-200000mg/L), has a significant inhibiting effect on metal corrosion, and the corrosion inhibition rate can reach more than 80%. The organic phosphonic acid molecular structure of the reagent contain a double bond structure, the structure and the calcium ions and magnesium ions in water can chelate to form a stable complex to be adsorbed on seed crystal surface active sites, thereby inhibiting crystal normal growth. With significant scale inhibiting effect and a scale inhibiting rate up to 94%, the product is suitable for inhibiting corrosion and scaling phenomena of oil-gas well rods and pipes containing carbon dioxide, hydrogen sulfide and other complex media conditions under high salinity.

The invention relates to a gas oil base invert oil-emulsion drilling fluid and a preparation method, wherein the total volume of gas oil and calcium chloride aqueous solution is 100 parts: the volume ratio of oil phase to water phase is between 95:5 and 70:30, and the concentration of calcium chloride aqueous solution is 5%-saturation; the required gas oil, primary emulsion, auxiliary emulsion and wetting agent are added into a high speed mixing beaker, and are mixed at high speed for 2-5 minutes; the calcium chloride aqueous solution is added and mixed at high speed for 15 minutes; organic soil, calcium oxide and a fluid loss agent are added and mixed at high speed for 10 minutes; and the required amount of barite is added according to density, and is mixed at high speed for 25 minutes. The gas oil base invert oil-emulsion drilling fluid is used for overcoming the defects of the existing gas oil base drilling fluid and solving the problems of the salt resistance and temperature resistance of the gas oil base drilling fluid, and can resist the temperature above 200 DEG C.

The invention discloses a method for preparing a high-stability heat-resistance and salt-tolerance air foam oil displacing agent. According to the method, a nanometer and nanometer modification technology is adopted, and nanometer hectorite is used as a foam stabilizer and a high-temperature stabilizer to prepare the high-stability heat-resistance and salt-tolerance air foam oil displacing agent. The technology includes the following steps that the hectorite is added into deionized water at the temperature of 50-90 DEG C, stirred and dispersed evenly, cooled to the room temperature and stewed and aged for a period of time to obtain hectorite aqueous dispersion, quantitative cationic surface active agents are added, evenly stirred, stewed and aged, finally, foaming agents are added, high-speed stirring is conducted on a high-speed emulsification machine, and the high-stability heat-resistance and salt-tolerance air foam oil displacing agent is obtained. The foam half-life period reaches up to 768 hours, the high foam stability is achieved, the foam half-life period reaches up to 70 hours under the condition that the degree of mineralization is 30000 mg/L, the good salt tolerance is achieved, the apparent viscosity reaches up to 2000 mPa.s, the heat resistance performance reaches 90 DEG C, the high foam strength and the heat resistance are achieved, the shearing rate is 170 per second, the foam apparent viscosity reaches 800 mPa.s after shearing is conducted for 60 minutes, the good shearing performance is achieved, and the method is suitable for exploration and development of conventional and unconventional oil fields.

The invention relates to a preparation method of a polymer weak gel deep profile control agent. The preparation method comprises the following steps of preparing sodium carboxymethyl cellulose and distilled water into sodium carboxymethyl cellulose water solution of which the mass percentage is 1%-2%; adding acrylamide of which the mass is 2-8 times as great as that of the sodium carboxymethyl cellulose into the sodium carboxymethyl cellulose water solution, and then adding a cross-linking agent which accounts for 0.01%-2% of the total weight of the sodium carboxymethyl cellulose and the acrylamide; enabling nitrogen to enter into a closed system and isolating the air, and adding an initiating agent which accounts for 1%-2% of the total mass of the sodium carboxymethyl cellulose and the acrylamide; and discharging after carrying out constant-temperature reaction for 4-12 hours under the temperature of 30-60 DEG C. According to the preparation method disclosed by the invention, the acrylamide is grafted to the sodium carboxymethyl cellulose, polymer weal gel with a mesh structure is formed under the action of the initiating agent and the cross-linking agent, and a polymer weak gel system integrates the advantages of the sodium carboxymethyl cellulose and the acrylamide.

The invention discloses biological environment-friendly hair-darkening and hairloss-preventing shampoo and a preparation method thereof. The shampoo contains alkyl polyglucoside (APG), coconut oil, water soluble wool oil, cocoamido propyl betaine, tea seed oil, ethylenediaminetetraacetic acid (EDTA) disodium, citric acid, sodium alginate, genma and plant hair-darkening and hairloss-preventing essence. The shampoo can effectively prevent hair loss, darken and brighten hair, remove dandruff and relieve itching, is less irritant to skin and can be used for a long time without causing medicine resistance.

