The invention discloses a preparation method and application of a hierarchical
zinc-based negative
electrode material, and belongs to the technical field of preparation of electrochemical materials. The
zinc-based negative
electrode material is prepared by an accumulative roll-bonding method, one or more dissimilar metals and a
zinc plate are subjected to hot-pressing rolling, an interface
alloy layer is formed on a contact surface, and the nano-level zinc-based negative
electrode material is obtained by repeated roll-bonding. Wherein
crystal grains are obviously refined through
hot pressing, uniform regulation and control of a
crystal structure are achieved through high-strain-rate rolling, orientation heterogeneity is eliminated, and the
electroplating stripping performance in charge-
discharge circulation is effectively improved. The synergistic effect of the nanolayer
alloy structure and the unipolar mode
texture feature fully releases the electrochemical advantages of high
ion diffusion rate, excellent
conductivity, low polarization and the like. The technology has the characteristics of simple process, low cost, easiness in large-scale production and the like. The prepared zinc-based negative
electrode material successfully solves the key problems of dendritic
crystal growth,
side reaction and the like caused by non-uniform deposition of zinc ions, and the
cycling stability of the electrode is remarkably improved.