The invention relates to a purification process of liquefied gas and particularly provides a high-temperature hydrogenation and purification process for liquefied gas materials. The high-temperature hydrogenation and purification process is characterized by comprising the following steps: (1) carrying out heat exchange on raw material liquefied gas and a reactor outlet product in a heat exchanger, heating by a heating furnace to a reaction temperature, then feeding the material into a reactor from the top, carrying out saturation hydrogenation on olefin in the material to obtain alkane, and respectively hydrogenating and converting sulfide, oxide, nitride and halide into hydrogen sulfide, water, ammonia and hydrogen halide; (2) carrying out sufficient heat exchange on the reactor outlet product and the raw material by an efficient heat exchanger, carrying out water cooling by a water cooler and enabling the material to enter a gas-liquid separation tank, compressing a flashing gas phase and fresh hydrogen by a compressor and circulating to the raw material liquefied gas; (3) enabling the flashing liquid phase to enter an alkali washing deposition tank and carrying out fiber membrane alkali washing to remove hydrogen sulfide, ammonia and hydrogen halide; (4) enabling the material which is subjected to the alkali washing to enter a dearsenicator, and removing arsenic and metal to obtain refined liquefied gas. The high-temperature hydrogenation and purification process mainly aims at a project which is very strict in requirement on the impurity content of a catalyst, and is short in flow, small in investment, low in cost and less in solid wastes.