917 results about "Nano al2o3" patented technology

The invention relates to the technical field of textiles, and discloses a cool and washable bio-based nylon 56 fabric and a preparation method thereof. The preparation method of the cool and washable bio-based nylon 56 fabric comprises the following steps: loading modified nano aluminum oxide on modified aluminum nitride microchips to obtain a composite cool material; nylon 56, an ethylene-methyl acrylate-glycidyl methacrylate terpolymer, polypentamethylene guanidine hydrochloride and a composite cool feeling material are subjected to blending extrusion and melt spinning, and then the bio-based nylon 56 fabric is woven. Mixing the composite modified boron nitride and ethanol to obtain finishing liquid; spraying the finishing liquid on one side of the bio-based nylon 56 fabric, and drying to obtain the cool washable bio-based nylon 56 fabric. The cool and washable bio-based nylon 56 fabric disclosed by the invention has excellent cool feeling, antibacterial property, washable property, moisture absorption property and unidirectional perspiration property.

The invention relates to an aluminum-based composite material, in particular to a preparation method of an in-situ micro-nano Al2O3 particle reinforced aluminum-based composite material. The preparation method comprises the following steps: carrying out ball-milling pre-dispersion on silica powder, calcined kaolin and aluminum powder according to a specified ratio, stirring an Al-Si alloy melt at a semi-solid temperature, adding ball-milling mixed powder, heating to a temperature above an Al-Si alloy liquidus, dispersing reactant powder by using a blade-tray integrated stirring device, heating, carrying out heat preservation, carrying out heat preservation, and carrying out vacuum drying to obtain the aluminum-silicon alloy. And reacting to generate in-situ micro-nano Al2O3 particles, cooling, supplementing alloy elements, refining, and pouring to obtain the in-situ micro-nano Al2O3 particle reinforced composite material. According to the blade-tray integrated stirring device, mechanical stirring and the rolling and impacting effects of the ceramic balls are combined, the problem of one-time dispersion of micro-nano reactant powder is effectively solved, meanwhile, passivation of edges and corners of micron particles is achieved, and the comprehensive performance of in-situ particle reinforced aluminum matrix composites is improved.

The invention discloses water-based wear-resistant ink and a preparation method thereof, and belongs to the technical field of ink. The ink is prepared from the following components in parts by weight: 20 to 35 parts of waterborne polyurethane resin, 15 to 25 parts of waterborne acrylic resin with an acid value of 40 to 80 mg KOH / g, 5 to 15 parts of KH570 silane coupling agent modified nano aluminum oxide, 3 to 8 parts of polyethylene wax emulsion, 10 to 20 parts of pigment and auxiliaries. The preparation method comprises the following steps: firstly, carrying out surface modification on the nano aluminum oxide by using KH570, and then mixing, dispersing and grinding all the components. Through the synergistic effect of the acrylic resin with a specific acid value and the modified nano aluminum oxide, the problem that nano particles are easy to agglomerate in a system is solved, the nano particles can be stably dispersed, and the interface bonding with the resin is enhanced, so that the ink is endowed with excellent adhesive force, wear resistance and storage stability while the process is simplified and the cost is reduced; the BOPP film packaging material is especially suitable for BOPP film packaging materials.

The invention discloses a coating as well as a preparation method and application thereof. The coating comprises the following raw materials: potassium silicate; ethyl orthosilicate; a nanometer titanium dioxide sol; rare earth is doped with nano titanium dioxide; compounding zinc oxide nanoparticles; nano silicon dioxide sol; a fluorosilane coupling agent; a fluorocarbon surfactant; a conductive carbon nanotube; nano aluminum oxide sol; an organic silicon modified acrylate emulsion; a boron nitride nanosheet; hollow glass beads; a shape memory polymer; the invention discloses a self-repairing nanofiber. After a coating is formed by using the coating, the coating has the characteristics of high light transmittance, good self-cleaning effect, high hardness, good adhesive force and excellent weather resistance, and can be applied to a photovoltaic module to replace an existing photovoltaic module coating product.

