598results about How to "Good activity and stability" patented technology

The invention relates to a preparation method of a silicon/graphene laminar composite material for lithium ion battery cathode. The composite material adopts a laminar sandwich structure, silicon nano-particles are dispersed on each lamina of the grapheme, the laminas of the grapheme are separated from one another by the silicon nano-particles and the edges of the laminas are in lapped joint so as to constitute a laminar conductive network structure. The preparation method thereof comprises the steps of: formulating anhydrous silicon tetrachloride, surface active agent, sodium naphthalene and graphite oxide to tetrahydrofuran solution, adding the tetrahydrofuran solution into a reactor for reaction in vacuum at the temperature ranging from 380 to 400 DEG C, filtering the reactant to result in the product, and then washing, drying and heating the product to obtain the silicon/grapheme composite material. The preparation method of the invention has the advantages of simple preparation process and great easiness for industrial production; and the silicon/graphene laminar composite material prepared according to the method includes excellent conductivity, power performance, electrochemical activity and cycle stability, and is particularly suitable for manufacturing lithium ion battery cathode.

This invention discloses a hydrogenation method for producing low-sulfur diesel oil. The method comprises: mixing base oil with hydrogen, introducing into a hydrogenation reactor to orderly contact hydrogenation protecting agent, hydrorefining catalyst I, hydrorefining catalyst II and freely selected hydrorefining catalyst III for reactions, cooling the effluent, and separating to obtain hydrogen-rich gas and liquid product. With the synergism of the catalysts, the whole catalyst activity is improved. By the method, high-sulfur, high-nitrogen and high-metal content diesel oil fraction can be treated under mild conditions, and low-sulfur diesel oil that can meet Europe III standard and Europe IV standard can be obtained. The method has such advantages as simple process, low operation pressure, low apparatus investment and low operation cost.

A catalytic cracking catalyst and its production are disclosed. The catalyst consists of clay 20 - 80m%, silica sol 5 - 30m%, pseudodiaspore 0 - 30%, faujusite with cell parameters of (2.432 - 2.472nm) 5 - 40%, and balanced of ZSM-5 zeolite, beta zeolite and their mixture, oxide selected from Sb, rare earths, Ti, Mg, Zn, P, Sr or their mixture. It uses silica sol as substrate or silica sol and pseudodiaspore as composite substrate to increase macromolecular cracking ability and to improve wearproof performance. It can be produced by non-continuous process or multi-stream continuous process with easy mass production.

The invention discloses a catalysts grading method for coker dry gas hydrogenation for preparation of ethylene cracking feed. According to the method, coker dry gas is contacted with a hydrogenation catalyst to carry out a hydrogenation reaction, and olefin in coker dry gas is saturated to further obtain an ethylene cracking feedstock, wherein three hydrogenation reaction zones are successively arranged in a hydrogenation reactor. By reasonable grading of catalysts in different systems, advantages of the respective catalysts during different hydrogenation processes are fully performed. By synergism among the catalysts and by cooperation of reaction temperature gradients of the three hydrogenation reaction zones, activity of the monolithic catalyst is raised.

The invention discloses a preparation method for a self-supporting metal-doped cobalt phosphide nano structure and an application of the self-supporting metal-doped cobalt phosphide nano structure as a catalytic electrode in water electrolytic hydrogen production, and belongs to the technical field of hydrogen energy and fuel cells. According to the invention, a metal element is firstly used as a doping agent for introducing cobalt phosphide, in-situ growth, on the surface of a collector, of the cobalt phosphide is realized, the catalytic activity and the structural stability are improved, the problem that a powder catalyst needs a polymer binder for being effectively fixed on the surface of the electrode is solved, and therefore, the self-supporting metal-doped cobalt phosphide nano structure is suitable for large-scale industrial hydrogen production application.

