The invention relates to a series of mulberry-shaped grade pore ZSM-5
molecular sieve single crystal derivatives and a synthesis method and application thereof. The preparation method comprises the following steps: under the conditions of no mesoporous template agent and no
etching treatment, firstly, by adjusting
zeolite nucleation and growth
kinetics, constructing a mulberry-shaped hierarchical pore ZSM-5
molecular sieve single crystal; then carrying out
ammonium exchange treatment to prepare mulberry-shaped H-type grade pore ZSM-5
molecular sieve single crystals; and then loading
rare earth elements into the mixture by adopting an impregnation method to obtain the mulberry-shaped
rare earth loaded H-type grade pore ZSM-5 molecular
sieve single crystal. According to the preparation method, the dual
gain effects of enhancing
diffusion of a grade pore structure and improving acidity of the
rare earth metal La are realized by utilizing the acidity
modulation effect of the
rare earth element La and the synergistic modification effect of
carbon deposit species, so that on one hand, the problem of micropore blockage caused by traditional molecular
sieve impregnation is solved; on the other hand, the MTO catalytic life and the propylene selectivity of the
bifunctional catalyst are remarkably improved by utilizing low-load rare earth elements.