The invention discloses a modified polysiloxane coating for a stainless steel pot and a preparation method of the modified polysiloxane coating, and belongs to the technical field of polysiloxane coatings. Comprising the following raw materials in parts by weight: 60-70 parts of hydroxyl polydimethylsiloxane, 20-30 parts of acrylate resin, 15-20 parts of ethanol, 25-30 parts of deionized water, 6-18 parts of modified nano aluminum oxide, 2-4 parts of a friction reducing agent, 0.2-0.4 part of benzophenone and 1-3 parts of a flatting agent. Polysiloxane is used as a main component, so that the coating is endowed with excellent heat resistance; wherein the antifriction agent can improve the wear resistance of the coating; wherein the leveling agent improves the surface flatness of the coating; wherein the modified nano aluminum oxide has good compatibility with polysiloxane, is not easy to agglomerate in the coating, has good dispersity, and can greatly improve the heat resistance, hardness and easy-to-clean property of the coating; the performance is stable and the service life is long; the method has important application value in the technical field of polysiloxane coatings.

The invention discloses a high heat storage density stable thermochemical adsorption composite heat storage material and a preparation method thereof, the high heat storage density stable thermochemical adsorption composite heat storage material comprises 54%-57% by mass of mixed salt and 43%-46% by mass of a porous material, the mixed salt comprises MgSO4 and MgCl2, the mass ratio of MgSO4 to MgCl2 is 9: 1-6: 4, and the porous material is expanded perlite modified by nano alumina or a silane coupling agent. The high-heat-storage-density stable thermochemical-adsorption composite heat storage material provided by the invention is simple in preparation method, and the modified expanded perlite is used as a carrier of the mixed hydrated salt; the obtained composite heat storage material has excellent performance: the salt-containing load rate is 114-121%, the water absorption rate is 1.2-1.28 g / g, the heat storage density is 1123.5-1208.6 kJ / kg, the heat storage temperature is 133.4-141.3 DEG C, the structural strength is 10.346-12.631 kPa, the structural stability is 99.27-99.53%, and the stability is 79.7-83.3% after circulation for 30 times, that is, the composite heat storage material is high in heat storage density, high in water absorption rate, low in heat storage temperature, high in strength and not easy to scatter and fall off, and the composite heat storage material is suitable for large-scale production. And the material also has relatively good cycling stability.

The invention discloses a cellulose coated diaphragm and a preparation method thereof in the field of lithium ion batteries, the diaphragm comprises alpha-cellulose pulp, a cellulose grafted phenylboronic acid-co-oligomeric ethylene oxide copolymer, a thermal response star zwitterionic polymer and nano aluminum oxide, and an N-methylmorpholine-N-oxide aqueous solution is adopted as a solvent system. The preparation method comprises the following steps: firstly synthesizing a cellulose grafted copolymer with dynamic borate bonds through atom transfer radical polymerization, then preparing a star polymer with thermal response arms and zwitter-ion terminals by taking cyclodextrin as a core, and finally mixing all the components to prepare coating slurry. And the composite diaphragm is prepared through the processes of coating, phase conversion, ultraviolet curing and drying. The diaphragm combines the thermal stability and lyophilic property of cellulose, forms a dynamic self-adaptive interface layer through the synergistic effect of two functional compounds, has the advantages of active safety protection, dendritic crystal inhibition, long cycle life and the like, and remarkably improves the comprehensive performance of the lithium ion battery.

