The invention relates to a fluorosulfonate-based compound preparation method, and belongs to the technical field of battery electrolytic solution additives. The preparation method comprises: using phenol, ethanol, allyl alcohol or 4-pentyne-1-ol as a raw material, adding the raw material, triethylamine and dioxane to a reaction container, stirring for 1-2 h at a room temperature, introducing sulfuryl fluoride gas, carrying out a reaction for 12-24 h at a reaction temperature of 35-50 DEG C by controlling the reaction pressure of the system at 7-10 atm, adding a hydrochloric acid aqueous solution, acidifying for 20-30 min, carrying out pressure reducing rotary evaporation on the solvent, and carrying out separation purification to obtain fluorosulfonyloxybenzene, fluorosulfonyloxyethane, allyl fluorosulfonate or 4-pentyne-fluorosulfonate. According to the present invention, the preparation method is simple, and the prepared fluorosulfonate-based compound has characteristics of high purity, high yield, safety and environmental protection.