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2914results about How to "High reuse rate" patented technology

Substrate with surface-enhanced Raman scattering activity and preparation method thereof

The invention provides a substrate with surface-enhanced Raman scattering activity and a preparation method thereof, and the method comprises the following steps: the glass base surface is subjected to hydroxylation and amination treatment; catalytic hydrolysis is carried out on ethyl orthosilicate under the alkali condition by taking alcohol as a solvent; Silica microspheres with even size and smooth surface are prepared by an oscillation method; silane coupling agent of which the tail end is provided with amino is assembled on the surface of the silica microspheres; silver sol obtained by reducing sodium borohydride to silver nitrate through oscillation is assembled on the surface of SiO2-NH2NPs, and is diffused in water again after centrifugal separation and washing by distillated water; self assembly is carried out on the silver sol after being placed in SiO2@Ag NPs dispersion for 6-12h; the SERS active substrate is obtained after taking out from water and drying. In the SERS active substrate of the invention, the active particles and the substrate are combined firmly, thus being applicable to detecting unimolecular Raman signals in aqueous solution; the substrate can be used for SERS detection repeatedly, thus improving repeated utilization ratio of the substrate.
Owner:NORTHWEST NORMAL UNIVERSITY

Method for deeply treating, desalting and recycling industrial wastewater with high salt content

The invention relates to the field of industrial wastewater treatment processes and provides a method for deeply treating, desalting and recycling industrial wastewater with high salt content. The method comprises the following steps: 1) carrying out efficient coagulation treatment on the industrial wastewater with high salt content to obtain supernatant; 2) carrying out chemical precipitation on the supernatant obtained in the step 1) to remove high valence ions with valence higher than bivalence in the wastewater; 3) carrying out catalytic ozonation treatment on the supernatant subjected to chemical precipitation in the step 2); 4) carrying out multi-media filtration, precise filtration and membrane filtration treatment on the wastewater subjected to catalytic ozonation in the step 3) in sequence; and 5) carrying out electrodialysis reversal treatment on the effluent obtained after membrane filtration in the step 4). By adopting the method, organic matters, bacteria, colloids, suspended particles, Ca<2+>, Mg<2+> and high valence ions, other soluble inorganic salts and the like in the industrial wastewater with high salt content are removed by utilizing the coupling and synergistic effects of different unit technologies, thus achieving deep treatment, desalting and recycling of the industrial wastewater with high salt content.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Conduction cooling superconducting magnet dewar convenient for loading and unloading

The invention relates to a conduction-cooled superconducting magnet Dewar with easy loading-unloading, comprising a Dewar cylinder. The conduction-cooled superconducting magnet Dewar is characterized in that the Dewar cylinder is a hollow annular cylinder, the middle of the annular cylinder is provided with a room temperature hole, an annular copper cold shield is arranged in the Dewar cylinder, a refrigerator and a superconducting magnet are arranged in the copper cold shield, a vacuum pumping port is arranged on the Dewar cylinder, a measuring device is arranged on an upper cover of the Dewar cylinder and the Dewar cylinder is in a vacuum state. Compared with the prior Dewar container, the conduction-cooled superconducting magnet Dewar is simpler, has small conduction heat leakage, and has the advantages of easy installation and disassembly; the refrigerator is used for conducting and cooling without a low temperature liquid (such as liquid helium and so on) cooling system; because of simple and safe system, a first-level cold junction of the refrigerator is operated under a temperature of 77K, thereby realizing heat sink of the copper cold shield, an electric lead and a support device; the first-level cold junction of the refrigerator adopts soft connection, thereby reducing temperature increment of the magnet due to vibration of the refrigerator; and the conduction-cooled superconducting magnet Dewar has the advantages of easy operation of manufacture, processing and installation, and is applicable to scale production.
Owner:INST OF PLASMA PHYSICS CHINESE ACAD OF SCI

Joint pumped storage power station and wind power and solar power complementary system and optimization method therefor

