557results about How to "Improve sulfur resistance" patented technology

The present invention discloses a preparation method for a composite oxide carrier. According to the method of the present invention, a composite oxide dry glue is prepared by the following steps, wherein the steps comprise: firstly preparing an aluminum hydroxide wet filter cake and an aqueous solution containing an IVB group metal complex; adding the wet filter cake to the complex solution, andstrongly stirring; carrying out filtering and drying to obtain the composite oxide dry glue. With the composite oxide dry glue prepared by the method, most of the IVB group metal oxide can be distributed on the surface of aluminum oxide so as to reduce the influence on the pore structure of the aluminum oxide, improve the assistant catalysis effect of the IVB group metal oxide, and improve the pore structure and the surface performance of the composite oxide carrier. In addition, with the present invention, the sulfurization performance of the catalyst adopting the composite oxide carrier as the carrier can be improved, and the loaded active metal is easy to reduce.

The invention discloses a preparation method of a catalyst for removing NOx in coke oven tail gas through low-temperature sulfur-resistant catalytic reduction.The catalyst is prepared by taking titanium oxide as a carrier, taking one or two of cerium oxide, zirconia oxide and lanthanum oxide as an auxiliary, taking one or more than two of manganese oxide, cobalt oxide, copper oxide and ferric oxide as an active ingredient and adopting a precipitation-deposition method, wherein two or three of TiO2, ZrO2, CeO2, La2O2, MgO, CaO and BaO can be adopted as the carrier.In the low-temperature sulfur-resistant denitration catalyst, the loading quantity of the active ingredient is 5 wt%-20 wt%, and the loading quantity of the auxiliary is 0.5%-5%.According to the preparation method, the active ingredient prepared by achieving precipitation and deposition sodium carbonate and oxidizing and loading the active ingredient manganese dioxide through potassium permanganate is mainly distributed in the surface area of the carrier, and the dosage of the active ingredient can be effectively decreased.The catalyst is high in activity and sulfur poisoning resisting capacity and particularly suitable for catalytic removal of the NOx in the coke oven tail gas, and the denitration effect of the catalyst also can be expanded to the low-temperature denitration process of other tail gases.

The invention discloses a method for simultaneously removing sulfur, niter and mercury from smoke based on catalytic oxidation. The method is characterized by comprising the following steps of: (1) arranging a catalytic reactor in a dust-removed smoke duct, wherein a catalyst for promoting oxidizing reaction of NO and HgO is filled in the catalytic reactor; (2) allowing the dust-removed smoke to pass through the catalytic reactor, wherein under catalysis of the catalyst, the reaction speed of the NO, the HgO and O2 is increased and the NO and the HgO are oxidized into NO2 and Hg<2+>; and (3) introducing the smoke subjected to catalytic oxidation into an absorber with an absorption solution, wherein the absorption solution is used for absorbing NO2, Hg<2+> and SO2 from the smoke. The invention also discloses a system applicable to the method. According to the method and the system, the sulfur, the niter and the mercury are removed from the smoke; external oxidant is not required to be added; preparation, transportation and storage of strong oxidant are avoided; operating cost is reduced; and economy and safety of the system are improved.

The invention relates to a Fischer-Tropsch synthesis catalyst, its preparation method and an application thereof. The catalyst comprises the following main components: Fe, a metal auxiliary component W, a Cu auxiliary agent, an alkaline auxiliary agent selected from Li, Na, K, Mg, Ca, Rb and Cs, and a structural promoter which contains at least one ingredient or any combination selected from SiO2, active carbon, Al2O3, ZrO2 and TiO2. The specific surface area of the catalyst provided by the invention is usually 50-240 m<2>/g. The catalyst can be prepared by a sol-gel method, a coprecipitation method, an immersion method or any combination of the above preparation methods, but preferably by a parallel flow precipitation method. The catalyst provided by the invention can be used in high selectivity production of hydrocarbons, oxygen-containing compounds and the like through Fischer-Tropsch synthesis of synthetic gas. its reaction activity and stability are obviously improved. And selectivity of light olefins in the Fischer-Tropsch synthesis product hydrocarbon is obviously raised.

