Preparation method for soft magnetic ferrite with high saturation magnetic induction strength and high magnetic permeability

A technology of magnetic induction intensity and soft ferrite, which is applied in the field of preparation of soft ferrite with high saturation magnetic induction intensity and high magnetic permeability, can solve the problems such as unsatisfactory magnetic permeability and saturation magnetic induction intensity, unable to guarantee mass production, etc., and achieve easy follow-up. The effect of sintering, easy molding, high saturation magnetic induction

Inactive Publication Date: 2015-12-23
ZHONGDE ELECTRONICS
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  • Claims
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Problems solved by technology

[0004] With the development of the electronics industry and the expansion of application fields, the requirements for magnetic materials are getting higher and higher, and the classification requirements for material properties are more detailed and specialized, but the soft magnetic ferrite in the prior art often has a magnetic permeability And the saturation magnetic induction is not ideal enough. I hope that the corresponding powder index of the product can reach: the saturation magnetic induction > 480mT at 25°C, and the initial magnetic permeability is above 3800, but the materials currently used cannot guarantee mass production of products that meet this requirement. There is a need for a new soft ferrite material with high saturation magnetic induction and high permeability

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  • Preparation method for soft magnetic ferrite with high saturation magnetic induction strength and high magnetic permeability

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[0024] refer to figure 1 , the preparation method of a kind of high saturation magnetic induction intensity high magnetic permeability soft ferrite that the present invention proposes, comprises the following steps:

[0025] S1. Add ferrous chloride, manganese chloride, zinc chloride, and nickel chloride to hydrochloric acid to completely dissolve them, then add yttrium oxide and strontium oxide, and stir until completely dissolved to obtain material A;

[0026] S2. Add sodium hydroxide solution dropwise to the material A until the pH value is 9-11, let stand and age for 10-15h, then add triethanolamine and polyvinyl alcohol to stir, carry out hydrothermal reaction after standing, and cool naturally, Washing, suction filtration, and drying to obtain material B;

[0027] S3, after mixing zirconium oxide, titanium oxide, vanadium oxide, magnesium oxide, platinum oxide, molybdenum oxide, barium oxide, cerium oxide, tin oxide, indium oxide, borax, calcium carbonate, strontium car...

Embodiment 1

[0030] A kind of preparation method of high saturation magnetic induction intensity and high magnetic permeability soft ferrite proposed by the present invention comprises the following steps:

[0031] S1. Add 53 parts of ferrous chloride, 24 parts of manganese chloride, 18 parts of zinc chloride and 8 parts of nickel chloride into hydrochloric acid to completely dissolve in molar parts, then add 3.6 parts of yttrium oxide and 2.5 parts of strontium oxide, and stir After being completely dissolved, material A is obtained;

[0032] S2. Add dropwise sodium hydroxide solution to 100 parts of material A by weight until the pH value is 9, keep stirring during the dropwise addition of sodium hydroxide solution, let it stand for aging for 15 hours, then add 5 parts of triethanolamine and 10 parts Stir with 100% polyvinyl alcohol, carry out hydrothermal reaction after standing still, the temperature of hydrothermal reaction is 180 ℃, the time of hydrothermal reaction is 14h, natural c...

Embodiment 2

[0035] A kind of preparation method of high saturation magnetic induction intensity and high magnetic permeability soft ferrite proposed by the present invention comprises the following steps:

[0036] S1. Add 56 parts of ferrous chloride, 20 parts of manganese chloride, 22 parts of zinc chloride and 5 parts of nickel chloride into hydrochloric acid to completely dissolve in molar parts, then add 5.2 parts of yttrium oxide and 1.8 parts of strontium oxide, and stir After being completely dissolved, material A is obtained;

[0037]S2. Add dropwise sodium hydroxide solution to 100 parts of material A by weight until the pH value is 11, keep stirring during the dropwise addition of sodium hydroxide solution, let it stand for aging for 10 hours, then add 8 parts of triethanolamine and 4 parts Stir with 100% polyvinyl alcohol, carry out hydrothermal reaction after standing still, the temperature of hydrothermal reaction is 200 ℃, the time of hydrothermal reaction is 12h, natural co...

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Abstract

The invention discloses a preparation method for soft magnetic ferrite with high saturation magnetic induction strength and high magnetic permeability. The method comprises the following steps: adding ferrous chloride, manganese chloride, zinc chloride and nickel chloride into hydrochloric acid, after completion of dissolving, adding yttrium oxide and strontium oxide, and carrying out stirring until completion of dissolving so as to obtain a material A; dropwise adding a sodium hydroxide solution into the material A until a pH value is 9 to 11, carrying out standing and aging for 10 to 15 h, then adding triethanolamine and polyvinyl alcohol under stirring, then carrying out standing and hydrothermal reaction, and carrying out natural cooling, washing, filtering and drying so as to obtain a material B; and mixing zirconium oxide, titanium oxide, vanadium oxide, magnesium oxide, platinum oxide, molybdenum oxide, barium oxide, cerium oxide, tin oxide, indium oxide, borax, calcium carbonate, strontium carbonate and absolute ethanol, then carrying out ball milling, adding the material B and an adhesive and then carrying out uniform mixing, and carrying out pressing molding, microwave sintering and cooling so as to obtain the soft magnetic ferrite with high saturation, high magnetic induction intensity and high magnetic permeability.

Description

technical field [0001] The invention relates to the technical field of soft ferrite, in particular to a method for preparing soft ferrite with high saturation magnetic induction and high permeability. Background technique [0002] Soft ferrite refers to a magnetic material that is easily magnetized and demagnetized under the action of an external magnetic field. It is often a composite oxide obtained by sintering iron oxide and one or more other metal oxides. The application of soft magnetic materials in industry began at the end of the 19th century, with the rise of electric power and telecommunication technology, and its application range is extremely wide. Soft magnetic materials are not only used in the fields of home appliances, information technology, automobiles and other supporting fields, but more importantly, soft magnetic materials, as the main raw materials for the production of electronic components, have brought a steady stream of demand for them. [0003] At ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/40C04B35/622
Inventor 瞿德林王久如王晓祥李丛俊
Owner ZHONGDE ELECTRONICS
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