The invention discloses a concrete surface hardener and a construction method thereof, wherein, the concrete surface hardener comprises the compositions by weight percent of 10-40 percent of inorganic silicate, 1-10 percent of alkali, 0.1-5 percent of catalyst, 0.1-2 percent of wetting dispersant, 1-5 percent of stabilizer and rest of water. The hardener prepared by the invention is characterized by easily-obtained material, simple production and convenient construction, unhealthy and environmentally harmful VOC avoidance, etc. In addition, the hardener can penetrate into the interior of the concrete to seal the capillary of the concrete, thus improving the surface density of the concrete, strengthening the impervious capability and strength of the concrete and prolonging the service life of the concrete. As the hardener does not comprise unhealthy and environmentally harmful substances, the increasingly improved requirements of the present environmental protection can be met, thus having extensive application prospect.