The invention discloses a joint pumped storage power station and wind power and solar power complementary system and an optimization method therefor, and belongs to the technical field a joint wind power and solar power energy storage power generation system. By transforming an available space of a waste mine, a hybrid power generation system, combined by an underground water-pumping energy-storage power station and a surficial wind power and solar power complementary power generation system, is established; by taking the operation indexes, such as the wind power and solar power complementary system, the water-pumping energy-storage power station, power grid transmission power and the like as constraint conditions, a configuration model with the minimum wind power and solar power complementary output fluctuation, the minimum joint system output fluctuation and an optimized tracking load curve is obtained; and finally, solving and optimization on the model is performed based on an improved simulated annealing algorithm. By taking full advantages of the energy storage and power generation capability of the underground water-pumping energy-storage power station and by combination with the complementary characteristics of the wind power and solar power resources, the joint system is higher in flexibility in output regulation, the total output tracking load curve is better in effect, and the system is higher in new energy consumption and utilization.
Owner:CHINA UNIV OF MINING & TECH

Steam stripping method of process condensate in CO conversion

The invention relates to a steam stripping method of process condensate in CO conversion. The invention is characterized in that the process condensate firstly enters the upper part of a carbon dioxide steam stripping tower for flashing evaporation; secondary steam from the upper part of an ammonia-evaporated steam stripper tower enters the bottom part of the carbon dioxide steam stripping tower and steam strips carbon dioxide by countercurrent contacting with the process condensate after flashing evaporation; the process condensate after flash evaporation and the steam stripped carbon dioxide carry out countercurrent contact; the process condensate after flash evaporation and steam stripping enters the upper part of the ammonia-evaporated steam stripper tower from the bottom part of the carbon dioxide steam stripping tower and is steam-stripped by low-pressure steam entering from a kettle of the ammonia-evaporated steam stripper tower; gas phase is treated by secondary condensation to obtain non-acid-coagulated gas and condensate sewage; and steam stripping water is obtained from the bottom part of the ammonia-evaporated steam stripper tower. The invention carries out steam stripping on the upper and lower towers to carbon dioxide and ammonia in the process condensate respectively, thus avoiding the possibility of coexistence of carbon dioxide and ammonia in a condensing system, effectively solving the problem that the steam stripping system of the process condensate in the conversion procedure occurs ammonium salt crystallization blockage and prolonging the period of stable operation of a conversion device.
Owner:CHINA PETROCHEMICAL CORP +2

Magnetic nanoparticle-based immobilized laccase and ionic liquid composite particle and application thereof

The invention discloses a magnetic nanoparticle-based immobilized laccase and an ionic liquid composite particle, a preparation method thereof and application in removal of contaminants in water. The preparation method comprises the steps that carbonyl iron is taken as an iron source and is synthesized to be gamma-Fe2O3 nano-particles through a chemical precipitation method; the magnetic nanoparticles are taken as cores, tetraethoxysilane and a silane coupling agent are taken as a silicon source, and by means of a sol-gel method, surface amino-functionalized nano core-shell type magnetic silicon dioxide is prepared; 1-ethyl-(3-dimethyllaminopropyl) carbodiie hydrochlide is taken as a coupling agent, and laccase is bonded on the surface of the nano core-shell type magnetic silicon dioxide in a covalent bond manner to obtain the immobilized laccase of the magnetic nanoparticle silicon dioxide particles; and then the immobilized laccase is reacted with a functionalized ionic liquid which is synthesized by reacting N,N-carbonyldiimidazole and an ionic carboxy contained liquid to prepare the magnetic nanoparticle immobilized laccase and ionic liquid composite particle, and the composite particle is applied to the removal of the contaminants in water.
Owner:SOUTH CHINA UNIV OF TECH

Preparation method and application of cobalt-loaded mesoporous graphite-phase carbon nitride visible-light-induced catalyst