The present invention relates to one kind of catalyst for liquid phase alkylation of ethylene to prepare ethylbenzene and aims at raising the stability and regeneration performance of catalyst. The present invention adops beta-zeolite molecular sieve with SiO2/Al2O3 molar ratio of 10-50 as catalyst, and the catalyst is processed first with high temperature steam and then with organic acid before use, and this raises the stability and regeneration performance of catalyst. The present invention may be used in the industrial production of liquid phase alkylation to prepare ethylbenzene.

The invention discloses reformate hydrogenation catalyst and the production method thereof. The invention is characterized in that the catalyst consists of a main active component, auxiliary agent, and carriers, the structural formula is Pd-Ma (Mb)/carriers; the main active component is a double noble metal component Pd, and the content is 0.01 to 0.5 wt percent; Ma is one of Au, Ag, Pt, Rh, and Ir, and the content is 0.01 to 0.5 wt percent; Mb is one of Sn, Pb, Sb, and Bi, and the content is 0.2 to 1.0 wt percent; the rest are carriers; inorganic acid or organic acid is taken as competitive adsorption auxiliary agent to achieve that the active component presents the distribution of an eggshell-shaped shallow layer, the active metal and the auxiliary agent are loaded by a distribution impregnation method or a co-impregnation method, and then the hydrogenation catalyst is produced through drying and roasting.

The invention relates to a silicon-containing distillate oil hydrofining method, which adopts the method that the silicon-containing distillate oil raw material and hydrogen pass through at least two hydrofining catalyst beds under the hydrofining condition, the silicon-containing distillate oil raw material first passes through a hydrogenising catalyst bed with the silicon catching function, and then passes through a conventional hydrofining catalyst bed; wherein the hydrogenising catalyst with the silicon catching function has a greater pore volume and a specific surface area and a relatively lower metal content. Compared with the prior art, the method has the advantages that the process is simple, the good hydrodesulfurization and hydrodedenitrification performance is kept on the premise of enhancing the silicon-containing ability, and the running period of the device is effectively prolonged. The method can be applied to various silicon-containing distillate oil hydrofining processes.

The invention discloses a preparation method of a catalytic combustion catalyst. The method comprises the following steps: firstly, performing hydrothermal pretreatment on a honeycomb ceramic matrix; secondly, soaking the honeycomb ceramic matrix with alumina sol; and finally, loading additives and precious metal active components. The catalyst coating obtained by the method of the invention has high bonding degree with the matrix, is difficult to crack and peel off and has less dosage of additives. Thus, the catalyst has good operational performance and activity stability and can maintain higher activity under the scouring of high space velocity airflow and thermal shock, so that the long-term stable operation of the catalyst can be ensured.

The invention discloses a metal-organic framework nanosheet as well as a preparation method thereof and application thereof in oxygen evolution reaction of electrolysis water. According to the preparation method, the energy consumption is low, the reaction is rapid, reaction conditions are mild, the thickness of the obtained metal-organic framework nanosheet is 3nm-5nm, the specific surface area can reach 450m<2>.g<1>, and the alkali resistance and the chemical stability are good. The metal-organic framework nanosheet can be prepared into an electrolysis water oxygen production electrode, and a particular ultra-thin sheet structure can be in well contact with the surface of the electrode, so that influences on mass transfer, diffusion and material resistance in the electrochemical oxygen production process are overcome, the initial oxidation potential can reach 1.42V, and the overpotential at 10mA/cm<2> can reach 250mV. By virtue of a 24-hour test, the oxygen production effect is still maintained above 99.6%, the activity, stability and price of the metal-organic framework nanosheet are superior to those of traditional noble metal RuO2, and extremely high actual application value is achieved.

The invention discloses a preparation method of a catalyst facilitating highly selective synthesis of light olefins from syngas. A compound adopting a spherical or ellipsoidal structure is taken as a carrier to be loaded with iron oxide and added with auxiliaries and is used for Fischer-Tropsch reaction for the syngas. The catalyst has very high catalytic activity on one hand and can effectively reduce alkane generated through secondary reaction hydrogenation of light olefins, and the selectivity of light olefins is improved. The preparation method of the catalyst is simple, and the catalyst has very good application prospects.