The invention discloses an emulsifying and flushing spacer fluid for improving the cementing quality of an oil-based drilling fluid and a preparation method of the emulsifying and flushing spacer fluid. The spacer fluid is prepared from the following components in parts by weight: 200 parts of water, 5-10 parts of a surfactant, 70-75 parts of base oil, 4-15 parts of a suspension stabilizer, 0.2-3.0 parts of a fluid loss agent, 0.2-2.0 parts of a tackifier, 0.2-5.0 parts of a diluent, 80-400 parts of a weighting agent and 0.05 part of a defoamer, wherein the surfactant is prepared from cocoanut fatty acid diethanolamide CDEA and alkyl glycoside APG in a weight ratio of 1: 2. The emulsifying and flushing spacer fluid which has an emulsifying structure with permeating, dissolving, volume-increasing, carrying functions and the like has a preferable flushing capacity to the oil-based drilling fluid and mud cakes adhered to a casing wall. The surfacant molecules in the spacer fluid can be adsorbed on the surfaces of a casing and a well wall to improve the interfacial wettability, so that cement slurry and the casing and the well wall are better contacted and cemented, and therefore, the first and second interfacial cementation qualities for well cementation are improved.

The invention discloses a preparation method of a depolymerized and dispersed viscosity reducer of heavy oil. The preparation method comprises selecting N,N-Dimethyloctadecylamine as a hydrophobic group monomer, and diethylene triamine, epoxy chloropropane and benzyl chloride as hydrophilic group monomers, and ethanol as a solvent. The preparation method sequentially comprises the following steps: (1) adding the N,N-Dimethyloctadecylamine (N,N-Dimethylhexadecylamine) and the ethanol to a reaction vessel with a stirring device, evenly mixing and keeping the mixture at constant temperature for 0.5h; (2) slowly dripping the epoxy chloropropane with a dropping funnel to the reaction vessel, heating to 70 DEG C-75 DEG C, and reacting for 1-4h to generate HDI-1; (3) dripping the epoxy chloropropane to the diethylene triamine at room temperature to generate HDI-2; (4) allowing reaction products in (3) and (2) to react to generate HDI-3; and (5) dripping the benzyl chloride with the dropping funnel to the HDI-3, evenly stirring the mixture, and reacting at increased temperature of 90-95 DEG C for 2-5h to obtain the target product HD.

The invention relates to a viscosity reducer by emulsification for heavy oil. The viscosity reducer comprises the following components: a nonionic surfactant, an anionic oligomeric surfactant, alcohol and water; the alcohol is C1-C8 alcohol, the anionic oligomeric surfactant comprises a structure shown in the formula (I), wherein n is any integer from 1 to 6, R is alkyl, and M is at least one from Li+, Na+ and K+. The viscosity reducer by emulsification for heavy oil has the advantages of good viscosity reducing effects for heavy oil, good salt resistance, low usage concentration, and low cost; alkali is not needed during usage, and the viscosity reducer by emulsification for heavy oil is suitable for stratum which is sensitive to alkali.

The invention relates to a hydrophobic association zwitterionic polymer and a preparation method thereof. The preparation method comprises the following steps: adding acrylamide, acrylic acid and cationic monomers containing quaternary ammonium groups sequentially into a reactor; adding water and dissolving; adjusting the pH value of a system to be 6 to 9 by using NaOH; supplementing deionized water to enable the total monomer mass percentage of the reaction system to be 10 to 30%; adding surfactant lauryl sodium sulfate and stirring uniformly; adding an acrylamide hydrophobic monomers containing capsaicin functional groups; introducing N2 for 20 minutes; and adding a water-soluble initiator and performing polymerization reaction to obtain the hydrophobic association zwitterionic polymer. The positive charge content and the negative charge content of the hydrophobic association zwitterionic polymer prepared with the method are equal, a solution of the polymer has an antipolyelectrolyte effect, and the hydrophobic association zwitterionic polymer has excellent salt resistance. The introduced hydrophobic units containing the capsaicin functional groups have bioactivity and adopts a rigid benzene ring structure, so that the polymer has excellent tackifying property, temperature resistance, salt resistance and anti-microbial property, high dissolution speed and low price, and has an excellent application prospect in petroleum reservoir exploitation under the conditions of high temperature, high salt and bacteria in existence.

