The invention discloses a microelectrochemical analyzer, which includes a power supply device, an optical microscope, an electrolytic cell, a camera, a computer, and a control software with image display and editing functions. The optical microscope and the CCD camera are connected through a standard CS interface, and the CCD The camera is connected to the computer through a video card, and the CCD camera transmits the data to the computer for software control and then enlarges and displays it on the monitor. The electrolytic cell is connected with a multifunctional power supply to form a working pool for electrochemical migration and electrochemical reaction. The present invention utilizes the principles of biological microscopic technology, electrochemical migration, and digital imaging technology to design and establish a set of electrical equipment that can continuously observe, photograph, and analyze various polar phase / non-polar phase systems under various electric field conditions. Migration, demulsification, and electrochemical reaction, an instrument that magnifies the microscopic dynamic process by more than 10 to 1500 times. It can be widely used in scientific research, analysis, detection, determination and improvement of production industry in various industrial fields such as petrochemical industry, bioengineering, and pharmaceutical industry.