The invention relates to the field of multifunctional coatings, in particular to a multifunctional coating based on acrylic resin and a production process of the multifunctional coating. Comprising the following raw materials in parts by weight: 40-60 parts of water-based acrylic resin emulsion, 0.3-0.6 part of a defoaming agent, 3-5 parts of modified nano hydroxyapatite, 0.3-0.5 part of a flatting agent, 2-5 parts of a dispersing agent, 1-3 parts of a curing agent, 3-5 parts of modified nano aluminum oxide and 30-50 parts of deionized water. The grafted chloroprene rubber can improve the interfacial compatibility of the nano-hydroxyapatite and a matrix and endows the coating with wear resistance, and after the nano-alumina is grafted with polybenzimidazole, a benzimidazole ring interacts with the matrix to enhance the interfacial compatibility of the nano-alumina and the matrix, so that the nano-alumina forms a high-temperature-resistant structure in the coating, and the wear resistance of the coating is improved. And the aromatic heterocyclic structure of the polybenzimidazole can endow the coating with higher thermal decomposition temperature, so that the coating has high temperature resistance.

The invention discloses a high-viscosity silicone rubber composite material and a preparation method thereof.The preparation method comprises the steps that a silicon-based polymerization solution and a silane raw material are mixed on the basis of a rotary dropper, and a silicon-based liquid compound containing a spiral laminated layer is obtained; the preparation method comprises the following steps: dispersing a nano-filler into a silicon-based liquid compound for synthesis treatment, carrying out crosslinking treatment on the obtained primary compound and peroxide to obtain a crosslinked compound, mixing the crosslinked compound with a fiber compound, and carrying out plasma treatment to obtain a fiber-reinforced compound; performing secondary cross-linking treatment on the fiber reinforced compound and a peroxide silicone oil solution in a vacuum high-temperature environment to obtain a secondary cross-linked compound; and immersing the secondary cross-linked compound into a turbid liquid containing nano aluminum oxide, and carrying out heating treatment to obtain a finished product of the high-viscosity silicone rubber composite material. According to the invention, the problem of compatibility between the filler and the matrix material is solved, the processability is improved, and the performance of the material in multiple aspects such as high temperature resistance and aging resistance is further improved.

The invention relates to the technical field of surface engineering, discloses a method and a system for preparing a yttrium fluoride composite ceramic coating through atmospheric plasma spraying, and aims to solve the problems that the yttrium fluoride coating generates a brittle aluminum fluoride layer on the surface of an aluminum substrate due to fluorine ion diffusion, so that the bonding strength is low, and the yttrium fluoride coating is easy to peel off and lose efficacy. The method comprises the following steps: sequentially carrying out mechanical polishing, ultrasonic cleaning and sand blasting roughening on an aluminum base material; preparing composite powder formed by mixing yttrium fluoride, yttrium oxide and nanometer aluminum oxide according to the mass ratio of 75: 20: 5; sequentially depositing a yttrium oxide transition layer, a composite barrier layer and a yttrium fluoride functional layer by adopting atmospheric plasma spraying; and finally carrying out vacuum post-heat treatment. According to the system, through the synergistic effect of the three layers of gradient structures, the transition layer forms an yttrium aluminate metallurgical bonding interface, the barrier layer inhibits fluorine ion diffusion through the dual mechanisms of nanometer aluminum oxide physical barrier and yttrium oxide chemical adsorption, and the functional layer guarantees the plasma erosion resistance. According to the method, the bonding strength of the coating is remarkably improved to 50 MPa or above, the porosity is lower than 3%, stripping is avoided under 500-hour high-energy plasma bombardment, the process cost is reduced by 40%, and the method is suitable for cavity protection of semiconductor etching equipment.

The present invention relates to a modified inorganic particle doped water-based paint and a preparation method thereof, belonging to the technical field of water-based paint. The raw materials for preparing the water-based paint include, by weight, 35-50 parts of water-based acrylic resin, 5-10 parts of modified inorganic particles, 8-12 parts of polyvinyl alcohol, 0.1-0.5 parts of defoaming agent, and 0.1-0.5 parts of dispersant; the modified inorganic particles are obtained by mixing nano titanium dioxide flame retardant particles, organic acid and biomass and then subjecting them to hydrothermal treatment, and the nano titanium dioxide flame retardant particles are obtained by subjecting polyimide particles and nano titanium dioxide particles to thermal treatment. The modified inorganic particles proposed by the present invention have good dispersibility and strong interaction force with the water-based paint matrix. Nano titanium dioxide is used instead of nano alumina, applied to water-based paint, and the flame retardancy of the water-based paint is increased. Organic acid, biomass powder and nano titanium dioxide flame retardant particles are used for hydrothermal treatment to increase the antibacterial durability of the water-based paint.