The invention discloses a preparation method of cobalt-loaded mesoporous graphite-phase carbon nitride (Co / mpg-C3N4) and an application of cobalt-loaded mesoporous graphite-phase carbon nitride (Co / mpg-C3N4) in visible-light-induced catalytic degradation of methylene blue. The catalyst is prepared by steeping a cobalt precursor and roasting at high temperature. The preparation method comprises the following steps of: (1) roasting at high temperature by using silica solution (Ludox, HS-40, 12nm, 40wt%SiO2) as a template and cyanamide as a carbon source and a nitrogen source, and removing the template to prepare mesoporous graphite-phase carbon nitride (mpg-C3N4); and (2) steeping the precursor solution of cobalt into mpg-C3N4, carrying out secondary high-temperature roasting in a muffle furnace to prepare the load-type catalyst Co / mpg-C3N4. By using the cobalt-carried mesoporous graphite-phase carbon nitride as the visible-light-induced catalyst, the result shows that the effect of the cobalt-carried mesoporous graphite-phase carbon nitride used for the visible-light-induced catalytic degradation of methylene blue is good, and the visible-light-induced catalytic degradation rate is obviously improved in comparison with the mesoporous graphite-phase carbon nitride (mpg-C3N4) without cobalt.
Owner:NANJING UNIV OF SCI & TECH

Preparation and application of amino modified Fe3O4@SiO2@mSiO2 composite particles with mesoporous structure

InactiveCN105964216AGood superparamagneticImproved saturation magnetizationOther chemical processesWater contaminantsSorbentSilanes
The invention relates to a preparation method of amino modified Fe3O4@SiO2@mSiO2 composite particles with a mesoporous structure. The preparation method comprises the steps: dispersing Fe3O4@SiO2 powder into a mixture solution of ethanol, deionized water, ammonia water and a template agent, so as to obtain a sol solution; then, dropwise adding TEOS into the sol solution, so as to prepare Fe3O4@SiO2@mSiO2 composite particles with the mesoporous structure; drying the Fe3O4@SiO2@mSiO2 composite particles, then, adding ethylene glycol into the dried Fe3O4@SiO2@mSiO2 composite particles, carrying out ultrasonic separation, then, adding a silane reagent, carrying out high-temperature refluxing while carrying out stirring so as to enable the silane reagent to be adsorbed into mesoporous pore passages of SiO2, carrying out a hydrolytic reaction, removing unreacted silane reagent or the silane reagent which is not adsorbed into the mesoporous pore passages, and finally, carrying out vacuum drying, thereby obtaining the amino modified Fe3O4@SiO2@mSiO2. According to the preparation method, SiO2 with a mesoporous structure serves as a shell layer, a nanoparticle Fe3O4 serves as a magnetic core, the stability in an acidic solution system is excellent, the difficult problem of the ordinary adsorbents that the separation is difficult after adsorption can be solved, the efficiency of adsorbing a target product is increased, and the reuse rate of an adsorbent is increased, so that the preparation method has good economic and environmental benefits.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

Purification process for preparing high-purity coenzyme Q10

The invention relates to a purification process for preparing high-purity coenzyme Q10 from crude coenzyme Q10 extracts obtained from thallus fermentation, which belongs to the technical field of compound separation purification. The purification process is characterized by sequentially comprising the following steps of: carrying out adsorbent resin adsorption, elution, concentration, crystallization and recrystallization on the crude coenzyme Q10 extracts; then, carrying out chromatography on a silicagel column; and purifying and refining by using a petroleum ether -aether or normal hexane-ethyl acetate mixed solvents as eluant. The invention has the following advantages that by adopting an adsorbent resin, good adsorption performance can be exerted on the coenzyme Q10, the desorption operation is simple, the stability is good, and the adsorbent resin can be reused many times; and by combining the adsorbent resin with the silica gel chromatography method, the silica gel utilization rate is high, the required silica gel is low quantity and can maintain good purification effect after being reused more than 10 times, the waste quantity of the silica gel is small, and the solvents can be recycled so that the purpose of environment protection is achieved. The production operation is simple and convenient, and the purity of the obtained coenzyme Q10 is higher than or equal to 98 percent.
Owner:EAST CHINA UNIV OF SCI & TECH +1

