The application belongs to the field of membrane
separation technology, and particularly relates to a novel high
desalination rate anti-
pollution reverse osmosis membrane material and a preparation method thereof. The preparation method comprises the following steps: contacting a porous support membrane with an
aqueous solution containing mixed
polyamine monomers and amine-modified nano-
silicon dioxide, and then interfacially polymerizing with an
oil phase solution containing mixed polyacyl
chloride monomers to form a
polyamide separation layer; then
coating a sulfonated polyether
sulfone coating solution to form a first modified layer; and finally
coating a reaction solution containing modified polyethyleneimine, carboxylated
graphene oxide and a crosslinking agent to form a second modified layer. By compounding aromatic and alicyclic polyamines, and combining amine-modified nano-
silicon dioxide anchored in the
polyamide network to form a dense separation layer, high
desalination rate is ensured; by chemical bonding between the sulfonated polyether
sulfone layer and the modified polyethyleneimine / carboxylated
graphene oxide / crosslinking agent layer, a stable double-layer modified structure is constructed, and excellent anti-
pollution performance is given to the
membrane surface. The obtained membrane material has high
desalination rate, strong anti-
pollution property and stable structure.