The invention discloses a preparation method of an anti-
pollution hollow PVDF (
polyvinylidene fluoride) 
fiber membrane with an efficient heavy 
metal ion and 
organic dye removing function, and belongsto the field of 
high polymer materials. A product of the 
hollow fiber membrane is characterized in that heavy 
metal ions such as 
nickel, 
chromium, lead and the like in water can be adsorbed and removed, organic dyes such as bright blue, 
methylene blue and the like can be simultaneously adsorbed and removed, removal efficiency of the heavy 
metal ions and organic dyes in water is high, and the product has anti-
pollution property to 
protein and microorganisms in water. According to the product of the 
hollow fiber membrane, the adsorption removal rate for low-concentration 
chromium ions reaches 90% or higher, and the 
methylene blue removal rate under the action of natural light reaches 90% or higher. Static 
protein adsorption tests show that adsorption of 
protein by the 
fiber membrane is reduced by 80% when compared with that by unmodified membranes. The product has the advantages that 
pressure resistance is good, a support body is not needed, the membrane area per 
unit volume and the fluxare large and the like; besides, special equipment is not required for preparation, industrial implementation is facilitated, and the cost is reduced.