The invention relates to a method for preparing an amphoteric chitosan flocculating agent. The method comprises the following steps that: chitosan is dissolved in an acrylic aqueous solution with a mass percentage concentration of between 0.1 and 1 percent so as to prepare a solution with a mass percentage concentration of chitosan of between 1 and 3 percent; the acquired solution is added with an ammonium ceric nitrate evocating agent, and is added with acrylamide; a mass ratio of the acrylamide to the chitosan is 1 to 1-8 to 1; and a mixture reacts for 2 to 4 hours at a temperature of between 45 and 65 DEG C, thereby preparing the amphoteric chitosan flocculating agent. The amphoteric chitosan flocculating agent prepared by the preparation method has the dual characteristics of having anionic groups and cationic groups, is suitable for processing a water body with different charges, has good salt resistance and wide application range and can be used both in an acid medium and an alkali medium. The method has simple operation, short synthetic time and low cost, uses natural macromolecular products with rich sources as main raw materials and is suitable for large industrialized production; and the method is an economic method for preparing and acquiring a high-quality water treatment agent.

The invention discloses a preparation method of a tackifier for a drilling fluid. The method comprises the following steps of: adding 71 kg of acrylamide and 700 kg of water into a polymerizing kettle, preparing a 20 percent acrylamide aqueous solution, adding 0.1 kg of initiator after a certain period of time, and reacting at constant temperature for a certain period of time to obtain gel polyacrylamide; taking the gel polyacrylamide out, pelletizing, and preparing into 2 percent polyacrylamide aqueous solution; adjusting the pH of a system to 11 with a sodium hydroxide solution, adding 85 kg of formaldehyde and 100 kg of sodium bisulfite aqueous solution, and reacting with stirring for a certain period of time to obtain sulfomethylated polyacrylamide gel; precipitating and separating reactants with 95 percent ethanol, and recycling and distilling an ethanol aqueous solution for circular use; and taking a precipitated polymer, removing ethanol, drying in vacuum and crushing to obtain a product. The tackifier has large tackifying and flow pattern adjusting capabilities, and can be used for keeping the viscosity of the drilling fluid under severe conditions such as high temperature, high salinity, high calcium-magnesium ions and the like.

The invention discloses a washing composition as well as a preparation method and application of the washing composition. The washing composition is prepared by taking water, alkyl polyglucoside, propylene glycol, alkyl betaine, sodium lauryl sulfate, flos lonicerae extract, chrysanthemum extract, radix sophorae flavescentis extract, mint extract, table vinegar (edible acetic acid), table salt, edible essence and a thickening agent as raw materials, and has the functions and characteristics of sterilization and disinfection, oil removal and stain removal, itching stopping and skin protection, odor removal and deodorization, low foam, and capability of being cleaned by washing; meanwhile, alcohol, an alkali, a preservative and other disinfection components are not added, so that a functional skin-protection daily chemical washing product, which can be used for naturally killing viruses and sterilizing, removing oil and dirt, stopping itching and dandruff, resisting allergy and protection skins, and has a medicine effect, is obtained.

The invention discloses a hypersalinity solid-free micro-foam drilling fluid or completion fluid. The drilling fluid is prepared from the following raw materials in parts by weight: (1) 0.3-0.6 parts of a tackifier, (2) 0.3-0.5 parts of a foam stabilizing agent, (3) 0.7-1.1 parts of a foaming agent, (4) 2-3 parts of a filtrate reducer, (5) 0.3-0.5 parts of a flow-pattern adjusting agent, (6) 0.2-0.3 parts of sodium carbonate and (7) 100 parts of a base fluid. The preparation method comprises: successively adding the compositions (1)-(6) according to the weight ratio into the composition (7) under the conditions of normal temperature, normal pressure and mechanical stirring in a routine manner, and stirring for 2-6 h after all compositions are added. The related hypersalinity solid-free micro-foam drilling fluid or completion fluid has excellent rheological performance, relatively good filtrate reducing performance and relatively good stability, and is applicable to well-drilling or well-completion construction of high-salinity (salt bed), low-pressure and easily-leaked stratums.

The invention relates to a chemical industry wastewater comprehensive treatment method which comprises a pretreatment system, a primary biochemical system, an ozone treatment system, a secondary biochemical system and an after-treatment system. By adopting the two biochemical treatment systems, the iron carbon treatment system is arranged before the primary biochemical treatment system, and the ozone treatment system is arranged between the two biochemical treatment systems so as to greatly enhance the biodegradability of the wastewater, so that the treated wastewater can satisfy the direct discharge requirement. The method is suitable for comprehensive treatment of various types of chemical industry wastewater, has the advantages of low treatment cost, high technical stability, high pollutant removal rate, stable and standard effluent water quality and the like, and is suitable to be widely used in chemical industry wastewater treatment.