The invention provides pseudo-
boehmite, a preparation method thereof and a gamma-
alumina carrier with high
diffusion mass transfer performance. The preparation method comprises the following steps: respectively preheating an aluminum-containing acidic solution, a
sodium metaaluminate solution and reaction
bottom water to
gel forming reaction temperature; under stirring, dropwise adding the first part of the aluminum-containing acidic solution and the first part of the
sodium metaaluminate solution into the reaction
bottom water, controlling the pH value of the gelling reaction to be 5.0-8.5, and uniformly mixing to obtain material
slurry; dropwise adding all the residual aluminum-containing acidic solution and the residual
sodium metaaluminate solution into the material
slurry, and carrying out
gel forming reaction to obtain reaction
slurry; and carrying out step-by-step variable-temperature aging on the reaction slurry, and carrying out suction
filtration, washing and
drying to obtain the pseudo-
boehmite. According to the method, the problem of poor pore regulation flexibility in a traditional double-aluminum method is solved, the limitation of the pore size can be overcome, and the pore permeability of the gamma-
alumina carrier is improved, so that the
diffusion mass transfer performance of the gamma-
alumina carrier is greatly enhanced.