The invention relates to the technical field of
industrial gas separation, in particular to a fluosilicate porous
hybrid material and a preparation method and application thereof. The structural general formula of the fluosilicate porous
hybrid material is [Cu(dpds)2(SiF6)]n, and dpds is 4,4'-dipyridyl disulfide. A
metal salt used by the fluosilicate porous
hybrid material is
copper hexafluorosilicate, the organic ligand is 4,4'-dipyridyl disulfide, and the fluosilicate porous
hybrid material is an anionic pillared
metal organic framework material with a proper
pore diameter and a proper fluorination functional site; the preparation method is low in
raw material price, cost-saving, simple to operate, easy to control conditions and easy to industrialize; and the fluosilicate porous
hybrid material provided by the invention has appropriate
pore diameter and fluorinated functional sites, can enhance the recognition of
acetylene through the action of
hydrogen bonds, can separate C2H2 / C2H4
mixed gas and / or C2H2 / CO2
mixed gas at the same time, and has higher separation selectivity, larger adsorption capacity and higher separation performance than most existing
solid adsorption materials.