This invention provides a
denitrification catalyst suitable for alkali furnaces, its preparation method, and its application, comprising the following raw materials: TiO2 support, pore modifier,
vanadium precursor,
tungsten precursor, Ce-modified component, and La-modified component; based on the
mass of the TiO2 support, the
mass percentages of the pore modifier are 3-7%, the
vanadium precursor is 1-3%, the
tungsten precursor is 1-7%, the Ce-modified component is 1-5%, and the La-modified component is 0.5-1.5%; the pore modifier is
methyltrichlorosilane. This invention uses a V-W-Ti
system as its base. By modifying the pore structure of the TiO2 support,
capillary condensation is eliminated, and hydrophobicity is achieved; Ce modification of the V-W-Ti
system enhances the
selective adsorption of
oxygen vacancies and NH3; and La modification of the V-W-Ti
system enhances the acidity of the catalyst and provides
alkali metal sacrificial sites. These three components synergistically address the problems of water poisoning, alkali poisoning, and insufficient activity at low temperatures.