The invention relates to a novel process for preparing an organic-inorganic
perovskite thin film through adopting an experimental scheme in which two kinds of
metal compounds are adopted as precursors. With the novel process adopted, an efficient
solar battery device with a planar structure can be prepared. According to the novel process, the two kinds of
metal compound precursors are compounded, and therefore, a pinhole defect of the
perovskite thin film can be effectively avoided, and compound of electrons and holes can be alleviated, and short-circuiting risks of the
perovskite thin film can be decreased. The novel process of the invention belongs to the photoelectric material field and is characterized in that the two kinds of
metal compounds are selected as a source of metal ions in a perovskite material, wherein the general formula of the organic-inorganic perovskite material is ABX3, wherein A is CH3NH3 or NH2-CH=NH2, B is Pb or Sn, and X is I or Br. With the preparation method adopted, the thickness of the perovskite thin film is uniform, and the
crystallinity of the perovskite thin film is high, the perovskite thin film can have
high electron and hole transport ability. The preparation method is suitable for large-area preparation of organic-inorganic perovskite
solar battery devices with planar structures.