The present invention relates to a non-noble metal oxide combustion catalyst and a preparation method and use thereof, and belongs to the technical field of energy utilization and environment protection. The catalyst is iron oxide, cobaltosic oxide, nickel oxide, cupric oxide, vanadium oxide, chrome oxide, manganese dioxide or cerium dioxide prepared according to the following steps: (1) using hydrothermal chemical synthesis to form a precursor of a catalyst; and (b) washing, filtering, shaping, drying and calcinating the obtained precursor of the catalyst, and finally forming a combustion catalyst or coating the precursor of the catalyst on a carrier to form a combustion catalyst. The catalyst prepared by the method can be used in catalytic combustion of methane and other VOC gas, and has the advantages that the synthesis process is simple, the cost is low, the catalytic activity and hydrothermal stability is high, and the light-off temperature and complete combustion temperature of methane are low.

The invention provides a silicon and phosphorus modified ZSM-5 molecular sieve and a preparation method thereof; the relative crystallinity of the molecular sieve is at least 75%; the distribution D of the phosphorus is larger than or equal to 0 and less than or equal to 0.5, wherein the D is equal to P(S)/P(C); the P(S) shows the phosphorus content at one fifth of the distance of crystal grains of the molecular sieve characterized with a TEM-EDX method from the edge to the center; and the P(C) show the phosphorus content at the center of the crystal grains of the molecular sieve. Compared with the prior art, the phosphorus contained in the silicon and phosphorus modified ZSM-5 molecular sieve provided by the invention is unevenly distributed on the surface layer and central layer of the molecular sieve. When the molecular sieve is used as a catalyst and applied to toluene alkylation with methanol for preparing p-xylene, the molecular not only shows excellent selectivity on the p-xylene and simultaneously has better activity and stability.

The invention provides a preparation method of dimethyl sulfoxide, the method is as follows: in oxidation reaction conditions, dimethyl sulfide is contacted with at least one oxidant, and the catalyst contains at least one titanium silicon molecular sieve. According to the preparation method of the dimethyl sulfoxide, the dimethyl sulfide conversion rate is high, the effective utilization rate of the oxidant is high, the dimethyl sulfoxide selectivity is good, the usage amount of the dimethyl sulfide and the oxidant can be effectively reduced, and the production cost of the dimethyl sulfoxide can be reduced. According to the method of the invention, the activity stability of the catalyst is good, even by long-time continuous operation and multiple-times of cycle use of the catalyst, a high dimethyl sulfide conversion rate, a high effective utilization rate of the oxidant and high dimethyl sulfoxide selectivity also can be achieved. In addition, the method of the invention is mild in reaction condition, easy to control, and suitable for mass production.

A catalyst for catalytic cracking process is prepared from kaolinite, solid crystal seed, assistant, organic disperser and/or adhesive through spray drying, shaping microspheres, high-temp calcining,crystallizing reaction on sodium silicate and sodium hydroxide to obtain crystallized microspheres (content of NaY zeolite is 20-70%, ratio of zeolite silica-alumina is 4.0-6.0), calcining, and exchanging with NH4 and Re3 three times. Its advantages are high resistance to heavy metal, high activity and stability, and low cost.

A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula:

(0-0.3)Na₂O.(0.3-5.5)Al₂O₃.(1.0-10)P₂O₅.(0.7-15)M1_xO_y.(0.01-5)M2_mO_n(0-10)RE₂O₃.(70-97)SiO₂  I

or

(0-0.3)Na₂O.(0.3-5)Al₂O₃.(1.0-10)P₂O₅.(0.7-15)M_pO_q.(0-10)RE₂O₃.(70-98)SiO₂  II

The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.

A high-activity catalyst for catalytic cracking process is prepared from kaolinite, solid seed, assistant, organic disperser and adhesive through spray drying, shaping, microspheres, high-temp calcining, crystallizing reaction on sodium silicate and sodium hydroxide to obtain crystallized microspheres content of zeolit is 20-70%, ratio of zeolit silica-alumina is 4.0-6.0), calcining, and exchanging with NH4 and Re3 three times. Its advantages are high resistance to heavy metal, high activity and stability, and low cost.

