The invention discloses an organic small molecule acceptor material and its preparation method and application. Suzuki‑Miyaura coupling reaction starting from 2,7‑dibromobenzo[b]benzo[4,5]thieno[2,3‑d]thiophene (BTBT) and difluoro‑indandione , Friedel-Crafts reaction, Vilsmeier-Haack reaction and Knoevenagel condensation reaction to synthesize A-D-A type organic small molecule acceptor material, as shown in formula (I), the resulting material can be purified by recrystallization, and has good thermal stability. When it is applied to polymer solar cells, an energy conversion efficiency of 12.66% can be obtained under optimized device conditions, which has certain practical application value.