The invention relates to a high-purity corundum brick with high thermal shock resistance and a preparation method thereof, and belongs to the technical field of refractory materials. The high-purity corundum brick with high thermal shock resistance is prepared from the following raw materials in parts by mass: 55 to 65 parts of tabular corundum particles, 20 to 25 parts of tabular corundum fine powder, 8 to 12 parts of modified fused zirconia corundum particles, 5 to 8 parts of nano aluminum oxide powder, 2 to 3 parts of rho-aluminum oxide powder, 0.3 to 1 part of toughening agent and 0.3 to 1.5 parts of binding agent. The toughening agent increases the fracture toughness of the high-thermal-shock-resistance high-purity corundum brick through a plurality of strengthening mechanisms such as crack deflection, crack branching and microcracks, so that the high-thermal-shock-resistance high-purity corundum brick has high thermal shock resistance and mechanical properties. Meanwhile, the fused zirconia corundum has a short fiber structure through modification, and fibers can hinder linear propagation of main cracks, force the cracks to deflect and form crack branches, so that the thermal shock resistance and mechanical properties of the high-purity corundum brick with high thermal shock resistance are further enhanced.

The invention discloses a polytetrafluoroethylene compensator with good corrosion resistance and a preparation method thereof.The polytetrafluoroethylene compensator is composed of a corrugated pipe, a pipe connecting flange and an end flange, the pipe connecting flange and the end flange are located at the two ends of the corrugated pipe, the corrugated pipe is composed of a lining layer and a base material layer, and the base material layer is made of stainless steel; the preparation method comprises the following steps: firstly, carrying out surface grafting on nano aluminum oxide by using isocyanate silane, and introducing an active reaction group; then part of active groups react with benzotriazole, so that the corrosion inhibition and adhesion enhancement functions are realized; finally, enabling the residual active groups to react with hydroxylated polytetrafluoroethylene activated by alkali treatment, and coating a chemical inert layer on the surface of the residual active groups; the obtained core-shell structure functional filler is dispersed in epoxy resin to prepare a coating, and after the coating is coated on a stainless steel base material and cured, a high-performance compensator with high hardness, strong adhesive force, excellent corrosion resistance and weather resistance is formed.

The invention provides a preparation process of an environment-friendly film coating, and belongs to the technical field of coatings, the preparation process comprises the following steps: S1, mixing 3-4 parts of epoxy resin, 25-28 parts of polyurethane emulsion, 35-38 parts of water-based acrylic resin emulsion, 0.5-1 part of a curing agent, 0.5-1 part of an accelerant, 2-2.5 parts of a dispersing agent, 0.3-0.5 part of a wetting agent and 6-8 parts of PVA emulsion to obtain a first mixture; s2, adding 4-5 parts of fluorine-doped hexagonal boron nitride and 10-12 parts of nano aluminum oxide into the first mixture, and stirring to obtain a second mixture; adding 2-3 parts of polyoxyethylene, 0.4-0.5 part of citric acid, 2-4 parts of a coalescing agent and 0.5-1 part of a defoaming agent into the second mixture, and stirring to obtain a coating; s3, performing plasma activation on the PET film to obtain a pretreated PET film; and S4, uniformly coating the pretreated PET film with the coating, and curing to obtain the environment-friendly film coating. The ink-jet adhesive force is improved, and meanwhile, the mechanical property of a PET film coated with a coating is improved.