The invention discloses nano-composite hydrogenation catalyst composition and a preparation method thereof. The catalyst composition includes active metal oxide and the composition of porous melt-resistant inorganic oxide. By utilizing the property that the precursors of the melt-resistant inorganic oxide, promoter oxide and the active metal oxide can form super-solubility nanometre micelle under the existence of surfactant with the VB value less than 1 and hydrocarbon composition, the invention facilitates the precursors and the hydroxide formed by precipitant to be in situ synthesized inside a micelle, so as to avoid the augment of the particle diameter of the oxide, and to facilitate the particle diameter to be in a single dispersed state. The catalyst of the invention has high specific surface area, large pore volume, large pore diameter, wide application range and good activity stability. The method of the invention has the advantages that the nano particle diameter is easy to be controlled, the distribution range of the particle diameter is narrow and the proportion of the carrier and the active component can be adjusted. The amount of the surfactant and the hydrocarbon component used for the method of the invention is less, and the cost is low.

The invention provides an amphiphilic Janus nano particle and a preparation method and application thereof. The preparation method comprises the following steps: dispersing silicon dioxide nanoparticles in water to obtain a dispersion liquid, mixing the dispersion liquid and liquid paraffin, heating and stirring in a water bath to form a Pickering emulsion, cooling to obtain small wax balls, adding a silane coupling agent into the small wax balls for modification to obtain modified small wax balls, mixing the modified small wax balls, an amidation catalyst and C12-C18 saturated fatty acid, andcarrying out an amidation reaction process to obtain organic hydrophobic chain grafted oil-water amphiphilic nanoparticles, and removing paraffin in the organic hydrophobic chain grafted oil-water amphiphilic nanoparticles to obtain the amphiphilic Janus nano particles. When the surfactant is used as an oil-displacing agent, oil-water interfacial tension can be effectively reduced at low concentration, rock wettability is changed, oil-displacing efficiency of nanofluid is remarkably improved, economic cost is reduced, and the surfactant has a wide application prospect.

This invention discloses a method for producing low-sulfur low-arene diesel oil. The method comprises: mixing base oil and hydrogen, introducing into a hydrogenation reactor, reacting in the first hydrogenation region by contacting hydrorefining catalyst I, directly introducing the reaction product into the second hydrogenation region without separation, reacting by contacting hydrorefining catalyst II, cooling and separating the reaction product to obtain hydrogen-rich gas and liquid substance, circulating the hydrogen-rich gas for repeated use, introducing the liquid substance into a fractionating system, fractionating to obtain crude gasoline fraction, light diesel oil fraction and heavy diesel oil fraction, introducing part or all of the heavy diesel oil fraction bake to the hydrogenation reactor. By the method, high-sulfur, high-nitrogen and high-metal content diesel oil fraction can be treated under mild conditions, and clean diesel oil (with low sulfur content and low arene content) can be obtained. The method has such advantages as simple process, low operation pressure, low apparatus investment and low operation cost.

The invention relates to a preparation method of a visible light catalyst with a surface plasmon effect and application thereof. The active component of the visible light catalyst is a precious metal Au, and the carrier is one of TiO2, CeO2, Nb2O5, SiO2, Ta2O5, Al2O3 and ZrO2, wherein, Au accounts for 0.2-5% in mass content, and the particle size of Au particle is 2-20nm. Preparation of the catalyst consists of two steps: the first step is to prepare a carrier; the second step is to prepare an Au/TiO2 (CeO2, SiO2, Al2O3, Nb2O5, Ta2O5, ZrO2) visible light catalyst with a plasmon effect througha sol precipitation method. Au nanoparticles prepared by the method of the invention have good dispersibility, easily controllable size, high active component utilization rate, as well as the effect of high efficiency photocatalytic degradation of organic pollutants by visible light.