The invention relates to a catalyst and applications in C11<+> heavy aromatic hydrocarbon lightening reactions, wherein the catalyst comprises, by weight, a) 5-80 parts of solid acid zeolite, b) 0.05-8 parts of a Group VIII metal, c) 3-25 parts of a Group VIB metal oxide, d) 0.1-2 parts of a Group VIB metal sulfide, and e) 20-95 parts of a binder. According to the present invention, the catalyst can be used for producing light aromatic hydrocarbons from full-distillate C11<+> poor-quality heavy aromatic hydrocarbons.

The invention relates to a method for separating and producing 1,3,5-trimethylbenzene through hydrocracking heavy aromatic hydrocarbons to mainly solve technical problems of low added value of the heavy aromatic hydrocarbons, and complex flow, low product purity, low yield and the like in separation of 1,3,5-trimethylbenzene monomers from the heavy aromatic hydrocarbons. According to the method, hydrogen type binder-free ten-membered ring zeolite loading 0.005-0.5% by mass of Pt or Pd is adopted as a catalyst, hydrogen and the heavy aromatic hydrocarbons which are raw materials undergo hydrocracking treatment, and 1,2,4-trimethylbenzene and heavy aromatic hydrocarbons having boiling points greater than the boiling point of the 1,2,4-trimethylbenzene in products are returned to a reactor, so BTX aromatic hydrocarbon yield increase and 1,3,5-trimethylbenzene separation production are realized. The method well solves the problems, and can be used for the industrial production for yield increases of the BTX (benzene, toluene and xylol) aromatic hydrocarbon and the 1,3,5-trimethylbenzene.

The invention provides a NH3 selective oxidation catalyst; the NH3 is selectively catalytically oxidated as N2 and H2O without pollution. The catalyst mainly solves the problems that the oxidation catalyst which is applied to elimination industries and traffic and the like and generates the NH3 pollution has bad low-temperature activity, low selectivity and poor anti-sulfur performance. The catalyst firstly prepares Fe-ZSM-5 molecular sieve catalyst with large specific area by a secondary ion exchanging method; subsequently, trace noble metal Pt is loaded on the Fe-ZSM-5 so as to prepare the Ptx-Fe-ZSM-5 catalyst; and the oxidation catalyst has high activity, N2 selectivity, good stability and anti-SO2 poisoning performance, and excellently solving the technical problem of the prior art. If the catalyst is prepared into slurry and loaded on honeycomb ceramics, the NH3 pollution in the practical industrial tailings can be expected to be removed; furthermore, the catalyst can be used as postpositive oxidation catalyst in the tailings disposal system of diesel engine so as to prevent the pollution caused by the leakage of NH3 in the NH3-SCR catalytic system.

The invention discloses a tool joint for petroleum drill pipe against erosion of sulfureted hydrogen and a heat treatment method thereof. The tool joint is made of the steel pipe comprising the following ingredients (wt%): C: 0.3-0.4; Si: 0.1-0.5; Mn: 0.4-1.0, Cr: 0.3-1.2, Mo: 0.4-1.0; V: 0.05-0.15; Nb: 0.04-0.1; Ti: 0.01-0.1; Cu: 0.1-0.4; Ni:0.1-0.4; P<=0.010; S<=0.005, the rests are Fe and unavoidable impurities. The heat treatment method of the tool joint comprises the steps of: heating the whole to 850-1000 DEG C and then cooling in an oil tank, after that, tempering at AC1 temperature which is over 680 DEG C and lower than the material. The invention not only guarantees the sufficient quenching of the tool for drill pipe, but also not produce quenching crack with outstanding performance resisting sulphur.

