The invention provides a dual-ion battery, and relates to the technical field of electrochemical energy storage. The dual-ion battery comprises a positive electrode, a negative electrode, a separator and an electrolyte solution, wherein the separator is arranged between the positive electrode and the negative electrode, the positive electrode comprises a graphite positive electrode material, a negative electrode material is a MnO or metal Sn foil, and the electrolyte solution comprises an electrolyte, an organic solvent and an electrolyte additive. The graphite material is selected as the positive electrode material of the battery, the MnO or Sn foil which has activity on lithium ions is selected as the negative electrode material, and the dual-ion battery obtained by assembly is low in raw material cost, is green and environmental-friendly and has favorable rate performance and coulombic efficiency; a positive electrode platform is high in level, the dendritic crystal on a surface of the negative electrode during the repeated charge-discharge process of the battery is prevented, and the safety of the battery is greatly improved; and moreover, the electrolyte additive is added into the electrolyte solution of the dual-ion battery, the stability of the battery can be effectively improved, and the rate performance of the battery is improved.