This invention discloses a
dry gas hydrogenation catalyst and its preparation method. The support component is
alumina, and the
active components are Group VIB
metal sulfides and Group VIII
metal sulfides. The average number of lamellar
layers of the sulfides is <1.5
layers, and the proportion of single
layers is 65%~80%. Based on the weight of the catalyst, Group VIB
metal sulfides account for 1wt%~20wt% of the total
mass of the catalyst, and Group VIII metal sulfides account for 0.5wt%~10wt% of the total
mass of the catalyst. The
total acid content of the catalyst is 0.1~0.25 mmol / g, of which the strong
acid content at 400-500℃ accounts for 1%~6%, the medium-strength
acid content at 250-400℃ accounts for 10%~20%, and the weak
acid content at 150-250℃ accounts for 74%~89%. The preparation method is as follows:
Boehmite dry
adhesive powder is calcined at high temperature in an
oxygen-containing
atmosphere. The
alumina dry
adhesive powder is then impregnated with an
active component impregnation solution, dried, and calcined at high temperature in an
oxygen-containing
atmosphere. Finally, it is calcined in a mixed
atmosphere of H2S and H2. After molding,
drying, and
calcination, a
dry gas hydrogenation catalyst is obtained. The catalyst of this invention exhibits good hydrogenation performance for organic
sulfur and olefins, and also possesses excellent resistance to
carbon deposition.