The invention relates to a kind of rare-earth hydroxide catalyst with medium-low carbonyl sulfur hydrolysis and its manufacturing method. The catalyst of the invention is rare earth hydroxide, and chemical molecular formulas of it are: Re(OH)3, on which Re is stood for La, Pr, Nd, Sm, Eu, Gd. Compared with the existing COS hydrolysis catalyst, the catalyst of the invention has the advantages of \ high medium-low activity, great operating elasticity, excellent resistibility of oxygen and sulfur, simple manufacturing method and so on. When the concentration of oxygen in virgin gas is less than 2%, the catalyst activity has no influence; furthermore, when the virgin gas contains oxygen and hydrogen sulfide at the same time, the influence of catalyst activity can be neglected.

The invention provides a graphene-loaded titanium-based core-shell-structured low-temperature SCR sulfur-resisting catalyst and a preparation method thereof. The preparation method of the graphene-loaded titanium-based core-shell-structured catalyst comprises the following steps: firstly forming a compound core-shell structure MnOx-CeO2@TiO2 by taking a nano particle MnOx-CeO2 as a core and TiO2 as a shell, and compounding the MnOx-CeO2@TiO2 with graphene, wherein the size range of the catalyst is within a range of about 20nm-200nm and the mol ratio of Mn to Ce to Ti in the core-shell structure MnOx-CeO2@TiO2 is (0.05-1) to (0.05-1) to 1; and the mass ratio of a graphene carrier to the nano core-shell structure MnOx-CeO2@TiO2 is (0.01-0.6) to 1. According to the invention, the graphene-loaded titanium-based core-shell structure is constructed for the first time and the active center of the catalyst is protected through special physicochemical properties of the core-shell catalyst and the accumulation of ammonium sulfate is reduced by virtue of graphene, so that the sulfur-resisting capability of a low-temperature denitration catalyst is enhanced.

The invention discloses a catalyst for catalytic combustion of VOCs and a preparation method of the catalyst. Cordierite honeycomb ceramic or a porous metal material is used as a carrier, the carrieris coated with a nano coating material, precious metal compound transition metal is used as an active component, compound rare earth oxide is used as a catalyst aid, and a solid solution prepared froman alkaline earth metal compound and main group metal oxide is used as a carrier modifier; the carrier and the active component are coated through an automatic production line; the catalyst has advantages of high substrate bonding force, high adhesive force between the active component and the carrier after high-temperature roasting, difficult shedding, high activity, good thermal stability, goodsulfur resistance and long service lifetime, is a broad-spectrum VOC oxidation catalyst, can be used for catalytic combustion treatment of VOCs in the industries of spraying, printing, electronics and the like, and is suitable for CO and RCO catalytic combustion devices.

The invention discloses an iron catalyst containing a cobalt auxiliary agent for a Fischer-Tropsch synthesis reaction and a preparation method thereof. The catalyst comprises Fe, Cu, K, Co and SiO2 in a weight ratio of 100:(0.1-10):(0.1-10):(0.01-5):(5-30). The iron catalyst containing the cobalt auxiliary agent has higher specific surface area, CO transforming activity, sintering resistance and sulfur resistance.

The invention discloses a hydrogen sulfide resistance stress corrosion oil sleeve, which comprises the following parts: 0.20-0.32% C, 0.1-0.5% Si, 0.4-1.0% Mn, 0.1-0.8% Cr, 0.5-1.2% Mo, 0.01-1.10% V, 0.01-0.10% Nb, not more than 0.015% P, not more than 0.010% S and Fe and inevitable impurity. The preparing method comprises the following steps: proceeding arc electric melting and external fine melting; deairing in the vacuum; proceeding calcium disposal; casting to form round mould; rolling to form seamless steel pipe; tempering to do heat disposal; quenching between 820 and 1000 deg.c; insulating for over 30min; quenching inner and outer steel pipe simultaneously; setting flashback temperature over 650 deg.c; insulating for over 60min; proceeding air cooling; making heat aligning temperature over 480 deg.c; preparing oil pipe or sleeve through fault finding and pipe manufacturing.

