Catalyst and process for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock
a technology of hydrocarbonaceous feedstock and catalyst, which is applied in the direction of catalyst activation/preparation, physical/chemical process catalyst, metal/metal-oxide/metal-hydroxide catalyst, etc., can solve the side reaction of aromatic ring saturation, poor catalytic efficiency, and reduced effective surface area
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example 1
[0030]A mixture of a solution of tetrapropylammonium hydroxide (TPAOH), tetraethyl orthosilicate (TEOS) and water in molar ratio of (TPA)2O:5.5TEOS:90H2O was stirred homogeneously, then aged and refluxed for 3-day at 80° C. to obtain ZSM-5 seed crystal orienting agent. Dosing 180 g white carbon black, 10 g sesbania flour, an aqueous solution of 19.7 g sodium aluminate and 40 g ZSM-5 seed crystal orienting agent, further adding 230 g silica sol(40 wt %) and required amount of water, then kneading and drying to obtain a cylindrical precursor. In a reaction vessel, to which a mixture of 35 g ethylenediamine and 5 g distilled water was pre-added, 150 g cylindrical precursor as above-prepared was placed on a porous stainless steel screen therein, and a vapor-solid phase treatment was carried out at 160° C. for 5-day after sealing the reaction vessel. The product was washed with distilled water and dried, then was calcined at 550° C. in air. The calcined product was demonstrated to be a b...
example 2
[0031]Mixing 100 g white carbon black, 20 g USY zeolite with a molar ratio SiO2 / Al2O3 of 16 and 20 g ZSM-5 seed crystal orienting agent from example 1, adding aqueous solution of 26 g Al2(SO4)3.18H2O to adjust the Si / Al ratio, further adding 150 g silica sol(40 wt %), then kneading and drying to obtain a cylindrical precursor. In a reaction vessel, to which a mixture of 34 g ethylamine and 5 g distilled water was pre-added, 100 g cylindrical precursor as above-prepared was placed on a porous stainless steel screen therein, and a vapor-solid phase treatment was carried out at 180° C. for 5-day after sealing the reaction vessel. The product was washed with distilled water and dried, then was calcined at 550° C. in air. The calcined product was demonstrated to be a binder-free ZSM-5 / USY composite zeolite by XRD characterization, ZSM-5 zeolite and USY zeolite therein are at amounts of 91 wt % and 9 wt % respectively as determined through quantitative analysis by XRD, ZSM-5 zeolite there...
example 3
[0032]Mixing 180 g white carbon black, 140 g beta zeolite with a molar ratio SiO2 / Al2O3 of 20 and 40 g ZSM-5 seed crystal orienting agent from example 1, adding an aqueous solution of 110 g Al2(SO4)3.18H2O to adjust the Si / Al ratio, further adding 220 g silica sol(40 wt %), then kneading and drying to obtain a cylindrical precursor. In a reaction vessel, to which a mixture of 40 g ethylamine and 5 g distilled water was pre-added, 100 g cylindrical precursor as above-prepared was placed on a porous stainless steel screen therein, and a vapor-solid phase treatment was carried out at 150° C. for 7-day after sealing the reaction vessel. The product was washed with distilled water and dried, then was calcined at 550° C. in air. The calcined product was demonstrated to be a binder-free ZSM-5 / beta composite zeolite by XRD characterization, ZSM-5 zeolite and beta zeolite therein are at amounts of 70.5 wt % and 29.5 wt % respectively as determined through quantitative analysis by XRD, ZSM-5 ...
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