The invention relates to a production method for ultra-low sulfur diesel oil; wherein, after mixed with hydrogen, straight-run atmosphere 3rd side cut distillate and (or) diesel oil heavy distillate enter(s) a first hydrogenation reaction zone and reacts under the action of hydro-upgrading catalyst and hydrofining catalyst; after mixed with the reaction effluent of the first hydrogenation reaction zone, straight-run atmosphere 2nd side cut distillate and (or) diesel oil light distillate enter(s) a second hydrogenation reaction zone and reacts under the action of the hydrofining catalyst; the reaction effluent of the second hydrogenation reaction zone is cooled, separated and distilled to obtain naphtha fraction and diesel products. The method provided by the invention can treat the diesel distillate with high sulfur, high nitrogen and high final boiling point, and under mild operating conditions, obtain clear diesel products with low content of sulfur and polycyclic aromatic hydrocarbons as well as high cetane number; meanwhile, the product quality can reach the indexes of the IV European emission standard.

The present invention is catalytically cracking co-catalyst for raising diesel oil yield and its preparation process. The co-catalyst is prepared with sprayed microballoon containing kaolin, pseudo boehmite and water galss, and through high temperature roasting over 900 deg.c, extraction with sodium hydroxide or other strong alkali to form pore channels, and final supporting phosphorus and RE oxide. The co-catalyst contains phosphorus in 1-3.5 wt%, RE oxide in 1-5 wt%, no zeolite component and sodium oxide less than 0.6 wt%. Adding certain amount of the co-catalyst into FCC catalyzing apparatus can raise diesel oil yield, improve product distribution and raise the utilization rate of available catalyst.

The invention relates to a heteroatom doped hollow carbon sphere material loaded precious metal nano particle and preparation thereof. The preparation comprises the following steps that firstly, heteroatom doped hollow carbon spheres are prepared, wherein 1-1, silicon dioxide serves as a template, comonomer phosphonitrilic chloride trimer and 4,4-dyhydroxyl bi-phenol are added, a polymerization reaction is carried out, and polyphosphazene wrapping silicon dioxide is generated; 1-2, the polyphosphazene wrapping silicon dioxide is calcined, and heteroatom doped carbon spheres with silicon dioxide as cores are obtained; 1-3, ultrasonic etching continues to be carried out, and after washing and drying, the heteroatom doped hollow carbon spheres are obtained; secondly, the prepared heteroatom doped hollow carbon spheres are dispersed into water, a precious metal precursor and a complexing agent are added, pH is adjusted to be 8-14, a reducing agent is added, stirring is carried out for a reaction, and after drying, the target product is obtained. Compared with the prior art, the catalyst has good electrocatalytic activity and electrochemical stability, and the preparation process is simple.

The invention relates to biological microcrystalline glass prepared by utilizing phosphate tailings and a preparation method thereof. The biological microcrystalline glass comprises the following raw materials in parts by weight: 30 to 35 parts of the phosphate tailings, 15 to 25 parts of quartz sand, 10 to 16 parts of aluminium hydroxide, 20 to 28 parts of calcium hydrophosphate, 9 to 13 parts of calcium fluoride, 0 to 5 parts of magnesium oxide, 0 to 5 parts of zinc oxide and 0.5 part of sodium borate, wherein the utilization rate of the tailings reaches more than 30%. Compared with a product produced by utilizing conventional chemical raw materials, the biological microcrystalline glass has better physical and chemical properties and realizes reduction in the raw material cost by more than 30%. Based on the SiO2-Al2O3-P2O5-CaO-CaF2 system, the magnesium and the zinc are utilized to replace the partial calcium, so that a new magnesium-series wagnerite phase and a zinc-series zinc pointed crystal phase are generated, and therefore, the brittleness of the biological microcrystalline glass is improved while the mechanical strength is improved. In addition, the biocompatibility, the bioactivity and the chemical stability of the biological microcrystalline glass are improved.