The invention relates to a preparation method of low-carbon magnesium phosphate cement. The low-carbon magnesium phosphate cement is prepared from the following raw materials in parts by weight: 40-50 parts of magnesium oxide, 20-30 parts of phosphate, 1-2 parts of a retarder, 6-8 parts of quartz powder, 1-3 parts of glass fibers, 0.5-1.5 parts of polypropylene fibers, 1-3 parts of steel fibers, 10-20 parts of slag powder, 5-15 parts of silica fume, 1-2 parts of nano silicon dioxide, 0.5-1.5 parts of nano aluminum oxide and 4-6 parts of an additive. According to the preparation method of the low-carbon magnesium phosphate cement, mineral admixtures or industrial waste residues which are lower in price are introduced to serve as partial substitute materials, the requirement for high-cost raw materials is reduced, waste such as fly ash and slag can be used for replacing partial expensive raw materials, the production cost is reduced, cyclic utilization of resources is promoted, and the low-carbon magnesium phosphate cement is suitable for industrial production. Secondly, in order to overcome the problem that the strength of traditional low-carbon magnesium phosphate cement is reduced in water, a special retarder, a stabilizer and other modified materials are added, and dissolution of hydration products in water can be effectively inhibited.

The invention provides a plasma spraying high-temperature-erosion-resistant coating and a coating preparation method, and relates to the technical field of material surface treatment. Comprising the following components in parts by mass: 30-45 parts of tungsten carbide, 15-25 parts of chromium carbide-nickel-chromium alloy, 15-25 parts of yttria-stabilized zirconia, 5-10 parts of aluminum oxide-titanium dioxide composite ceramic, 10-20 parts of nickel-chromium-aluminum-yttrium alloy, 1-3 parts of nano aluminum oxide and 1-3 parts of lanthanum oxide. Multiphase collaborative design is adopted, tungsten carbide and chromium carbide-nickel-chromium alloy form double hard phases, the hardness is higher, aluminum oxide-titanium dioxide composite ceramic fills pores and improves compactness, rare earth and nanometer are adopted to cooperate, lanthanum oxide and nanometer aluminum oxide react to generate a LaAlO3 protective layer, oxidation weight gain is small, oxygen diffusion is inhibited, nanometer aluminum oxide refines grains, and the hardness is higher. In conclusion, the high-temperature oxidation resistance is high, and the erosion rate is low.

The invention provides a novel underwater wet welding flux-cored wire and a preparation method thereof. The flux-cored wire comprises a metal sheath and a flux core, the flux core is prepared by sintering a flux core base material and a flux core additive; the flux core base material comprises the following raw materials in percentage by mass: 20-40% of rutile, 15-35% of fluoride, 2-7% of titanate, 3-10% of aluminum powder, 5-15% of manganese powder and 10-15% of composite nano metal oxide; the composite nano metal oxide at least comprises the following raw materials: nano aluminum oxide, nano zirconium dioxide, nano yttrium oxide, nano cerium oxide and nano lanthanum oxide; and the flux-cored additive is linear aliphatic epoxy resin. The specific mixed nano metal oxide powder is added into the flux-cored wire, grain refinement is achieved, a quenched martensite structure is reduced, the mechanical property of a weld joint is improved, meanwhile, the specific epoxy resin and the flux-cored base material are mixed, filled and sintered, a proper amount of carbon element is introduced while all raw material components of the flux-cored wire are dispersed uniformly and stably, and the welding quality of the flux-cored wire is improved. And metal is prevented from being oxidized in the welding process.

The invention provides an acidic redox flow battery diaphragm and a preparation method thereof, belongs to the technical field of flow batteries, and aims to solve the technical problems of low energy efficiency and poor cycling stability of flow batteries. The preparation method comprises the following steps: preparing a sulfonated polyetheretherketone solution, and coating one surface of a diaphragm substrate with the sulfonated polyetheretherketone solution; and dispersing and dissolving nano aluminum oxide and an adhesive into a solvent to prepare slurry, and coating the slurry on the other surface of the diaphragm substrate. The positive electrode side is coated with a layer of sulfonated polyetheretherketone, the hydrophilicity and ion exchange rate of the modified membrane are improved by regulating and controlling the sulfonation degree and the thickness of a modified layer, the negative electrode side is coated with Nano-Al2O3, and the purposes of improving the mechanical strength of the positive electrode side of the diaphragm and inhibiting zinc dendrite generation are achieved by regulating and controlling the content of Nano-Al2O3 and the coating thickness.

