The invention provides a preparation method of a
germanium triphosphide
nanosheet, and belongs to the technical field of
electrode material preparation. The preparation method comprises the following steps: step 1), pre-pressing mixed
powder formed by red
phosphorus powder and
germanium powder to obtain a pre-pressed body; (2) carrying out high-temperature and high-pressure
sintering on the pre-pressed body prepared in the step (1) to obtain bulk-phase
germanium triphosphide; (3) taking the bulk-phase germanium triphosphide prepared in the step (2) as an
electrode, and putting the bulk-phase germanium triphosphide into an electrolytic tank; 4) applying
voltage or current to the
electrode in the step 3) to perform intercalation dissociation on the germanium triphosphide; and (5) centrifuging the
electrolyte subjected to electrochemical dissociation in the step (4), and collecting supernate to obtain the germanium triphosphide
nanosheet. A large number of high-purity micron-sized germanium triphosphide nanosheets are prepared by combining a high-temperature and high-pressure technology with an electrochemical dissociation technology.