The invention relates to a method for improving water resistance and sulfur resistance of a manganese-based low-temperature SCR denitration catalyst, which belongs to the technical field of a water-resistant sulfur-resistant catalyst. The hydrophobic polytetrafluoroethylene is used as a coating or a dopant, is simply dispersed in a reaction vessel containing anhydrous ethanol, and then is mixed with the manganese-based catalyst, and steps of filtering, drying and calcining are carried out to obtain the manganese-based low-temperature SCR denitration catalyst. The method of the invention has the advantages of simple process, low cost, no toxicity and no pollution, and can prepare the manganese-based low-temperature SCR catalyst with excellent water and sulfur resistance.

The invention relates to a sulfur tolerant catalyst suitable for slurry bed methanation. The catalyst adopts the main metal W as an active component, and on the basis the assistant metal W1 is added as an auxiliary agent, and the catalyst carrier is M. The catalyst is composed of, by mass: 2-40% of W, 0.5-35% of W1, and 50-97.5% of the carrier M. The sulfur tolerant catalyst provided in the invention has the advantages of high catalytic activity, long service life and high selectivity.

The invention relates to sulfur-tolerant low-carbon alcohol catalyst which has the expression of MC-M1-M2. The sulfur-tolerant low-carbon alcohol catalyst takes the M metal carbide as the active component, and M1 metal element and M2 metal element are added to the M metal carbide so as to be used as the auxiliary agents. The molar ratio of the M1 to the M2 to the M is 0.01-0.5:0.1-1:1. The M is one or some of the Mo, the W and the V, the M1 is one or some of the Fe, the Co, the Ni, the Cr, the Mn, the La, the Y and the Ce, and the M2 is one or some of the K, the Na, the Be and the Mg. The sulfur-tolerant low-carbon alcohol catalyst has the advantages of good sulfur tolerance, good stability and high activity.

The invention relates to a method for the increase production of BTX aromatic hydrocarbons and trimethylbenzene through hydrocracking heavy aromatic hydrocarbons to mainly solve technical problems of low heavy aromatic hydrocarbon added value and high cost for separating and producing trimethylbenzene monomers in the heavy aromatic hydrocarbons containing methylethylbenzene, propylbenzene and butylbenzene. The method comprises a step that the heavy aromatic hydrocarbons are subjected to a hydrocracking reaction through adopting Pt/Pd-loaded hydrogen type binder-free ten-membered ring zeolite as a catalyst under reaction conditions comprising that the reaction temperature is 320-450DEG C, the reaction pressure is 2.0-4.0Mpa, the hydrocarbons raw material weight hourly space velocity is 1.0-4.0h<-1> and the hydrogen/hydrocarbon raw material ratio by mole is 3-10:1. The method well solves the problems through above technical scheme, and can be applied to the industrial production of the BTX aromatic hydrocarbons and the trimethylbenzene.

The invention discloses a molybdenum sulfide catalyst and a preparation method thereof, and applications of the molybdenum sulfide catalyst in high-added value aromatic fine chemical product production reactions through hydrogenation degradation of aromatic phenol and ether compounds. According to the molybdenum sulfide catalyst I, molybdenum sulfide is adopted as a main active component, one or a plurality of materials selected from nickel, cobalt, iron, copper, platinum, ruthenium, rhodium, palladium, lanthanum, osmium, iridium and the like can be added as a second metal component, the components can be supported on one carrier selected from active carbon (AC), carbon black (VB), carbon fiber (CF), graphene, carbon nano-tubes (CT), a mesoporous carbon material, gamma-alumina (gamma-Al2O3), silica (SiO2), zirconia (ZrO2), titania (TiO 2), a silicon-aluminum molecular sieve and a phosphorous-aluminum molecular sieve, and the catalyst is used for the catalytic hydrogenation degradation reaction of aromatic phenol and ether compounds. According to the present invention, with the catalyst, the aromatic phenol and ether compounds can be catalytically converted into the high-added value aromatic chemical products having the aromatic structure at the temperature of 150-350 DEG C under the initial hydrogen gas pressure of 1-6 MPa in the high-efficiency, high-selectivity and high-yield manner.