The invention discloses silicon solar cell front face electrode silver paste. The silicon solar cell front face electrode silver paste comprises, by mass, 75-80 percent of silver powder, 3-10 percent of lead-free glass powder, 10-15 percent of organic vehicle and 0.5-3 percent of additive. The silver powder is the spherical micro silver powder with nano bismuth serving as the core, the silver content is 99.1-99.7 percent, the bismuth content is 0.3-0.9 percent, the particle size is 1-2 microns, the tap density is 4.5-5.0 g/ml, the specific surface area is 0.4-1.0 m<2>/g, and the silver powder is prepared by conducting liquid-phase chemical reduction on bismuth nitrate and silver nitrate through glyoxal or acetaldehyde. Bismuth-silicon-antimony-molybdenum lead-free glass powder serves as an adhesive, and potassium fluotitanate, potassium fluoroaluminate, magnesium fluoride and the like are added to serve as the silicon nitride antireflective film eroding additive. According to the silicon solar cell front face electrode silver paste, the contact resistance between a silver electrode and a silicon wafer can be reduced, the stripping strength of the electrode is improved, the electrical property of a solar cell is improved, the production cost of the conductive silver paste is reduced, and the requirement for nonexistence of lead and environmental friendliness are met.