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Catalyst and process for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock

a technology of hydrocarbonaceous feedstock and catalyst, which is applied in the direction of catalyst activation/preparation, physical/chemical process catalyst, metal/metal-oxide/metal-hydroxide catalyst, etc., can solve the side reaction of aromatic ring saturation, poor catalytic efficiency, and reduced effective surface area

Inactive Publication Date: 2009-01-22
CHINA PETROCHEMICAL CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a catalyst for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock. The catalyst uses a binder-free zeolite as a support for metallic catalytic active components, which results in a catalyst with large acid density, unobstructed pores, and moderate hydrogenation activity. The catalyst can be easily separated from the hydrocarbonaceous feedstock and has high stability. The process for producing light aromatic hydrocarbons and light alkanes using the catalyst is simple and efficient.

Problems solved by technology

The acidic catalyst used in these catalytic conversion processes would deactivate quickly due to coke and / or carbon-deposition, although this can be alleviated by supporting the metals with high hydrogenation activity and the hydrogenation activity of the catalyst also can be adjusted by varying the amount and / or the distribution of the supported metals, however, too high hydrogenation activity on the metallic center may result in side reaction of saturation of aromatic rings.
This is because the shaped catalysts are widely used in industries and have to suffer from various stresses during its use, thus, sufficient mechanical strengths are necessary for ensuring the whole catalytic process to be conducted smoothly, otherwise if the shaped catalysts have poor mechanical strengths, some problems such as the lines being blocked by fine powders, the liquid being distributed unevenly, the pressure drop being increased and the like would be introduced, so as to lead to poor catalytic efficiency, and even a unexpected shut-down in worse case.
However, introduction of binders during shaping the zeolite powders would reduce the concentration of effective components in the zeolite particles, result in reduced effective surface area, thus the adsorption value would be reduced.
This is because some binders would enter into part of channels of the zeolite or block part of pores of the zeolite, thus limiting the diffusion, resulting in poor adsorption ability and adsorption selectivity as well as reduced rates of adsorption and desorption, further the reduced activity and selectivity in the catalytic reactions; furthermore, undesired side reactions may be initiated in the presence of binders.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0030]A mixture of a solution of tetrapropylammonium hydroxide (TPAOH), tetraethyl orthosilicate (TEOS) and water in molar ratio of (TPA)2O:5.5TEOS:90H2O was stirred homogeneously, then aged and refluxed for 3-day at 80° C. to obtain ZSM-5 seed crystal orienting agent. Dosing 180 g white carbon black, 10 g sesbania flour, an aqueous solution of 19.7 g sodium aluminate and 40 g ZSM-5 seed crystal orienting agent, further adding 230 g silica sol(40 wt %) and required amount of water, then kneading and drying to obtain a cylindrical precursor. In a reaction vessel, to which a mixture of 35 g ethylenediamine and 5 g distilled water was pre-added, 150 g cylindrical precursor as above-prepared was placed on a porous stainless steel screen therein, and a vapor-solid phase treatment was carried out at 160° C. for 5-day after sealing the reaction vessel. The product was washed with distilled water and dried, then was calcined at 550° C. in air. The calcined product was demonstrated to be a b...

example 2

[0031]Mixing 100 g white carbon black, 20 g USY zeolite with a molar ratio SiO2 / Al2O3 of 16 and 20 g ZSM-5 seed crystal orienting agent from example 1, adding aqueous solution of 26 g Al2(SO4)3.18H2O to adjust the Si / Al ratio, further adding 150 g silica sol(40 wt %), then kneading and drying to obtain a cylindrical precursor. In a reaction vessel, to which a mixture of 34 g ethylamine and 5 g distilled water was pre-added, 100 g cylindrical precursor as above-prepared was placed on a porous stainless steel screen therein, and a vapor-solid phase treatment was carried out at 180° C. for 5-day after sealing the reaction vessel. The product was washed with distilled water and dried, then was calcined at 550° C. in air. The calcined product was demonstrated to be a binder-free ZSM-5 / USY composite zeolite by XRD characterization, ZSM-5 zeolite and USY zeolite therein are at amounts of 91 wt % and 9 wt % respectively as determined through quantitative analysis by XRD, ZSM-5 zeolite there...

example 3

[0032]Mixing 180 g white carbon black, 140 g beta zeolite with a molar ratio SiO2 / Al2O3 of 20 and 40 g ZSM-5 seed crystal orienting agent from example 1, adding an aqueous solution of 110 g Al2(SO4)3.18H2O to adjust the Si / Al ratio, further adding 220 g silica sol(40 wt %), then kneading and drying to obtain a cylindrical precursor. In a reaction vessel, to which a mixture of 40 g ethylamine and 5 g distilled water was pre-added, 100 g cylindrical precursor as above-prepared was placed on a porous stainless steel screen therein, and a vapor-solid phase treatment was carried out at 150° C. for 7-day after sealing the reaction vessel. The product was washed with distilled water and dried, then was calcined at 550° C. in air. The calcined product was demonstrated to be a binder-free ZSM-5 / beta composite zeolite by XRD characterization, ZSM-5 zeolite and beta zeolite therein are at amounts of 70.5 wt % and 29.5 wt % respectively as determined through quantitative analysis by XRD, ZSM-5 ...

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Abstract

The present invention provides a catalyst comprising metallic Pt and / or Pd supported on a binder-free zeolite for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock, wherein the amount of metallic Pt and / or Pd is of 0.01-0.8 wt %, preferably 0.01-0.5 wt % on the basis of the total weight of the catalyst, and the binder-free zeolite is selected from the group consisting of mordenite, beta zeolite, Y zeolite, ZSM-5, ZSM-11 and composite or cocrystal zeolite thereof. The present invention also provides a process for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock using said catalyst.

Description

TECHNICAL FIELD [0001]The present invention relates to a catalyst as well as the corresponding process for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock.BACKGROUND ART [0002]Regarding the separation of aromatic hydrocarbons BTX,i.e.benzene, toluene and xylene, from non-aromatic hydrocarbons, some catalytic conversion processes have been developed in the prior art. For example, U.S. Pat. No. 3,729,409 disclosed converting non-aromatic hydrocarbons to lower alkanes by hydrocracking reaction and then separating aromatic hydrocarbons from non-aromatic hydrocarbons through gas-liquid separation; U.S. Pat. No. 5,865,986 and U.S. Pat. No. 6,001,241 disclosed a process for upgrading naphtha fraction, wherein a zeolite-based catalyst is used in some reactors to improve the production of aromatic hydrocarbons; and CN1217892C disclosed a similar process, wherein reformate, pyrolysis gasoline and the like are upgrade to produce LPG and light aromatic h...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C07C5/00B01J29/18B01J29/40B01J29/06
CPCB01J29/068B01J29/126B01J29/22B01J29/405B01J29/44B01J37/10B01J29/7415B01J29/80B01J37/0009B01J37/0018B01J29/74B01J21/12B01J23/42B01J23/44
Inventor WANG, DEJULIU, ZHONGNENGLI, XUELIHOU, MINBOWANG, ZHEMINGWANG, JIANQIANG
Owner CHINA PETROCHEMICAL CORP
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