The invention, which relates to an electrochromic device and a preparation method thereof, discloses a quick-response all-solid-state electrochromic device and a preparation method thereof, thereby solving problems of low preparation efficiency and low response speed of the existing electrochromic device. The quick-response all-solid-state electrochromic device comprises a substrate, a bottom electrode layer, an electrochromic layer, a complementary color-changing layer, a lithium layer and a top electrode layer. In addition, the method includes: depositing a bottom electrode layer, a electrochromic layer, a complementary color-changing layer, a lithium layer and a top electrode layer on a substrate by adopting a vacuum coating method, a magnetron sputtering method, a vacuum thermal evaporation method or an electron beam evaporation method. According to the invention, the prepared device has response time less than five seconds; and a quick-response all-solid-state electrochromic device can be obtained.