The invention discloses an energetic
type metal-organic framework material and a preparation method thereof. The complex consists of five
metal ions Co(II), four 2,2'- binitro-4, 4'-biphenyldicarboxylic acid ligands, six coordinated water, two hydroxyls and sixteen
crystal water. The preparation method for the energetic
type metal-organic framework material comprises the following steps: adding the ligands into H2O, regulating the pH by use of LiOH, then, adding Co(NO3)2.6H2O, sufficiently stirring, placing into a stainless steel reaction kettle with a
polytetrafluoroethylene lining; heating the stainless steel reaction kettle to 150 DEG C in a programmed manner and keeping the temperature for 48 hours, cooling the stainless steel reaction kettle to the
room temperature in the programmed manner, leaving purple pink cubic
crystal particles on the lining wall, filtering, washing and
drying in the air to obtain the complex. The
brisance and the work capability of the
energetic material prepared by the preparation method are improved.