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67 results about "Molecular precursor" patented technology

Preparation method of molecularly-imprinted magnetic silica microsphere with hydrophilic external surface

The invention relates to a preparation method of a molecularly-imprinted magnetic silica microsphere with a hydrophilic external surface. The preparation method comprises the following steps: A, preparing a magnetic silica microsphere by taking Fe3O4 as magnetic particles, ethyl alcohol and distilled water as reaction solvents and TEOS (Tetraethyl Orthosilicate) as a molecular precursor; B, with anhydrous methylbenzene as a solvent, and reacting the magnetic silica microsphere with KH-550 to obtain an amination magnetic silica microsphere; C, with bisphenol A as a template molecule, TEOS and PTMS (Phenyltrimethoxysilane) as cross-linking agents and HCl as a catalyst, reacting with the amination magnetic silica microsphere, and eluting the template molecule to obtain a bisphenol A imprinted magnetic silica microsphere; and D, reacting the bisphenol A imprinted magnetic silica microsphere with KH-560, and performing hydrolysis to obtain the molecularly-imprinted magnetic silica microsphere with the hydrophilic external surface. The method has the advantages of simplicity in preparation, strong selectivity, excellent enrichment and high separation efficiency, is capable of effectively excluding biomacromolecules and reducing impurities of treated samples and can be widely used in separation and extraction of pretreatment of the samples.
Owner:HEBEI UNIVERSITY

Graphite-phase carbon and nitrogen compound powder, as well as preparation method and application thereof

The invention relates to graphite-phase carbon and nitrogen compound powder, as well as a preparation method and an application thereof. The powder uses an aromatic multimember heterocyclic ring composed of carbon and nitrogen elements as a repeat unit, and has a layered graphite phase structure. The preparation method of the powder comprises the following steps of: slowly heating an organic small-molecule compound containing carbon and nitrogen elements and other precursors to 450-600 DEG C, reacting at the temperature to form a yellow solid, washing the solid with an acidic solution and drying to obtain a target product. According to the invention, the product is acquired by carrying out a solid phase reaction under normal pressure and using inexpensive and easily available raw materials containing carbon and nitrogen elements as a single molecular precursor, the process is simple, the reaction atmosphere does not need to be adjusted and controlled, the equipment investment is low, the large-scale production can be realized, and the obtained product has multiple optional practical forms and can be widely applied in the industries of air purification, such as sewage treatment, self-cleaning coating, environmental purification including hydrogen preparation through utilizing water photolysis and CO2 photocatalytic reduction and the like, solar energy conversion and utilization, etc.
Owner:SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI

High-molecular mask plate and manufacturing method and application thereof

The invention discloses a high-molecular mask plate. The high-molecular mask plate comprises a bearing substrate, a sacrificial layer and a mask, and the sacrificial layer and the mask are sequentially arranged on the bearing substrate in an overlapped mode. The mask comprises a high-molecular membrane layer and a plurality of holes which are formed in the high-molecular membrane layer and penetrate through the high-molecular membrane layer, and magnetic nano-particles are doped in the high-molecular membrane layer. The invention further discloses a manufacturing method of the high-molecular mask plate. The manufacturing method comprises the steps that S1, the sacrificial layer is manufactured on the bearing substrate; S2, the sacrificial layer is coated with a high-molecular precursor doped with the magnetic nano-particles, curing is conducted for membrane forming, and a raw high-molecular membrane is formed; S3, ablation is conducted on the area, unshielded by a photomask mask plate,of the raw high-molecular membrane through the photomask mask plate in a laser scanning mode so as to form holes and the mask, and a high-molecular mask plate precursor is obtained; and S4, after thehigh-molecular mask plate precursor is cleaned and dried, the acting force between the bearing substrate and the mask is weakened, and the high-molecular mask plate is obtained. The invention furtherdiscloses application of the high-molecular mask plate to OLED manufacturing.
Owner:WUHAN CHINA STAR OPTOELECTRONICS SEMICON DISPLAY TECH CO LTD

Method for preparing high-quality stannic sulfide nanosheet by use of single-source molecular precursor

The invention relates to a method for preparing a high-quality stannic sulfide nanosheet by use of single-source molecular precursor. The method comprises adding stannic chloride pentahydrate into anhydrous ethanol to prepare stannic chloride solution; dissolving sodium diethyldithiocarbamate powder in anhydrous ethanol to prepare sodium diethyldithiocarbamate solution; adding the stannic chloride solution into the sodium diethyldithiocarbamate solution, stirring, vacuum filtering and drying at 60 DEG C. to obtain a single-source molecular precursor Sn-(DDTC)4; putting the single-source molecular precursor Sn-(DDTC)4 into a high pressure vessel, and adding 2.5%-10% aqueous solution of acetic acid as solvent; and placing in an electric oven, heating at 180 DEG C. for 24 hours, cooling, vacuum filtering, washing by deionized water and anhydrous ethanol, and drying at 60 DEG C. to obtain yellow stannic sulfide powder. The invention overcomes the defects of an element direct reaction method and a chemical precipitation method, involves a low-toxicity easily-accessible single-source molecular precursor with reasonable price, simplifies the preparation process, and easily obtains a uniform-composition pure phase nanomaterial conforming to stoichiometric ratio. The obtained product has high crystallization degree and is nanosheet-like pure hexagonal phase stannic sulfide.
Owner:YANGZHOU UNIV
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