The invention belongs to the technical field of adhesives, and particularly discloses a single-component silicone sealant for stainless steel bonding and a preparation method thereof, and the single-component silicone sealant comprises the following components by weight: 50-60 parts of alpha, omega-dihydroxy polydimethylsiloxane; 10 to 15 parts of a polydopamine coated silicon carbide nanowire; 5 to 15 parts of modified nano aluminum oxide gel; 5 to 10 parts of methyltris (methylethylketoxime) silane; 1 to 3 parts of dodecyl tris (methylethylketoxime) silane; 0.03 to 0.3 part of a coordination enhanced organic tin catalyst; and 8-14 parts of a plasticizer. According to the single-component silicone sealant for stainless steel bonding and the preparation method of the single-component silicone sealant, the modified nanometer aluminum oxide gel is selected, the bonding performance of stainless steel in a humid and hot environment is promoted and improved, the silicon carbide nanowire is coated with polydopamine, the bonding performance of the stainless steel is effectively improved, and the single-component silicone sealant can be widely applied to various indoor and outdoor scenes.

The invention relates to an automobile scratch-resistant protective film and a preparation method thereof, and belongs to the technical field of automobile protective materials. The material is prepared from modified nano aluminum oxide, modified polyurethane acrylate, polyurethane acrylate, a photoinitiator, a flatting agent, an antioxidant and a solvent, the modified nano aluminum oxide is prepared through an esterification reaction of nano alpha-Al2O3 and stearic acid, and the hardness and wear resistance of a coating are enhanced; and the modified polyurethane acrylate is prepared by reacting a polyurethane prepolymer with a hydroxyl compound, so that the interface bonding force with the nano particles and the flexibility of the coating are improved. The preparation method comprises the following steps: dispersing modified nano aluminum oxide into a solvent, sequentially adding other components, and uniformly mixing to obtain functional coating slurry; the surface of a PET base material is coated with the slurry, and ultraviolet curing molding is performed after pre-drying. The prepared protective material has the characteristics of high hardness, scratch resistance, strong adhesive force with automobile paint and excellent weather resistance, and is suitable for automobile surface protection.

The invention relates to the technical field of coatings, and particularly discloses a durable reflective thermal insulation coating and a preparation method thereof. The coating provided by the invention comprises a finish paint and a primer, the finish paint comprises a component A and a component B, the primer comprises a component C and a component D, resin in the component A is limited to comprise fluorocarbon resin and hydroxy acrylic resin modified by a first silane coupling agent, nano-zinc oxide is selected as a filler in the component A, and nano-zinc oxide is selected as a filler in the component B; the resin in the component C comprises flexible epoxy resin and epoxy resin modified by a second silane coupling agent, and the modified rutile type titanium dioxide in the component C comprises nano aluminum oxide and nano yttrium oxide modified rutile type titanium dioxide. According to the invention, by limiting the resin and the filler in the finishing coat, the resin in the primer and limiting a modified substance for rutile type titanium dioxide in the primer, the composite coating composed of the primer and the finishing coat achieves excellent durability, corrosion resistance and reflective insulation effect.