Manufacturing method of ice bag for preserving biological products

The invention discloses a manufacturing method of an ice bag for preserving biological products. The manufacturing method comprises the following steps: 1) adding a thickener into hot water or boiling water, and fully stirring till dissolution; 2) adding high molecular water-absorbing resin into a solution in the step 1) while hot, stirring, then standing to carry out full reaction and imbibition on the high molecular water-absorbing resin and the thickener, and forming a gelatinous solid, wherein the reaction time is 5-30minutes; and 3) bagging the gelatinous solid in the step 2), cooling, and then placing into a cold storage, a refrigerating cabinet or a refrigerator at the temperature of -10 DEG C to -20 DEG C for freezing for above 12hours. The invention provides a simple, convenient and high-efficient manufacturing method of a high molecular cold storage agent, namely the manufacturing method of the ice bag for preserving the biological products. The prepared cold storage agent has the advantages of high repeatability, great freezing-thawing phase change latent heat, long cold storage time and fast water absorption speed, and furthermore, the cost of the process is low; and by changing the added thickener, the different phase change temperatures can be obtained for meeting various different application requirements.
Owner:浙江赛灵特医药科技有限公司

Construction method of geogrid reinforced clay edge-covered tailing subgrade

ActiveCN104631254AImprove overall strengthImproved deformation and failure characteristicsRoadwaysCapillary waterSubgrade
The invention discloses a construction method of a geogrid reinforced clay edge-covered tailing subgrade and belongs to the technical field of subgrades in the civil engineering. The construction method comprises the following steps: foundation treatment, sand gravel underlayer construction, laying of a two-way geogrid and water-permeable geotechnical cloth, feeding laying operations of clay edge-covering layers on the two sides of the subgrade and a tailing subgrade main body layer by layer, rolling construction, one-way geogrid construction between the tailing subgrade main body and the edge-covering clay to a designed elevation, and finally, the construction of an ash doped clay sealing layer. As the one-way geogrids are laid between the clay edge-covering layers on the two sides of the subgrade and the tailing subgrade main body, the defects such as differential settlement, poor subgrade stability and the like between the two fillers, namely the clay and the tailings, are reduced. The construction method has the advantages of simple structure, low cost and convenience for construction; besides, the consumption of the tailings and the overall stability of the subgrade can be increased, the differential settlement and the usage of the earthwork of the subgrade are reduced, rainfall infiltration and capillary water rise are decreased, and the internal drainage performance of the section of the subgrade is improved.
Owner:SHIJIAZHUANG TIEDAO UNIV

Dual-shear force wall deformation slit formwork

The invention discloses a novel double shear wall deformation joint mould plate. Forming mould plate system on each side comprises a panel, wherein vertical wood keels are fixed outside the panel by iron nails, horizontal keels are arranged outside the vertical wood keels, the horizontal keels are made of steel pipes, and each two steel pipes are closely arranged; the two adjacent steel pipes of the forming mould plate system on one side are welded with a steel plate provided with a screw rod hole, a nut of a double-pulling screw rod is welded in the screw rod hole; the horizontal keels of the forming mould plate system on the other side are provided with a reverse M-shaped clip used to fix the double-pulling screw rod; the double-pulling screw rod passes through the forming mould plate system on the left side and the forming mould plate system on the right side, and is fixed by the steel plates and the nut in the reverse M-shaped clip; a wall plate thickness limitation support is arranged between the panels of the forming mould plate system on the left side and the forming mould plate system on the right side; the double-pulling screw rod is sleeved by a plastic sleeve, both ends of which are inserted in the panels of the forming mould plate system on the left side and the forming mould plate system on the right side respectively. The mould plate of the invention has the advantages of reasonable structure, cost conservation, short construction period, convenient use, flexible assembly, high repeated use rate and good constructional safety.
Owner:JIANGSU NANTONG NO 2 CONSTR ENG GRP

