The application relates to the technical field of
lithium batteries, and particularly discloses a
solid-state
lithium battery
polymer electrolyte and a preparation method thereof, which are used to solve the problems of a complicated preparation process, easy interlayer voids, and interface discontinuity of a multilayer gradient
composite polymer electrolyte film, and to improve the problems of nanofiller agglomeration, high
ion transmission impedance, poor mechanical performance, and poor batch consistency. The
electrolyte comprises a
solid-state electrolyte film, and the
solid-state electrolyte film is composed of a
polymer reticular matrix, a
lithium ion carrier, an inorganic nanoskeleton, a surface active additive, a visible
light sensitive photoinitiator, a
silane coupling agent, and a nucleating agent. The preparation method comprises the following steps: preparing a
prepolymer solution, infiltrating and fusing, electric pulse orientation, one-step crosslinking and solidification,
solvent replacement, and online screening. The application combines
solvent system optimization, mixed process regulation, and electric pulse orientation to construct continuous gradient nanochannels, so that the comprehensive performance of the solid-state electrolyte film is improved in terms of
ion conductivity,
interface impedance, tensile strength, and capacity
retention rate at 25 DEG C.