The invention belongs to the technical field of granary building coatings, and provides a composite aerogel granary heat preservation and insulation coating as well as a preparation method and a use method thereof. The coating comprises a reflective coating, a heat-insulating coating and a weather-resistant coating, the reflective coating is prepared from water-based acrylic resin, rutile type nano titanium dioxide, hydrophobic silicon dioxide aerogel, an auxiliary agent and water; the heat insulation coating comprises hollow ceramic microbeads, epoxy resin, a polyamide curing agent, nano diatomite, hydrophobic aerogel powder and polyether modified silicone oil; the weather-resistant coating is prepared from organosilicone acrylic resin, nano aluminum oxide, an ultraviolet light absorber and a water-based flatting agent. Through the gradient design of the reflecting layer (visible light reflection), the thermal insulating layer (infrared barrier) and the weather-proof layer (environmental protection), the unification of spectrum selective regulation and control and long-acting protection is realized; the thermal insulation coating is easy to construct, and the construction viscosity is adjusted by adjusting the use amount of water, so that the thermal insulation coating adapts to different construction conditions and process requirements.

The invention relates to the technical field of brake discs, in particular to a carbon-ceramic brake disc with a composite functional layer and a preparation method of the carbon-ceramic brake disc. The problems that a brake disc is insufficient in strength and poor in ablation resistance are solved. The preparation method comprises the following steps: carrying out low-temperature plasma treatment and silicon dioxide sol impregnation on carbon fibers, and inserting a graphene oxide film between woven layers, so as to obtain a carbon fiber preform; primary densification is carried out through pretreatment activation, low-temperature permeation and high-temperature permeation, and two graphitization treatments are combined; siliconizing is carried out through low-pressure permeation, high-pressure strengthening and laser cladding, and secondary densification is carried out through precursor impregnation and cracking; the titanium zirconium silicide-nano aluminum oxide composite layer generated through the embedding process forms a compact oxidation film at high temperature, and the silicon carbide nano crystal whiskers are subjected to chemical vapor deposition, so that the strength and ablation resistance of the prepared carbon ceramic brake disc are improved.

The concrete aggregate based on the modified coal gangue is prepared from the following components in parts by weight: 35 to 40 parts of slag, 5 to 9 parts of nano aluminum oxide, 80 to 100 parts of red mud, 10 to 20 parts of fly ash, 80 to 100 parts of the modified coal gangue and 10 to 15 parts of hybrid fiber. The concrete aggregate based on the modified coal gangue has better strength, so that the mechanical property of concrete is improved.

The invention belongs to the technical field of thermal power heating surface treatment, and provides a multi-layer composite self-repairing anti-oxidation coating for a boiler heating surface and a preparation method of the multi-layer composite self-repairing anti-oxidation coating aiming at the technical problems that a thermal power boiler heating surface protective coating is insufficient in bonding strength, insufficient in long-term anti-oxidation capacity and concentrated in interface stress among multi-layer structures. Comprising a bonding layer, a gradient transition layer, a self-repairing functional layer and a ceramic surface layer which are sequentially arranged from inside to outside. The self-repairing functional layer is made of NiCoCrAlY alloy, the bonding layer is made of NiCrAlY alloy, the gradient transition layer comprises four layers of gradient transition layer units, each layer of gradient transition layer unit comprises a gradient composite structure of NiCrAlY and nano Al2O3, the self-repairing functional layer comprises NiCoCrAlY serving as a base body, thermal response type microcapsules are embedded in the NiCoCrAlY base body, and the ceramic surface layer comprises a nano ceramic material composed of Cr, Co, Ni, Fe, Al, Ti and B elements.

The invention relates to the technical field of refractory materials, in particular to an antioxidant and application thereof in steel ladle slag line bricks, and the antioxidant comprises a Si / SiC multiphase material, modified nano Al2O3 and CaF2; the ladle slag line brick comprises an antioxidant, fused magnesite, crystalline flake graphite and phenolic resin. Si-SiC compound waste is subjected to magnetic separation and acid pickling, then a SiO2 passivation layer is formed through pre-oxidation, moisture and air in the storage period are isolated, and a titanate coupling agent is introduced to improve the wettability and compatibility with phenolic resin. P2O5 released by phosphate on the surface of the modified nano Al2O3 at a high temperature reacts with alkali (earth) metal migrated to a SiO2 oxide layer to prevent the alkali (earth) metal from forming a low-melting-point eutectic substance, CaF2 reacts with SiO2 along with temperature rise, a passivation layer is broken, internal Si and SiC are directly exposed, and boron oxide of the modified nano Al2O3 remarkably reduces activation energy and a temperature threshold value of the reaction of CaF2 and SiO2.