Excellent and efficient carbon fiber biofilm carrier modification method

The invention discloses an excellent and efficient carbon fiber biofilm carrier modification method and aims to improve water treatment performance of carbon fibers used as biofilm carrier materials. A basic raw material is the carbon fibers; the modification method mainly comprises steps as follows: firstly, acid oxidation treatment is performed on the carbon fibers, so that surfaces of the carbon fibers are ensured to have sufficient functional groups for preparation for iron carrying; then an organic iron solution is used as a modifying agent, surface modification is performed on the carbon fibers with a liquid phase impregnation method, and an organic-iron-modified carbon fiber biofilm carrier material with the surface containing the iron element is prepared. The preparation method is simple and easy to implement, prepared organic-iron-modified carbon fibers can keep original excellent performance of the carbon fibers, the surface roughness and the hydrophilicity are significantly improved, the film colonization cycle is short, the microbial activity is improved, time required for water treatment is short, removal rates of COD, ammonia nitrogen and total phosphorus are obviously increased, the outgoing water quality is good in stability, and the reuse rate is higher.
Owner:HANGZHOU INST OF ADVANCED MATERIAL BEIJING UNIV OF CHEM TECH

Microorganism-loaded sandwiched micro-nano fiber composite membrane and preparation method and application thereof

The invention discloses a method for preparing a microorganism-loaded sandwiched micro-nano fiber composite membrane capable of adsorbing heavy metals on the basis of alternate use of electrostatic spinning and electrostatic spraying. The method comprises the steps that a polymer composite is dissolved into an organic solvent, and magnetic stirring is conducted to obtain a mixed solution; a micro-nano fiber membrane is prepared through an electrostatic spinning technology; microorganisms are dispersed into deionized water, and the solution is stirred to be uniform and electrostatically sprayed on the surface of the micro-nano fiber membrane; a sample is put into a vacuum drying oven to be dried till the solvent is completely volatilized, and a double layer is obtained; the microorganism-loaded sandwiched micro-nano fiber composite membranes with the different needed odd and even layer numbers can be obtained through repeated operation. What is more novel is that the material can achieve repeated desorption and reutilization and is significant in adsorption effect; in addition, the method is low in raw material cost, good in biocompatibility, mild in reaction condition, wide in applicability and the like and is expected to be applied to large-scale industrial production.
Owner:WUHAN UNIV

Polyacrylonitrile fiber duplex metal complexes catalyst and preparation method thereof

The invention relates to a polyacrylonitrile fiber bimetallic complex catalyst and a preparation method thereof. The catalyst is characterized in that the appearance is between brownish yellow and yellowish green and is fiber-shaped; and the catalyst is formed by polyacrylonitrile fiber which is modified by hydrazine hydrate and hydroxylamine hydrochloride, and a coordination compound of iron ion and copper ion, wherein, the contents of iron ion and copper ion are 11.60mg / g to 26.10mg / g and 11.15mg / g to 28.30mg / g respectively. The preparation method adopts the following steps: 1. the pre-treatment of the polyacrylonitrile fiber; 2. modified reaction of the hydrazine hydrate of the polyacrylonitrile fiber and hydroxylamine hydrochloride; 3. the preparation of mixed solution of iron ion and copper ion; 4. the coordination reaction of the modified polyacrylonitrile fiber and metal ions; therefore, the fiber-shaped polyacrylonitrile fiber bimetallic complex catalyst with the color between brownish yellow and pale green is obtained. The catalyst has good catalytic activity, is applicable to the degradation of dyes in the basic printing and dyeing wastewater and has high reuse rate.
Owner:TIANJIN POLYTECHNIC UNIV
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