The invention discloses Gemini dication based acid ionic liquid and a preparation method thereof. The structure of a cation part of the ionic liquid is represented by a formula I, a formula II, a formula III or a formula IV, wherein in the formula I, the formula II, the formula III or the formula IV, m represents 3 or 4, and n represents an integral number of 1-15; and the structure of an anion part is selected from one of CH3(C6H4)SO<3->, C6H4COO<->, CF3SO<3->, CH3SO<3->, CH3COO<->, CF3COO<->, HSO<4->, BF<4->, PF<6->, H2PO<4->, NO<3-> and Cl<->. The preparation method comprises the following steps of: making Gemini bi-heterocyclic alkane react with alkyl sulfoacid inner ester to generate a sulfoacid inner salt; and then making the sulfoacid inner salt react with acid to obtain the ionic liquid. The ionic liquid can be used as a substitute of a traditional liquid acid catalyst and has industrial application prospect.