The invention relates to the technical field of paper printing, in particular to a waterproof printing process of a paper printed matter. The method overcomes the problems of poor waterproof effect and poor adhesive force of printed matters caused by imperfect traditional printing processes. According to the method, the printed matter is obtained by pretreating the base material, coating the bottom layer, coating the surface layer and calendering the mirror surface roller; parameters of corona treatment and micron-sized embossing treatment in pretreatment are changed; acrylic resin is modified and then mixed with nano silicon dioxide, and bottom layer coating liquid is prepared; a transition layer is arranged between the bottom layer coating and the surface layer coating; specially-treated hydrophobic nano-alumina is introduced into a surface coating liquid and has a synergistic effect with modified polyurethane, so that the waterproof effect and adhesive force of the printed matter are improved.

The invention relates to the technical field of green building materials, in particular to phase-change energy-storage thermal insulation mortar and a preparation method of the phase-change energy-storage thermal insulation mortar. 25 to 40 parts of methyl palmitate; 120 to 180 parts of hydrophobic perlite; 8 to 15 parts of expanded graphite; 3-6 parts of phosphorus sheet-shaped aluminum nitride; 180 to 250 parts of sulphoaluminate cement; 60 to 100 parts of volcanic rock micro powder; 0.3 to 0.8 part of hydroxypropyl methyl cellulose; 0.6 to 1.2 parts of a polycarboxylic acid water reducing agent; 2 to 4 parts of nano aluminum oxide; 0.8 to 1.5 parts of propyl gallate; and 1-2 parts of zinc borate. Through the proportion design of the antioxidant flame-retardant microcapsules and the lightweight composite aggregate, the problems of poor thermal conductivity and insufficient durability of a traditional phase change material are solved. Through phase change material loading, interface modification and multi-component cooperative regulation, the thermal insulation performance, energy storage efficiency and structural stability are remarkably improved, and the material is suitable for the fields of building energy saving, intelligent temperature control and the like.

The invention discloses a modified nano aluminum oxide marine anticorrosive coating and a preparation method thereof, and the modified nano aluminum oxide marine anticorrosive coating comprises the following raw materials in parts by weight: 40-80 parts of epoxy resin, 5-15 parts of furan resin, 15-25 parts of modified nano aluminum oxide, 1-5 parts of modified glass flakes, 10-25 parts of a diluent, 20-70 parts of a curing agent and 0.05-0.2 part of an accelerant. 0.1 to 0.5 part of a defoaming agent and 0.1 to 0.5 part of a microbial preservative. The prepared modified nano aluminum oxide marine anticorrosive paint has good weather resistance and wear resistance and excellent acid, alkali and salt corrosion resistance, is particularly suitable for anticorrosive protection in a marine environment, and shows a wide application prospect.

The invention discloses a lightweight heat-insulating fireproof material and a preparation method thereof, and relates to the technical field of fireproof materials. The light heat-insulation fireproof material provided by the invention is prepared from the following components in parts by weight: 15 to 25 parts of nano aluminum oxide fiber, 10 to 20 parts of calcium silicate powder, 30 to 40 parts of modified phosphorus-nitrogen flame retardant, 5 to 8 parts of zinc borate, 5 to 10 parts of epoxy resin, 8 to 15 parts of silicon dioxide aerogel, 3 to 5 parts of expanded graphite, 1 to 2 parts of coupling agent, 0.5 to 1.5 parts of foaming agent and 0.1 to 0.5 part of dispersing agent. The fireproof material prepared by the invention simultaneously meets the requirements of high strength, ultralow heat conductivity coefficient and high fire endurance.